Fatty acid, triacylglycerol compositions, and crystalline structure of bambangan (mangifera pajang) seed fat extracted using different solvent

Nowadays, research on the bambangan fruit waste (seed) has become an interest because of its potential application as a cocoa butter alternative. This work aimed to determine the changes in the quality of the extracted bambangan seed fat (BSF) obtained from hexane, petroleum ether, and ethanol. The total fat content (TFC), physicochemical properties, fatty acid profiles, triacylglycerol composition, and crystalline structure of the extracted BSF were all affected by the extraction solvents. The results showed that BSF has a high content of 1,3-distreoyl-2-oleoyl-glycerol (SOS) of 30.22 – 44.29 %. The solvent type significantly (p<0.05) impacts the stearic and oleic acids of the extracts, resulting in the apparent changes in the high melting symmetrical triacylglycerols such as the SOS. Petroleum ether extracted BSF has high stearic acid of 33.40 %, followed by the hexane and ethanol extracted BSF of 29.29 % and 27.84 % respectively. Moreover, the spherulitic microstructure with needle-like crystals of the extracts also ranging from 30 to 70 μm diameters. Hexane extracted BSF illustrated a less dense spherulitic crystalline micro-structure with a less granular centre than those extracted using the other solvents. The results suggested that the quality of the extracted BSF obtained from non-polar solvent of hexane and petroleum ether is better than the polar solvent (ethanol)

Characterization and nutritional content of Terminalia catappa kernel and its oil from Sabah, Malaysia

This study was aimed to evaluate the nutritional quality of Terminalia catappa kernel oil (TCKO) and its characterization as well as total phenolic content cultivated in two different locations in Sabah, Malaysia. TCK contained 6.87 to 6.92% moisture, 4.54 to 4.77% ash, 21.98 to 22.44% protein, 5.13 to 5.36% total fibre, 6.88 to 7.01% carbohydrate, and 49.45 to 54.47% oil. The iodine value (IV), free fatty acid (FFA), peroxide value (PV), refractive index (RI), and total phenolic content (TPC) were found to be comparable to that of edible oils. The FFA, IV, PV, color, and TPC values showed significant differences. These results also revealed that the oil from Kota Kinabalu TCK contain more unsaturated fatty acids and display lower oxidative stability as compared to oil extracted from Keningau TCK. From the nutritional point of view, TCK oil had interesting fatty acid composition, displaying the lowest atherogenicity and thrombogenicity indices, highest polyunsaturated/saturated fatty acids and hypocholesterolemic/hypocholesterolemic ratios, respectively. This is suggested that TCK oil have potential to become a new source of healthy edible oil

Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique

The search for hard fats is increasing by the day due to their demand for industrial purposes. Rambutan seed fat (RSF) was fractionated prior to investigate the melting and crystallisation behaviours, triacylglycerols (TAGs), and morphology using different chromatographic and thermal techniques. The increasing trends were observed for high‐melting symmetrical monounsaturated TAGs such as 1,3‐distearoyl‐2‐oleoyl‐glycerol and 1‐palmitoyl‐3‐stearoyl‐2‐oleoyl‐glycerol in both solid fractions upon fractionation. The solid fractions (F1‐S) and (F2‐S) exhibited small peaks towards low melting area and big peaks towards high melting area with the offset temperatures of 35.29–48.75 °C and 43.58–52.70 °C with significantly higher enthalpies (93.49 and 105.13 J g−1) upon fractionation. F2‐S showed the densely packed microstructure compared to that of crude RSF and F1‐S. Based on the thermal behaviours as well as morphology of RSF fractions, cocoa butter improver could be prepared that has the potential to be utilised in chocolate manufacturing in tropical countries

A review on functional and nutritional properties of noni fruit seed (Morinda citrifolia L.) and its oil

