Bis(4-(3,4-dimethylenepyrrolidyl)-phenyl) methane

It is the primary object of the present invention to prepare high temperature polymeric materials, especially linear aromatic polyimides, which maintain their integrity and toughness during long exposure times at elevated temperatures. According to the present invention, this object is achieved, and the attending benefits are obtained, by first providing the bis(exocyclodiene) bis(4-(3,4-dinethylene pyrrolidyl) phenyl) methane, which is formed from the monomer N-phenyl 3,4-dimethylene pyrrolidine. This bis-(exocyclodiene) undergoes Diels-Alder reaction with a bismaleimide without the evolution of gaseous by-products, to form the aromatic polyimide

Observable Graphs

An edge-colored directed graph is \emph{observable} if an agent that moves along its edges is able to determine his position in the graph after a sufficiently long observation of the edge colors. When the agent is able to determine his position only from time to time, the graph is said to be \emph{partly observable}. Observability in graphs is desirable in situations where autonomous agents are moving on a network and one wants to localize them (or the agent wants to localize himself) with limited information. In this paper, we completely characterize observable and partly observable graphs and show how these concepts relate to observable discrete event systems and to local automata. Based on these characterizations, we provide polynomial time algorithms to decide observability, to decide partial observability, and to compute the minimal number of observations necessary for finding the position of an agent. In particular we prove that in the worst case this minimal number of observations increases quadratically with the number of nodes in the graph. From this it follows that it may be necessary for an agent to pass through the same node several times before he is finally able to determine his position in the graph. We then consider the more difficult question of assigning colors to a graph so as to make it observable and we prove that two different versions of this problem are NP-complete.Comment: 15 pages, 8 figure

Resonance and marginal instability of switching systems

We analyse the so-called Marginal Instability of linear switching systems, both in continuous and discrete time. This is a phenomenon of unboundedness of trajectories when the Lyapunov exponent is zero. We disprove two recent conjectures of Chitour, Mason, and Sigalotti (2012) stating that for generic systems, the resonance is sufficient for marginal instability and for polynomial growth of the trajectories. We provide a characterization of marginal instability under some mild assumptions on the sys- tem. These assumptions can be verified algorithmically and are believed to be generic. Finally, we analyze possible types of fastest asymptotic growth of trajectories. An example of a pair of matrices with sublinear growth is given

Finite size scaling in three-dimensional bootstrap percolation

We consider the problem of bootstrap percolation on a three dimensional lattice and we study its finite size scaling behavior. Bootstrap percolation is an example of Cellular Automata defined on the $d$-dimensional lattice $\{1,2,...,L\}^d$ in which each site can be empty or occupied by a single particle; in the starting configuration each site is occupied with probability $p$, occupied sites remain occupied for ever, while empty sites are occupied by a particle if at least $\ell$ among their $2d$ nearest neighbor sites are occupied. When $d$ is fixed, the most interesting case is the one $\ell=d$: this is a sort of threshold, in the sense that the critical probability $p_c$ for the dynamics on the infinite lattice ${\Bbb Z}^d$ switches from zero to one when this limit is crossed. Finite size effects in the three-dimensional case are already known in the cases $\ell\le 2$: in this paper we discuss the case $\ell=3$ and we show that the finite size scaling function for this problem is of the form $f(L)={\mathrm{const}}/\ln\ln L$. We prove a conjecture proposed by A.C.D. van Enter.Comment: 18 pages, LaTeX file, no figur

Polyimide from bis(n-isoprenyl)s of aryl diamides

A process and polyimide product formed by the reaction of a bismaleimide with a bis(amidediene) is disclosed wherein the bis(amidediene) is formed by reacting an excess of an acid chloride with 1,4-N,N'-diisoprenyl 2,3,5,6-tetramethy1 benzene