Poly(1,3,4-oxadiazoles) via aromatic nucleophilic displacement

Poly(1,3,4-oxadiazoles) (POX) are prepared by the aromatic nucleophilic displacement reaction of di(hydroxyphenyl) 1,3,4-oxadiazole monomers with activated aromatic dihalides or activated aromatic dinitro compounds. The polymerizations are carried out in polar aprotic solvents such as sulfolane or diphenylsulfone using alkali metal bases such as potassium carbonate at elevated temperatures under nitrogen. The di(hydroxyphenyl) 1,3,4-oxadiazole monomers are synthesized by reacting 4-hydroxybenzoic hydrazide with phenyl 4-hydrobenzoate in the melt and also by reacting aromatic dihydrazides with two moles of phenyl 4-hydroxybenzoate in the melt. This synthetic route has provided high molecular weight POX of new chemical structure, is economically and synthetically more favorable than other routes, and allows for facile chemical structure variation due to the large variety of activated aromatic dihalides which are available

Self streamlining wind tunnel: Low speed testing and transonic test section design

Comprehensive aerodynamic data on an airfoil section were obtained through a wide range of angles of attack, both stalled and unstalled. Data were gathered using a self streamlining wind tunnel and were compared to results obtained on the same section in a conventional wind tunnel. The reduction of wall interference through streamline was demonstrated

Studies of self streamlining wind tunnel real and imaginary flows

Testing in the low speed flexible walled tunnel in an effort to explain the reasons for data discrepancies at high angles of attack are presented. Automated transonic test sections were developed. The flexible walled tunnel was used in a new operating mode to a generated curved flow around the airfoil, allowing the extraction of purely rotary derivatives. Some straight wall, low speed pressure data, for wall and model, which is used for checking interference correction methods were reported. Computer software which includes an old streamlining algorithm and a prediction algorithm was examined

Correlation effects in the density of states of annealed GaMnAs

We report on an experimental study of low temperature tunnelling in hybrid NbTiN/GaMnAs structures. The conductance measurements display a root mean square V dependence, consistent with the opening of a correlation gap in the density of states of GaMnAs. Our experiment shows that low temperature annealing is a direct empirical tool that modifies the correlation gap and thus the electron-electron interaction. Consistent with previous results on boron-doped silicon we find, as a function of voltage, a transition across the phase boundary delimiting the direct and exchange correlation regime.Comment: Replaced with revised version. To appear in Phys. Rev.

Dielectronic recombination data for astrophysical applications: Plasma rate-coefficients for Fe^q+ (q=7-10, 13-22) and Ni^25+ ions from storage-ring experiments

This review summarizes the present status of an ongoing experimental effort to provide reliable rate coefficients for dielectronic recombination of highly charged iron ions for the modeling of astrophysical and other plasmas. The experimental work has been carried out over more than a decade at the heavy-ion storage-ring TSR of the Max-Planck-Institute for Nuclear Physics in Heidelberg, Germany. The experimental and data reduction procedures are outlined. The role of previously disregarded processes such as fine-structure core excitations and trielectronic recombination is highlighted. Plasma rate coefficients for dielectronic recombination of Fe^q+ ions (q=7-10, 13-22) and Ni^25+ are presented graphically and in a simple parameterized form allowing for easy use in plasma modeling codes. It is concluded that storage-ring experiments are presently the only source for reliable low-temperature dielectronic recombination rate-coefficients of complex ions.Comment: submitted for publication in the International Review of Atomic and Molecular Physics, 8 figures, 3 tables, 68 reference

Calculations of K+, K- and phi Production in Near-Threshold Proton-Nucleus Collisions

K+, K- and \phi meson production in proton-nucleus (pA) collisions has been calculated within a BUU transport model. It is shown that the nucleon-hyperon strangeness transfer channel is essential. The role of three-body reactions has been investigated within the medium. The targetmass dependence of $\phi$ production is predicted to give important information on the in-medium properties of all three mesons.Comment: Talk presented by H.W.B. at the Budapest 2004 workshop on 'Hot and Dense Matter in Relativistic Heavy Ion Collisions', March 24-27, 2004, Budapest, Hungar

Structure determination of the clean Co(110) surface by LEED

The atomic structure of the (11 0) surface of cobalt has been determined by LEED using six intensity spectra at normal incidence. The surface exhibits the truncated bulk structure with a contraction of the first interlayer spacing by about 8.5% with respect to the bulk value. Quantitative evaluation of the LEED spectra was done using Zanazzi and Jona's and Pendry's r-factors. The minimum averaged r-factors are and . No change of the interatomic distances within the plane could be detected and no rearrangement of the surface structure takes place up to temperatures shortly below the transition temperature