Precision spectroscopy with two correlated atoms

We discuss techniques that allow for long coherence times in laser spectroscopy experiments with two trapped ions. We show that for this purpose not only entangled ions prepared in decoherence-free subspaces can be used but also a pair of ions that are not entangled but subject to the same kind of phase noise. We apply this technique to a measurement of the electric quadrupole moment of the 3d D5/2 state of 40Ca+ and to a measurement of the linewidth of an ultrastable laser exciting a pair of 40Ca+ ions

Nonlinear coupling of continuous variables at the single quantum level

We experimentally investigate nonlinear couplings between vibrational modes of strings of cold ions stored in linear ion traps. The nonlinearity is caused by the ions' Coulomb interaction and gives rise to a Kerr-type interaction Hamiltonian H = n_r*n_s, where n_r,n_s are phonon number operators of two interacting vibrational modes. We precisely measure the resulting oscillation frequency shift and observe a collapse and revival of the contrast in a Ramsey experiment. Implications for ion trap experiments aiming at high-fidelity quantum gate operations are discussed

Generalized spin squeezing inequalities in NN qubit systems: theory and experiment

We present detailed derivations, various improvements and application to concrete experimental data of spin squeezing inequalities formulated recently by some of us [Phys. Rev. Lett. {\bf 95}, 120502 (2005)]. These inequalities generalize the concept of the spin squeezing parameter, and provide necessary and sufficient conditions for genuine 2-, or 3- qubit entanglement for symmetric states, and sufficient entanglement condition for general $N$-qubit states. We apply our method to theoretical study of Dicke states, and, in particular, to $W$-states of $N$ qubits. Then, we analyze the recently experimentally generated 7- and 8-ion $W$-states [Nature {\bf 438}, 643 (2005)]. We also present some novel details concerning this experiment. Finally, we improve criteria for detection of genuine tripartite entanglement based on entanglement witnesses.Comment: Final versio

Continuous loading of a non-dissipative atom trap

We study theoretically a scheme in which particles from an incident beam are trapped in a potential well when colliding with particles already present in the well. The balance between the arrival of new particles and the evaporation of particles from the trapped cloud leads to a steady-state that we characterize in terms of particle number and temperature. For a cigar shaped potential, different longitudinal and transverse evaporation thresholds can be chosen. We show that a resonance occur when the transverse evaporation threshold coincides with the energy of the incident particles. It leads to a dramatic increase in phase space density with respect to the incident beam.Comment: 7 pages, 2 figure

'Designer atoms' for quantum metrology

Entanglement is recognized as a key resource for quantum computation and quantum cryptography. For quantum metrology, the use of entangled states has been discussed and demonstrated as a means of improving the signal-to-noise ratio. In addition, entangled states have been used in experiments for efficient quantum state detection and for the measurement of scattering lengths. In quantum information processing, manipulation of individual quantum bits allows for the tailored design of specific states that are insensitive to the detrimental influences of an environment. Such 'decoherence-free subspaces' protect quantum information and yield significantly enhanced coherence times. Here we use a decoherence-free subspace with specifically designed entangled states to demonstrate precision spectroscopy of a pair of trapped Ca+ ions; we obtain the electric quadrupole moment, which is of use for frequency standard applications. We find that entangled states are not only useful for enhancing the signal-to-noise ratio in frequency measurements - a suitably designed pair of atoms also allows clock measurements in the presence of strong technical noise. Our technique makes explicit use of non-locality as an entanglement property and provides an approach for 'designed' quantum metrology

Computation of conical intersections by using perturbation techniques

Multiconfigurational second-order perturbation theory, both in its single-state multiconfigurational second-order perturbation theory (CASPT2) and multistate (MS-CASPT2) formulations, is used to search for minima on the crossing seams between different potential energy hypersurfaces of electronic states in several molecular systems. The performance of the procedures is tested and discussed, focusing on the problem of the nonorthogonality of the single-state perturbative solutions. In different cases the obtained structures and energy differences are compared with available complete active space self-consistent field and multireference configuration interaction solutions. Calculations on different state crossings in LiF, formaldehyde, the ethene dimer, and the penta-2,4-dieniminium cation illustrate the discussions. Practical procedures to validate the CASPT2 solutions in polyatomic systems are explored, while it is shown that the application of the MS-CASPT2 procedure is not straightforward and requires a careful analysis of the stability of the results with the quality of the reference wave functions, that is, the size of the active [email protected] [email protected] [email protected]

Robust entanglement

It is common belief among physicists that entangled states of quantum systems loose their coherence rather quickly. The reason is that any interaction with the environment which distinguishes between the entangled sub-systems collapses the quantum state. Here we investigate entangled states of two trapped Ca$^+$ ions and observe robust entanglement lasting for more than 20 seconds