2,021 research outputs found
One-step synthesis of pyridines and dihydropyridines in a continuous flow microwave reactor
The BohlmannâRahtz pyridine synthesis and the Hantzsch dihydropyridine synthesis can be carried out in a microwave flow reactor or using a conductive heating flow platform for the continuous processing of material. In the BohlmannâRahtz reaction, the use of a Brønsted acid catalyst allows Michael addition and cyclodehydration to be carried out in a single step without isolation of intermediates to give the corresponding trisubstituted pyridine as a single regioisomer in good yield. Furthermore, 3-substituted propargyl aldehydes undergo Hantzsch dihydropyridine synthesis in preference to BohlmannâRahtz reaction in a very high yielding process that is readily transferred to continuous flow processing
Workâlife balance and the needs of female employees in the telecommunications industry in a developing country: A critical realist approach to issues in industrial and organizational social psychology
Finding a balance between the demands of the role requirements of work, family, and social life is a challenging problem for modern society and is particularly relevant for the growth of womenâs participation in the workforce. These role conflicts may result in significant psychological stress for individuals. For corporations, stressed employees are also a problem. Workâ life balance (WLB) programs to address these issues have emerged in Western countries in the past three decades and have been evaluated in various ways in multidisciplinary studies which have employed sociological and psychological methodologies. WLB programs in developed countries often reflect the ethos of particular cultures, and Western models may not be wholly relevant for cross-cultural comparison. The present study explores these issues using the methodology of critical realism in companies in the telecommunications sector of Palestine. This qualitative study develops a complex model of a newly identified set of factors, which may be relevant for other Arabic cultural settings. Further exploration of this model using psychometric techniques is proposed
Margaret Archer (1943-2023) on Critical Realism and Morphogenesis: Linking Critical Realist Research Models from East and West
Critical Realism (CR) is a philosophical approach to social science research, social action, and social change activism. It provides a framework for social scientists whose value commitments leads them to view the construction of social phenomenon in critical ways, which identify the often hidden oppressive elements in social structures. This understanding of a ânewâ reality underlies the advocacy of change strategies, and the initiation of dialogue between members of disadvantaged and oppressed groups through the process of âmorphogenesisâ Â This model of dialogues enabling change and the âunmasking of alienationâ stem from the work of Roy Bhaskar, and has been developed by Margaret Archer and other European scholars. An important feature of CR has been the application by the emergence of shared understanding, by social scientists from different value traditions (e.g. Christianity, Secular Humanism, and Islam). The JOCRISE in taking CR understandings of oppressive social forces into new fields, and with fresh CR models, is welcomed. In appraising the new model from JOCRISE, we offer both Cartesian dualism, and Popperâs World 3 model as elements of a new, dynamic focus on social change advocacy
Consumptive Use and Water Requirements for Utah
Foreword: Studies on the meteorological determinants of evapotranspiration were initiated at least as long ago as the 1920s and by the late 1940s had produced the Blaney-Criddle method for estimating crop consumptive use. The resulting ability to estimate water requirements by both location and crop added a new scientific dimension to water rights administration that was first introduced into the courts of Utah during adjudication of water rights in the Escalante Valley in 1949. Application of the consumptive use concept to water rights administration and water resources planning, however, required a wirtten reference. Technical Publication No. 8 entitled Consumptive Use of Water and Irrigation Requirements of Crops in Utah was published by the State Engineer in 1952. By 1962, methods had been developed for going beyond agriculture to estimate water requirements for municipal, industrial, and recreational uses. Technical Publication No. 8 was revised and published under the title Consumptive Use and Water Requirements for Utah. Continuing advancements in water requirements estimation have occurred over the last 20 years. The present revision, Technical Publication No. 75, updates estimatino of agricultural, municipal, recreational, and industrial water uses. It presents an isogram of potential consumptive use that permits the determination of crop water requirements at any point within the state
Woman and management: a conceptual review, with a focus on Muslim Women in management roles in Western and in Muslim-Majority countries
We consider the roles of Muslim women managers, executives and professionals in three ways: as women qua women; as women of the Muslim diaspora in Western countries; and as women in Muslim Majority Cultures (MMCs). In reviewing the literature on the âglass ceilingâ which prevents women achieving parity with men in middle and senior management roles, we are impressed by the work of Helgeson and Johnson on the special qualities of women in management roles, and compare their social psychological model with accounts of âstrongâ Muslim women who, drawing on Islamic traditions have performed many leadership roles outside of the traditional family. Nevertheless, it is Muslim womenâs strength as strong family managers, with men being supporters rather than leaders of such family roles, which we generalise in describing an ideal model of a Muslim women manager. We draw too on traditional Islamic models in describing the kind of capitalist enterprise which may thrive in MMCs, and in which women will play leading roles. Nevertheless, we observe that in many MMCs non-Muslim (but strong) traditions of patriarchy often prevail, and subvert womenâs search for higher education and leadership roles
Personality, work-life balance, hardiness, and vocation: a typology of nurses and nursing values in a special sample of English hospital nurses
This initial report of a longitudinal study of 192 English hospital nurses measured Nursing Values (the 6Cs of nursing); Personality, Self-Esteem and Depression; Burnout Potential; Work-Life Balance Stress; âHardy Personalityâ; and Intention to Leave Nursing. Correlational, component, and cluster analysis identiďŹed four groups: âThe Soldiersâ (N = 79), with medium scores on most measures, who bravely âsoldier onâ in their nursing roles, in the face of numerous ďŹnancial cuts to the National Health Service, and worsening nurseâpatient ratios; âCheerful Professionalsâ (N = 54), copingsuccessfullywithnursingroles,andavarietyofchallenges,inupwardlymobilecareers;âHigh Achieversâ (N = 39), senior nurses with strong proďŹles of a âhardy personalityâ, and commitment to fundamental nursing values; and âHighly Stressed, Potential Leaversâ (N = 20), with indicators of signiďŹcant psychological distress, and difďŹculty in coping with nursing role challenges. We have initiated a program of co-counselling and social support for this distressed group, by nurses who are coping more successfully with multiple challenges. We discuss the role of nurse educators in fostering nursing values, developing and supporting a âhardy personalityâ and emotional resilience in recruits to nursing
Retarding Sub- and Accelerating Super-Diffusion Governed by Distributed Order Fractional Diffusion Equations
We propose diffusion-like equations with time and space fractional
derivatives of the distributed order for the kinetic description of anomalous
diffusion and relaxation phenomena, whose diffusion exponent varies with time
and which, correspondingly, can not be viewed as self-affine random processes
possessing a unique Hurst exponent. We prove the positivity of the solutions of
the proposed equations and establish the relation to the Continuous Time Random
Walk theory. We show that the distributed order time fractional diffusion
equation describes the sub-diffusion random process which is subordinated to
the Wiener process and whose diffusion exponent diminishes in time (retarding
sub-diffusion) leading to superslow diffusion, for which the square
displacement grows logarithmically in time. We also demonstrate that the
distributed order space fractional diffusion equation describes super-diffusion
phenomena when the diffusion exponent grows in time (accelerating
super-diffusion).Comment: 11 pages, LaTe
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