105 research outputs found
On Electron Transport in ZrB12, ZrB2 and MgB2
We report on measurements of the temperature dependence of resistivity,
, for single crystal samples of ZrB, ZrB and
polycrystalline samples of MgB. It is shown that cluster compound
ZrB behaves like a simple metal in the normal state, with a typical
Bloch -- Gr\"uneisen dependence. However, the resistive Debye
temperature, , is three times smaller than obtained from
specific heat data. We observe the term in of these borides,
which could be interpreted as an indication of strong electron-electron
interaction. Although the dependence of ZrB reveals a sharp
superconductive transition at , no superconductivity was observed
for single crystal samples of ZrB down to .Comment: 5 pages, 4 figure
Electron transport, penetration depth and upper critical magnetic field of ZrB12 and MgB2
We report on the synthesis and measurements of the temperature dependence of
resistivity, R(T), the penetration depth, l(T), and upper critical magnetic
field, Hc2(T), for polycrystalline samples of dodecaboride ZrB12 and diboride
MgB2. We conclude that ZrB12 as well as MgB2 behave like simple metals in the
normal state with usual Bloch-Gruneisen temperature dependence of resistivity
and with rather low resistive Debye temperature, TR=280 K, for ZrB12 (as
compared to MgB2 with TR=900 K). The R(T) and l(T) dependencies of ZrB12 reveal
a superconducting transition at Tc=6.0 K. Although a clear exponential
l(T)dependence in MgB2 thin films and ceramic pellets was observed at low
temperatures, this dependence was almost linear for ZrB12 below Tc/2. These
features indicate s-wave pairing state in MgB2, whereas a d-wave pairing state
is possible in ZrB12. A fit to the data gives a reduced energy gap
2D(0)/kTc=1.6 for MgB2 films and pellets, in good agreement with published data
for 3D \pi - sheets of the Fermi surface. Contrary to conventional theories we
found a linear temperature dependence of Hc2(T) for ZrB12 (Hc2(0)=0.15 T).Comment: 8 pages, 10 figures, submitted to JET
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