Extended x-ray absorption fine structure study of porous GaSb formed by ion implantation

Porous GaSb has been formed by Ga ion implantation into crystalline GaSb substrates at either room temperature or −180 °C. The morphology has been characterized using scanning electron microscopy and the atomic structure was determined using extended x-ray absorption fine structure spectroscopy. Room-temperature implantation at low fluences leads to the formation of ∼20-nm voids though the material remains crystalline. Higher fluences cause the microstructure to evolve into a network of amorphous GaSb rods ∼15 nm in diameter. In contrast, implantation at −180 °C generates large, elongated voids but no rods. Upon exposure to air, the surface of the porous material is readily oxidized yielding Ga₂O₃ and metallic Sb precipitates, the latter resulting from the reduction of unstable Sb₂O₃. We consider and discuss the atomic-scale mechanisms potentially operative during the concurrent crystalline-to-amorphous and continuous-to-porous transformations

Professional Development for Middle School Math and New Standards Curriculum: Current Experiences of Teachers and Administrators

In 2009, President Obama, in conjunction with the National Governors Association and the Council for Chief State School Officers, supported the federally adopted Common Core State Standards Agenda (Achieve.org, 2013). The purpose of this agenda was to increase standards for all students, with provisions for student achievement to be linked to teacher performance. The teacher performance connection created a need to better prepare teachers for the new standards curriculum. As teachers implemented the Common Core State Learning Standards for Mathematics (CCSLSM), they needed to develop a deep understanding of the new mathematical practices and skills. With the short timeline for implementing the Common Core State Learning Standards, effective professional development strategies needed to be thoughtfully planned. An understanding of best practices surrounding professional development for middle school mathematics teachers was essential. This qualitative study explored what professional development opportunities are most effective for implementing a new curriculum for middle school mathematics teachers. Data were collected and analyzed using three focus groups and a document review of professional development plans from selected school districts. Collectively, focus group participants shared their beliefs about what professional development opportunities and resources were available to support the implementation of the CCSLSM. The study resulted in recommendations based on themes that emerged from the focus groups for school districts, middle school math teachers, and policy makers to provide guidance on creating effective professional development opportunities aligned with Malcolm Knowles’s adult learning theory (1990)

Nanoscale density fluctuations in swift heavy ion irradiated amorphous SiO2

We report on the observation of nanoscale density fluctuations in 2 μm thick amorphous SiO₂ layers irradiated with 185 MeV Au ions. At high fluences, in excess of approximately 5 × 10¹² ions/cm², where the surface is completely covered by ion tracks, synchrotron small angle x-ray scattering measurements reveal the existence of a steady state of density fluctuations. In agreement with molecular dynamics simulations, this steady state is consistent with an ion track “annihilation” process, where high-density regions generated in the periphery of new tracks fill in low-density regions located at the center of existing tracks.The authors acknowledge the Australian Research Council and the Australian Synchrotron Research Program for financial support and thank the staff at the ANU Heavy Ion facility for their continued technical assistance. O.P., F.D., and K.N. acknowledge financial support from the Academy of Finland under its Centre of Excellence program as well as the OPNA project, and grants of computer capacity from CSC

Formation and structural characterization of Ni nanoparticles embedded in SiO₂

Face-centered cubic Ni nanoparticles were formed in SiO₂ by ion implantation and thermal annealing. Small-angle x-ray scattering in conjunction with transmission electron microscopy was used to determine the nanoparticle size as a function of annealing temperature, whereas the local atomic structure was measured with x-ray absorption spectroscopy. The influence of finite-size effects on the nanoparticle structural properties was readily apparent and included a decrease in coordination number and bond length and an increase in structural disorder for decreasing nanoparticle size. Such results are consistent with the non-negligible surface-to-volume ratio characteristic of nanoparticles. In addition, temperature-dependent x-ray absorption spectroscopy measurements showed the mean vibrational frequency (as obtained from the Einstein temperature) decreased with decreasing nanoparticle size. This reduction was attributed to the greater influence of the loosely bound, under-coordinated surface atoms prevailing over the effects of capillary pressure, the former enhancing the low frequency modes of the vibrational density of statesThis work was financially supported by the Australian Synchrotron and the Australian Research Council with access to equipment provided by the Australian Nanofabrication Facility

Nano-porosity in GaSb induced by swift heavy ion irradiation

Nano-porous structures form in GaSb after ion irradiation with 185 MeV Au ions. The porous layer formation is governed by the dominant electronic energy loss at this energy regime. The porous layer morphology differs significantly from that previously reported for low-energy, ion-irradiated GaSb. Prior to the onset of porosity, positron annihilation lifetime spectroscopy indicates the formation of small vacancy clusters in single ion impacts, while transmission electron microscopy reveals fragmentation of the GaSb into nanocrystallites embedded in an amorphous matrix. Following this fragmentation process, macroscopic porosity forms, presumably within the amorphous phase.The authors thank the Australian Research Council for support and the staff at the ANU Heavy Ion Accelerator Facility for their continued technical assistance. R.C.E. acknowledges the support from the Office of Basic Energy Sciences of the U.S. DOE (Grant No. DE-FG02-97ER45656)

