Survey efficiency of ultraviolet and zinc oxide process (UV/ZnO) for removal of diazinon pesticide from aqueous solution

The presence of persistent organic pollutants and toxics (e.g., pesticides) in ground, surface, and drinking water resources combined with the inability of conventional treatment methods to remove these pollutants have led to the development of advanced oxidation processes. Nowadays, nanophotocatalyst processes are considered as clean and environmentally-friendly treatment methods that can be extensively used for removing contaminants. The objective of the present study was to determine the efficiency of the ultraviolet and zinc oxide (UV/ZnO) process in the removal of diazinon pesticide from aqueous solutions. For the purposes of this study, samples were adjusted in a batch reactor at five different detention times. The pH levels used were 3, 7, and 9. Irradiation was performed using a 125 W medium-pressure mercury lamp. The diazinon concentrations of the samples were 100 and 500 Sg/L and the concentrations of zinc oxide nanoparticles were 50, 100, and 150 mg/L. The highest degradation efficiency was observed at pH 7 (mean = 80.92 ± 30.3), while the lowest was observed for pH 3 (mean 67.11 ± 24.49). Results showed that the optimal concentration of nanoparticles (6-12 nm) was 100 mg L-1

Potoccatalytic oxidation of oganophosphorus pesticides using zinc oxide

Abstract In recent years, the application of heteroge-neous photocatalytic water treatment processses has gained wide attention due to its effectiveness in degra-ding and mineralizing the pesticides. These pesticides are often found in many surface and groundwater sources and their concentration levels often exceed the drinking water permissible limits recommended by Iran and European drinking water standards. The aim of the present study was to investigate the influence of various parameters such as initial malathion and diazinon concentration catalyst amount, initial pH of the reaction medium and pesticide types on the photocatalytic decomposition of pesticides in the presence of ZnO using an ultraviolet lamp as the light source. The best conditions for the photocatalytic degradation of pesticides were obtained. Results showed that the optimal concentration of catalyst was found to be 100 mg. L -1 . The photodegradation efficiency of pesticides increases with the increase of the illumination time. The photodegradation rate of pesticides was higher in alkaline than in acidic conditions. The photocatalytic degradation rate of the malathion was more than diazinon. The photodegradation efficiency decreases with the increase in the initial concentration of pesticides. The photocatalytic system afforded the highest removed percentage at initial concentration for diazinon and malatlion were 100 and 200 mg.L-1 respectivel

Magnetic Branes in Gauss-Bonnet Gravity

We present two new classes of magnetic brane solutions in Einstein-Maxwell-Gauss-Bonnet gravity with a negative cosmological constant. The first class of solutions yields an $(n+1)$-dimensional spacetime with a longitudinal magnetic field generated by a static magnetic brane. We also generalize this solution to the case of spinning magnetic branes with one or more rotation parameters. We find that these solutions have no curvature singularity and no horizons, but have a conic geometry. In these spacetimes, when all the rotation parameters are zero, the electric field vanishes, and therefore the brane has no net electric charge. For the spinning brane, when one or more rotation parameters are non zero, the brane has a net electric charge which is proportional to the magnitude of the rotation parameter. The second class of solutions yields a spacetime with an angular magnetic field. These solutions have no curvature singularity, no horizon, and no conical singularity. Again we find that the net electric charge of the branes in these spacetimes is proportional to the magnitude of the velocity of the brane. Finally, we use the counterterm method in the Gauss-Bonnet gravity and compute the conserved quantities of these spacetimes.Comment: 17 pages, No figure, The version to be published in Phys. Rev.

Slowly rotating charged black holes in anti-de Sitter third order Lovelock gravity

In this paper, we study slowly rotating black hole solutions in Lovelock gravity (n=3). These exact slowly rotating black hole solutions are obtained in uncharged and charged cases, respectively. Up to the linear order of the rotating parameter a, the mass, Hawking temperature and entropy of the uncharged black holes get no corrections from rotation. In charged case, we compute magnetic dipole moment and gyromagnetic ratio of the black holes. It is shown that the gyromagnetic ratio keeps invariant after introducing the Gauss-Bonnet and third order Lovelock interactions.Comment: 14 pages, no figur

Horizonless Rotating Solutions in (n+1)(n+1)-dimensional Einstein-Maxwell Gravity

We introduce two classes of rotating solutions of Einstein-Maxwell gravity in $n+1$ dimensions which are asymptotically anti-de Sitter type. They have no curvature singularity and no horizons. The first class of solutions, which has a conic singularity yields a spacetime with a longitudinal magnetic field and $k$ rotation parameters. We show that when one or more of the rotation parameters are non zero, the spinning brane has a net electric charge that is proportional to the magnitude of the rotation parameters. The second class of solutions yields a spacetime with an angular magnetic field and $$ boost parameters. We find that the net electric charge of these traveling branes with one or more nonzero boost parameters is proportional to the magnitude of the velocity of the brane. We also use the counterterm method inspired by AdS/CFT correspondence and calculate the conserved quantities of the solutions. We show that the logarithmic divergencies associated to the Weyl anomalies and matter field are zero, and the $r$ divergence of the action can be removed by the counterterm method.Comment: 14 pages, references added, Sec. II amended, an appendix added. The version to appear in Phys. Rev.

