A novel drifter designed for use with a mounted Acoustic Doppler Current Profiler in shallow environments

We present a novel design for a surface drifter, mounted with a pulse-coherent Acoustic Doppler Current Profiler (ADCP) for measuring near-surface (depths 0.18-1 m) flows. During repeated drifter deployments over the tidal flats of Skagit Bay, the mounted ADCP recorded high quality and high resolution profiles of velocity in depths as shallow as 0.4 m. Depth-dependent velocities revealed regions of vertically sheared currents and wave motions not resolved by surface drifters alone. Although the cost of ADCPs is substantial, the drifter bodies were low cost, robust, and of simple construction

Lagrangian measurements of turbulent dissipation over a shallow tidal flat from pulse coherent Acoustic Doppler Profilers

We present high resolution (25 mm spatial, 8 Hz temporal) profiles of velocity measured over a shallow tidal flat using pulse-coherent Acoustic Doppler Profilers mounted on surface drifters. The use of Lagrangian measurements mitigated the problem of resolving velocity ambiguities, a problem which often limits the application of high-resolution pulse-coherent profilers. Turbulent dissipation rates were estimated from second-order structure functions of measured velocity. Drifters were advected towards, and subsequently trapped on, a convergent surface front which marked the edge of a freshwater plume. Measured dissipation rates increased as a drifter deployed within the plume approached the front. A drifter then propagated with and along the front as the fresh plume spread across the tidal flats. Near-surface turbulent dissipation measured at the front roughly matched a theoretical mean-shear-cubed relationship, whereas dissipation measured in the stratified plume behind the front was suppressed. After removal of estimates affected by surface waves, near-bed dissipation matched the velocity cubed relationship, although scatter was substantial. Dissipation rates appeared to be enhanced when the drifter propagated across small subtidal channels

A Lifecourse Approach to Long-Term Sickness Absence-A Cohort Study

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited

Hartree-Fock symmetry breaking around conical intersections

We study the behavior of Hartree-Fock (HF) solutions in the vicinity of conical intersections. These are here understood as regions of a molecular potential energy surface characterized by degenerate or nearly-degenerate eigenfunctions with identical quantum numbers (point group, spin, and electron number). Accidental degeneracies between states with different quantum numbers are known to induce symmetry breaking in HF. The most common closed-shell restricted HF instability is related to singlet-triplet spin degeneracies that lead to collinear unrestricted HF (UHF) solutions. Adding geometric frustration to the mix usually results in noncollinear generalized HF (GHF) solutions, identified by orbitals that are linear combinations of up and down spins. Near conical intersections, we observe the appearance of coplanar GHF solutions that break all symmetries, including complex conjugation and time-reversal, which do not carry good quantum numbers. We discuss several prototypical examples taken from the conical intersection literature. Additionally, we utilize a recently introduced a magnetization diagnostic to characterize these solutions, as well as a solution of a Jahn-Teller active geometry of H$_8^{+2}$.Comment: accepted to JCP December 2017, published online January 201

Reliable and robust molecular sexing of the hen harrier (Circus cyaneus) using PCR-RFLP of the CHD1 gene

The hen harrier (Circus cyaneus) is a bird of prey that is persecuted in the United Kingdom, and there is a need for a DNA-based individual identification and sexing system for the use in forensic investigations. This study reports a new set of PCR primers for the chromo-helicase-DNA-binding protein 1 gene, which allows sexing using PCR-RFLP. Instead of exonic primers that amplify across a large intron, this set consists of a primer within the intron, enabling reduction in amplicon sizes from 356 to 212 bp and 565 to 219 bp in W and Z chromosomes. DNA degradation and dilution experiments demonstrate that this set is significantly more robust than one that amplifies across the intron, and sequencing of the intronic primer-binding region across several individuals shows that it is highly conserved. While our objective is to incorporate this primer set into an STR-based individualization kit, it may in the meantime prove useful in forensic or conservation studies

Determination of complex absorbing potentials from the electron self-energy

The electronic conductance of a molecule making contact to electrodes is determined by the coupling of discrete molecular states to the continuum electrode density of states. Interactions between bound states and continua can be modeled exactly by using the (energy-dependent) self-energy, or approximately by using a complex potential. We discuss the relation between the two approaches and give a prescription for using the self-energy to construct an energy-independent, non-local, complex potential. We apply our scheme to studying single-electron transmission in an atomic chain, obtaining excellent agreement with the exact result. Our approach allows us to treat electron-reservoir couplings independent of single electron energies, allowing for the definition of a one-body operator suitable for inclusion into correlated electron transport calculations.Comment: 11 pages, 8 figures; to be published in the J. Chem. Phy

On the Assouad dimension of self-similar sets with overlaps

It is known that, unlike the Hausdorff dimension, the Assouad dimension of a self-similar set can exceed the similarity dimension if there are overlaps in the construction. Our main result is the following precise dichotomy for self-similar sets in the line: either the \emph{weak separation property} is satisfied, in which case the Hausdorff and Assouad dimensions coincide; or the \emph{weak separation property} is not satisfied, in which case the Assouad dimension is maximal (equal to one). In the first case we prove that the self-similar set is Ahlfors regular, and in the second case we use the fact that if the \emph{weak separation property} is not satisfied, one can approximate the identity arbitrarily well in the group generated by the similarity mappings, and this allows us to build a \emph{weak tangent} that contains an interval. We also obtain results in higher dimensions and provide illustrative examples showing that the `equality/maximal' dichotomy does not extend to this setting.Comment: 24 pages, 2 figure

High-Frequency Microstrip Cross Resonators for Circular Polarization EPR Spectroscopy

In this article we discuss the design and implementation of a novel microstrip resonator which allows for the absolute control of the microwaves polarization degree for frequencies up to 30 GHz. The sensor is composed of two half-wavelength microstrip line resonators, designed to match the 50 Ohms impedance of the lines on a high dielectric constant GaAs substrate. The line resonators cross each other perpendicularly through their centers, forming a cross. Microstrip feed lines are coupled through small gaps to three arms of the cross to connect the resonator to the excitation ports. The control of the relative magnitude and phase between the two microwave stimuli at the input ports of each line allows for tuning the degree and type of polarization of the microwave excitation at the center of the cross resonator. The third (output) port is used to measure the transmitted signal, which is crucial to work at low temperatures, where reflections along lengthy coaxial lines mask the signal reflected by the resonator. EPR spectra recorded at low temperature in an S= 5/2 molecular magnet system show that 82%-fidelity circular polarization of the microwaves is achieved over the central area of the resonator.Comment: Published in Review of Scientific Instrument