Electric field induced order reconstruction in a nematic cell

We have experimentally observed the biaxial switching between two topologically distinct textures of a nematic liquid crystal cell submitted to a strong electric field. The effect is deduced from optical and electrical measurements across the cell. Above a static threshold, a bulk order reconstruction is observed, where the final nematic orientation in the centre becomes perpendicular to its initial one, inducing a total π change of orientation across the cell. Using short electric field pulses, a higher dynamical threshold is observed. These experiments are explained by a Landau-de Gennes-Khalatnikov model. The threshold implies the local exchange of two eigenvalues of the nematic order tensor through intermediate biaxial states. The onset of the effect in a thin splay-bend wall decreases the static threshold by almost an order of magnitude. The model explains reasonably well the static and dynamic measurements within the present description of nematic biaxiality

Shape amphiphiles: mixing rods and disks in liquid crystals

Mixtures of rodlike and disklike liquid crystals suffer from phase separation. However, such mixtures can be homogenized if a molecule is added which comprises a rod- and a disklike fragment linked together covalently. We have termed such a molecule a shape amphiphile and believe that this represents a new class of amphiphilicity