Applying job hazard analysis and William Fine methods on risks identification and assessment of jobs in hot rolling steel, Iran

Background and purpose: Comprehensive evaluation of jobs in industries is a practical and effective method that could identify the jobs and industries with negative effects on the environment. This study identified environmental hazards of hot rolling process and assessing their risks. Materials and methods: An observational study was carried out in which identification of human activity and job’s risks in production hall of Kavir Steel Complex was done according to ISO 14001 approaches (pollutant emissions to air, discharges to water, energy consumption, energy released as heat, wastes, side products, etc) by Job Hazard Analysis method (JHA). Then the risks identified were prioritized and assessed using William Fine method. Results: We identified 205 environmental hazards (in 9 groups) associated with production personnel (n= 81), mechanics and maintenance personnel (n= 44), bed personnel (n= 9), personnel of cleaning services (n= 33), and water plant personnel (n= 38). The highest and lowest rate of risks were due to creation and distribution of wastes (n= 73) and corrosion and depreciation of equipment, (n= 1), respectively. Conclusion: The production personnel were mainly responsible for environmental emissions. The leading causes were stress and anxiety about stoppage of production, payment reduction, and lack of awareness and workers and supervisors on environmental issues. © 2017, Mazandaran University of Medical Sciences. All rights reserved

Removal of malathion insecticide from water by employing acoustical wave technology

Background: Organophosphorus pesticides are one of the most prevalent usages for pest control in the country. Such pesticides enter into water sources by different routes. Since drinking of contaminated water at the higher doses than the standard level, may causes undesirable effects to human health and ecosystem. The object of this research was to investigate the effect of various parameters including time, power and concentration on sonodecomposition of malathion insecticide in the water. Methods: The sonochemical degradation of malathion was investigated using acoustic wave technology (AWT). AWT with 130 kHz was used to study the decomposition of insecticide solution. Samples were analyzed using HPLC at different intervals times. Effectiveness of AWT at different times (20, 40, 60, 80, 100, and 120 minutes), concentrations of malathion at 2, 4 and 8 mg/L as well as powers of device (300W, 400W, 500W) are compared. Results: These findings showed that the degradation of the malathion insecticide at lower concentrations was greater in comparison to higher concentrations. Also, there was positive correlation between power increasing and the ability to malathion degradation Conclusion: The sonodegradation of malathion at different concentrations and powers was successfully achieved. It has been shown that acoustical wave technology can be used to reduce the concentration of dissolved insecticide using high frequency

Ricci flat rotating black branes with a conformally invariant Maxwell source

We consider Einstein gravity coupled to an $U(1)$ gauge field for which the density is given by a power of the Maxwell Lagrangian. In $d$-dimensions the action of Maxwell field is shown to enjoy the conformal invariance if the power is chosen as $d/4$. We present a class of charge rotating solutions in Einstein-conformally invariant Maxwell gravity in the presence of a cosmological constant. These solutions may be interpreted as black brane solutions with inner and outer event horizons or an extreme black brane depending on the value of the mass parameter. Since we are considering power of the Maxwell density, the black brane solutions exist only for dimensions which are multiples of four. We compute conserved and thermodynamics quantities of the black brane solutions and show that the expression of the electric field does not depend on the dimension. Also, we obtain a Smarr-type formula and show that these conserved and thermodynamic quantities of black branes satisfy the first law of thermodynamics. Finally, we study the phase behavior of the rotating black branes and show that there is no Hawking--Page phase transition in spite of conformally invariant Maxwell field.Comment: 13 pages, one figur

Charged rotating dilaton black branes in AdS universe

We present the metric for the $(n+1)$-dimensional charged rotating dilaton black branes with cylindrical or toroidal horizons in the background of anti-de Sitter spacetime. We find the suitable counterterm which removes the divergences of the action in the presence of the dilaton potential in all higher dimensions. We plot the Penrose diagrams of the spacetime and reveal that the spacetime geometry crucially modifies in the presence of the dilaton field. The conserved and thermodynamic quantities of the black branes are also computed.Comment: 13 pages, 3 figures, to appear in Gen. Relat. Gravi

Abelian Higgs Hair for Rotating and Charged Black Holes

We study the problem of vortex solutions in the background of rotating black holes in both asymptotically flat and asymptoticlly anti de Sitter spacetimes. We demonstrate the Abelian Higgs field equations in the background of four dimensional Kerr, Kerr-AdS and Reissner-Nordstrom-AdS black holes have vortex line solutions. These solutions, which have axial symmetry, are generalization of the Nielsen-Olesen string. By numerically solving the field equations in each case, we find that these black holes can support an Abelian Higgs field as hair. This situation holds even in the extremal case, and no flux-expulsion occurs. We also compute the effect of the self gravity of the Abelian Higgs field show that the the vortex induces a deficit angle in the corresponding black hole metrics.Comment: 22 pages, 16 figures, a section about the vortex self gravity on Kerr black hole added, extremal black holes considered, one figure changed, one reference adde