Photoinduced Atomic Force Spectroscopy and Imaging of Two-Dimensional Materials

International audienc

Photonic Excitation of a Micromechanical Cantilever in Electrostatic Fields

International audienceWe present a specific near-field configuration where an electrostatic force gradient is found to strongly enhance the optomechanical driving of an atomic force microscope cantilever sensor. It is shown that incident photons generate a photothermal effect which couples with electrostatic fields even at tip-surface separations as large as several wavelengths, dominating the cantilever dynamics. The effect is the result of resonant phenomena where the photothermal-induced parametric driving acts conjointly (or against, depending on electric field direction) with a photovoltage generation in the cantilever. The results are achieved experimentally in an atomic force microscope operating in vacuum and explained theoretically through numerical simulations of the equation of motion of the cantilever. Intrinsic electrostatic effects arising from electronic work-function difference of tip and surface are also highlighted. The findings are readily relevant for other opto-micromechanical systems where electrostatic force gradients can be implemented

A spin-selective approach for surface states at Co nanoislands

During recent years the surface electronic states of cobalt nanoislands grown on Cu(111) and Au(111) have been extensively studied and still yield fascinating results. Among magnetic surfaces, cobalt islands are particularly appealing because of their spin-polarized electronic states near the Fermi energy, involving localized d states of minority character, as well as free-like s–p states of majority character. We show here that these states are a sensitive probe to minute changes of structural details such as strain and stacking, and therefore constitute an ideal playground to study the interplay between structural and spin-related properties. Due to their size, cobalt islands on Cu(111) offer the additional opportunity to host single-magnetic adsorbates suitable for spin-polarized scanning tunneling microscopy and spectroscopy (SP-STM and SP-STS). We establish here that, in an energy interval just below the Fermi level, the spin-polarization of a transition-metal atom is governed by surface-induced states opposite in sign compared to the island, while the spin-polarization of Co-Phthalocyanine molecules is governed by molecular states. This opens up interesting perspectives for controlling and engineering spin-polarized phenomena at the nanoscale