Transport Anomalies and Marginal Fermi-Liquid Effects at a Quantum Critical Point

The behavior of the conductivity and the density of states, as well as the phase relaxation time, of disordered itinerant electrons across a quantum ferromagnetic transition is discussed. It is shown that critical fluctuations lead to anomalies in the temperature and energy dependence of the conductivity and the tunneling density of states, respectively, that are stronger than the usual weak-localization anomalies in a disordered Fermi liquid. This can be used as an experimental probe of the quantum critical behavior. The energy dependence of the phase relaxation time at criticality is shown to be that of a marginal Fermi liquid.Comment: 4 pp., LaTeX, no figs., requires World Scientific style files (included), Contribution to MB1

Measurement of intact methane isotopologues, including ^(13)CH_3D

Methane (CH_4) is both a significant greenhouse gas and resource. Its present and past cycling can be studied through measurements of concentration and/or bulk isotopic ratios (^(13)C/^(12)C, D/H, and ^(14)C/^(12)C). Currently, isotope ratios are measured by mass spectrometric analysis of H_2 and CO_2 produced from CH_4, or by spectroscopy of CH_4. However, the interpretation of bulk isotopic variations of CH_4 are often equivocal, necessitating additional tracers

Hydrologic change in New Zealand during the last deglaciation linked to reorganization of the Southern Hemisphere westerly winds

Millennial‐scale climate anomalies punctuating the last deglaciation were expressed differently in the Northern and Southern Hemispheres. While changes in oceanic meridional overturning circulation have been invoked to explain these disparities, the nearly synchronous onset of such events requires atmospheric mediation. Yet the extent and structure of atmospheric reorganization on millennial timescales remains unclear. In particular, the role of the Southern Hemisphere westerly winds (SHWW) and associated storm tracks is poorly constrained, largely due to the paucity of accessible archives of wind behavior. Here we present a new paleohydrologic record from a Lake Hayes, New Zealand (45° S) sediment core from ~17‐9 ka. Using two independent proxies for lake hydrology (Ca/Ti in sediments and δD values of aquatic plant biomarkers), we find evidence for a wetter Antarctic Cold Reversal (ACR, 14.7‐13.0 ka) and a drying trend during the Younger Dryas (YD, 12.9‐11.6 ka) and early Holocene (11.7 ka onward in this record). Comparisons of the Lake Hayes record with other Southern Hemisphere sites indicate coherent atmospheric shifts during the ACR and YD, whereby the former is wetter/cooler and the latter is drier/warmer. The wet/cool phase is associated with a northward shift and/or strengthening of the SHWW, whereas the drier/warmer phase indicates weaker mid‐latitude winds. These climatic trends are opposite to the Northern Hemisphere. There is a decoupling of climatic trends between Southern Hemisphere low‐ and mid‐latitude climates in the early Holocene, which could be explained by several mechanisms, such as the retreat of Antarctic sea ice

Isotopic exchange of carbon-bound hydrogen over geologic timescales

The increasing popularity of compound-specific hydrogen isotope (D/H) analyses for investigating sedimentary organic matter raises numerous questions about the exchange of carbon-bound hydrogen over geologic timescales. Important questions include the rates of isotopic exchange, methods for diagnosing exchange in ancient samples, and the isotopic consequences of that exchange. This article provides a review of relevant literature data along with new data from several pilot studies to investigate such issues. Published experimental estimates of exchange rates between organic hydrogen and water indicate that at warm temperatures (50–100°C) exchange likely occurs on timescales of 10^4 to 10^8 yr. Incubation experiments using organic compounds and D-enriched water, combined with compound-specific D/H analyses, provide a new and highly sensitive method for measuring exchange at low temperatures. Comparison of δD values for isoprenoid and n-alkyl carbon skeletons in sedimentary organic matter provides no evidence for exchange in young (350 Ma) rocks. Specific rates of exchange are probably influenced by the nature and abundance of organic matter, pore-water chemistry, the presence of catalytic mineral surfaces, and perhaps even enzymatic activity. Estimates of equilibrium fractionation factors between organic H and water indicate that typical lipids will be depleted in D relative to water by ∼75 to 140‰ at equilibrium (30°C). Thus large differences in δD between organic molecules and water cannot be unambiguously interpreted as evidence against hydrogen exchange. A better approach may be to use changes in stereochemistry as a proxy for hydrogen exchange. For example, estimated rates of H exchange in pristane are similar to predicted rates for stereochemical inversion in steranes and hopanes. The isotopic consequences of this exchange remain in question. Incubations of cholestene with D_2O indicate that the number of D atoms incorporated during structural rearrangements can be far less than the number of C-H bonds that are broken. Sample calculations indicate that, for steranes in immature sediments, the D/H ratio imparted by biosynthesis may be largely preserved in spite of significant structural changes

Probing the Subcellular Localization of Hopanoid Lipids in Bacteria Using NanoSIMS

The organization of lipids within biological membranes is poorly understood. Some studies have suggested lipids group into microdomains within cells, but the evidence remains controversial due to non-native imaging techniques. A recently developed NanoSIMS technique indicated that sphingolipids group into microdomains within membranes of human fibroblast cells. We extended this NanoSIMS approach to study the localization of hopanoid lipids in bacterial cells by developing a stable isotope labeling method to directly detect subcellular localization of specific lipids in bacteria with ca. 60 nm resolution. Because of the relatively small size of bacterial cells and the relative abundance of hopanoid lipids in membranes, we employed a primary ^2H-label to maximize our limit of detection. This approach permitted the analysis of multiple stable isotope labels within the same sample, enabling visualization of subcellular lipid microdomains within different cell types using a secondary label to mark the growing end of the cell. Using this technique, we demonstrate subcellular localization of hopanoid lipids within alpha-proteobacterial and cyanobacterial cells. Further, we provide evidence of hopanoid lipid domains in between cells of the filamentous cyanobacterium Nostoc punctiforme. More broadly, our method provides a means to image lipid microdomains in a wide range of cell types and test hypotheses for their functions in membranes

Neocarchean carbonate-associated sulfate records positive Δ^(33)S anomalies

Mass-independent fractionation of sulfur isotopes (reported as Δ^(33S) recorded in Archean sedimentary rocks helps to constrain the composition of Earth’s early atmosphere and the timing of the rise of oxygen ~2.4 billion years ago. Although current hypotheses predict uniformly negative Δ^(33)S for Archean seawater sulfate, this remains untested through the vast majority of Archean time.We applied x-ray absorption spectroscopy to investigate the low sulfate content of particularly well-preserved Neoarchean carbonates and mass spectrometry to measure their Δ^(33)S signatures. We report unexpected, large, widespread positive Δ^(33)S values from stratigraphic sections capturing over 70 million years and diverse depositional environments. Combined with the pyrite record, these results show that sulfate does not carry the expected negative Δ^(33)S from sulfur mass-independent fractionation in the Neoarchean atmosphere

Sub-wavelength focusing of high intensities in microfibre tips

Sub-wavelength efficient intensity confinement has been demonstrated in nanostructured optical microfibre tips. Focus Ion Beam (FIB) milling was used to nanostructure gold-coated optical microfibre tips and form apertures at the apex. Simulations were carried out to optimize the device design. Enhanced transmission efficiency (higher than 10-2) was achieved in spot sizes of ~λ/10. Nanostructured microfibre tips have the potential for a number of applications including optical recording, photolithography and scanning near-field optical microscopy (SNOM)