18 research outputs found

    Hydroethoxycarbonylation of α-Olefins at Low Pressure of Carbon(II) Oxide in the Presence of the PdCl2(PPh3)2–PPh3–AlCl3 System

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    High catalytic activity of the PdCl2(PPh3)2â\u80\u93PPh3â\u80\u93AlCl3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (â\u89¤25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6â\u80\u9393.8%
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