Noni (Morinda citrifolia L.) is native to the Polynesian and recognized in the tropical and subtropical countries as a sustainable crop with feasible commercial applications. It has been reported that the interest in developing noni plant as a novel source of bioactive compounds are increasing by the day. This review describes the safety, nutritional values, and the properties of noni seed oil (NSO) with potential industrial uses. In particular, the bioactive compounds, anti-nutrients, antioxidant activity, and IC50 values of noni seed and the chemical composition of NSO are also described. NSO has high contents of polyunsaturated fatty acids, total phytosterols and tocopherols that could be better choices for patients with high cholesterol and cardiovascular diseases. Extracts of noni seed have been shown to possess bioactive compounds that exhibit antioxidant, anti-mutagenic, anti-tumor, anti-inflammatory, anti-allergic, anti-viral, anti-fungal, anti-microbial, and anti-carcinogenic properties. Bioactive compound-rich noni fruit seed could be a potential source of functional foods. Moreover, noni seeds could be a valuable new source of vegetable oil because of its nutritional properties and non-toxic nature along with the increasing supply of seeds as by-products from noni juice industry. Comprehensive studies are needed on NSO to explore more potential product development. Moreover, further study is needed on the development of nutraceutical food products from noni seed by-products

Hard fats improve the physicochemical and thermal properties of seed fats for applications in confectionery products

Hard fats, obtained from liquid oils by different fat modification techniques, are composed of high-melting-point triacylglycerols (TAGs) that can be used as alternatives to improve the functional characteristics of lipid systems. These low‐cost industrial products are regarded as raw materials in lipid technology. They can behave as modifiers in crystallization processes, acting as preferential nuclei for ordering crystal lattices and inducing specific polymorphic patterns because of their homogeneous TAGs. Adding hard fats, such as mango, illipe, kokum, sal, shea, rambutan, palm oil, palm kernel oil, and sunflower oil, into other oils is beneficial as it increases their compatibility for uses in fat-based products, especially confectionery products. The addition of hard fats has a significant effect on the rate of crystallization, significantly decreasing the induction time for nucleation and leading to a higher hardness, and increases the thermal resistance for applications in fat-based products. The aim of this article is to review the changes in the physicochemical and thermal properties of hard fats and their mixtures obtained by fractionation, enzymatic interesterification and blending, which broaden their applicability in the food industry

Physicochemical properties of bambangan kernel fat and its stearin mixtures with cocoa butter

The fractionated cocoa butter improver from the bambangan kernel fat (BKF) was blended with commercial cocoa butter (CB), and the physicochemical properties of the blends were determined. The characteristics, such as solid fat content (SFC), fatty acids composition and physicochemical properties of pure BKF, its first (S-1) and second stearin (S-2) fractions integrated with CB at varying ratios (g/100 g) were determined. B4, F4, and M4 blends containing 20% BKF or S-1 and S-2 with 80% CB showed good compatibility with the presence of 22.42–22.57% palmitic, 37.23–37.63% stearic, and 33.67–33.91% oleic acids. These blends also showed similar pattern of SFC curves as CB, at which the SFCs of the three blends dropped to 0% after 35 ◦C. Moreover, the blends also exhibited comparable iodine value (36.17–36.58 g iodine/g) and slip melting point (SMP) (28.83–29.17 ◦C) with the commercial CB. In comparison with the hard fat (S-1 and S-2), which had high SMP and stearic acid (44.71–48.51%), the fatty acids composition of fat blends significantly (p < 0.05) decreased and resulted in low SFC values. The results obtained in this study proposed that the best blends to converge with CB were B4, F4 and M4

Fatty acids, triacylglycerols, thermal properties, morphology and antioxidant activity of Canarium odontophyllum seed oil

Canarium odontophyllum Miq. (Dabai) is an underutilized fruit and its oil has the potential to broaden the availability of healthy edible oil. The objective of this study was to determine the physiochemical and thermal properties, fatty acid and triacylglycerol profiles, morphological behavior, and antioxidant capabilities of dabai seed oil (DSO) by using chromatographic and thermal techniques. The results showed that DSO has a low unsaturation values, high peroxide and refractive index values with a melting point at body temperature. DSO showed 56.47% saturated fatty acids, 40% unsaturated fatty acids and 29.88% of 1,3-dipalmitoyl-2-oleoyl-glycerol content. Some crystals showed larger than 30 µm in size and others smaller, including spherical, dot-covered spherulites between 0.5 and 5 µm in size. In addition, the amount of ferric reducing power and phenolic contents of DSO were 3.62±0.10 mMol of Fe2+/g and 21.73±0.98 mg GAE per 100 g of samples. The DSO mimics the composition of palm stearin and palm oil mid fraction and showed comparable physicochemical and thermal properties to that of commercial cocoa butter. The results showed that the DSO has a traceable amount of antioxidant activity and good potential to be developed as a healthy edible oil resource