Aspects of power corrections in hadron-hadron collisions

The program of understanding inverse-power law corrections to event shapes and energy flow observables in e+ e- annihilation to two jets and DIS (1+1) jets has been a significant success of QCD phenomenology over the last decade. The important extension of this program to similar observables in hadron collisions is not straightforward, being obscured by both conceptual and technical issues. In this paper we shed light on some of these issues by providing an estimate of power corrections to the inter-jet E_t flow distribution in hadron collisions using the techniques that were employed in the e+ e- annihilation and DIS cases.Comment: 15 pages, 1 figure, uses JHEP3.cl

The PTI1-like kinase ZmPti1a from maize (Zea mays L.) co-localizes with callose at the plasma membrane of pollen and facilitates a competitive advantage to the male gametophyte

BACKGROUND: The tomato kinase Pto confers resistance to bacterial speck disease caused by Pseudomonas syringae pv. tomato in a gene for gene manner. Upon recognition of specific avirulence factors the Pto kinase activates multiple signal transduction pathways culminating in induction of pathogen defense. The soluble cytoplasmic serine/threonine kinase Pti1 is one target of Pto phosphorylation and is involved in the hypersensitive response (HR) reaction. However, a clear role of Pti1 in plant pathogen resistance is uncertain. So far, no Pti1 homologues from monocotyledonous species have been studied. RESULTS: Here we report the identification and molecular analysis of four Pti1-like kinases from maize (ZmPti1a, -b, -c, -d). These kinase genes showed tissue-specific expression and their corresponding proteins were targeted to different cellular compartments. Sequence similarity, expression pattern and cellular localization of ZmPti1b suggested that this gene is a putative orthologue of Pti1 from tomato. In contrast, ZmPti1a was specifically expressed in pollen and sequestered to the plasma membrane, evidently owing to N-terminal modification by myristoylation and/or S-acylation. The ZmPti1a:GFP fusion protein was not evenly distributed at the pollen plasma membrane but accumulated as an annulus-like structure which co-localized with callose (1,3-β-glucan) deposition. In addition, co-localization of ZmPti1a and callose was observed during stages of pollen mitosis I and pollen tube germination. Maize plants in which ZmPti1a expression was silenced by RNA interference (RNAi) produced pollen with decreased competitive ability. Hence, our data provide evidence that ZmPti1a plays an important part in a signalling pathway that accelerates pollen performance and male fitness. CONCLUSION: ZmPti1a from maize is involved in pollen-specific processes during the progamic phase of reproduction, probably in crucial signalling processes associated with regions of callose deposition. Pollen-sporophyte interactions and pathogen induced HR show certain similarities. For example, HR has been shown to be associated with cell wall reinforcement through callose deposition. Hence, it is hypothesized that Pti1 kinases from maize act as general components in evolutionary conserved signalling processes associated with callose, however during different developmental programs and in different tissue types

Pt nanocrystals formed by ion implantation: a defect-mediated nucleation process

The influence of ion irradiation of SiO₂ on the size of metalnanocrystals (NCs) formed by ion implantation has been investigated. Thin SiO₂ films were irradiated with high-energy Ge ions then implanted with Pt ions. Without Geirradiation, the largest Pt NCs were observed beyond the Pt projected range. With irradiation, Ge-induced structural modification of the SiO₂ layer yielded a decrease in Pt NC size with increasing Ge fluence at such depths. A defect-mediated NC nucleation mechanism is proposed and a simple yet effective means of modifying and controlling the Pt NC size is demonstrated.The authors thank the Australian Research Council for financial support

Hyperpycnal wave-modified turbidites of the Pennsylvanian Minturn Formation, north-central Colorado

The Pennsylvanian Minturn Formation in north-central Colorado exhibits a complex stratigraphic architecture of fan-delta deposits that developed in association with high topographic relief in a tectonically active setting. The formation records a wide range of environments including alluvial fan, fluvial, deltaic, and open marine settings. This field trip will examine outcrops of a remarkable ~20 to 35-m-thick, unconformity-bound unit with turbidite-like beds that presumably developed within the lower reaches of incised valleys. This unit consists of dark green shale and graded sandstone beds with tool marks produced by abundant plant material. The sandstone event beds contain evidence for strong unidirectional flows and the variable influence of storm-generated waves. Proximal deposits contain beds with evidence for wave-dominated combined flows, including well developed, large-scale hummocky cross-stratification. Distal sections contain beds with reverse-to-normal grading and vertical successions of sedimentary structures that indicate long-lived waxing-to-waning unidirectional flows in conjunction with storm waves. We interpret these beds as a record of deposition from hyperpycnal flows, i.e., turbidity currents generated directly from highly concentrated river plumes, which waxed and waned in response to the rising and falling flood hydrograph. The focus of this trip will be the hydrodynamic interpretation of these different bed types, including their spatial and stratigraphic distribution