Theory of site-disordered magnets

In realistic spinglasses, such as CuMn, AuFe and EuSrS, magnetic atoms are located at random positions. Their couplings are determined by their relative positions. For such systems a field theory is formulated. In certain limits it reduces to the Hopfield model, the Sherrington-Kirkpatrick model, and the Viana-Bray model. The model has a percolation transition, while for RKKY couplings the ``concentration scaling'' T_g proportional to c occurs. Within the Gaussian approximation the Ginzburg-Landau expansion is considered in the clusterglass phase, that is to say, for not too small concentrations. Near special points, the prefactor of the cubic term, or the one of the replica-symmetry- breaking quartic term, may go through zero. Around such points new spin glass phases are found.Comment: 26 pages Revtex, 6 figure

Chemical and morphological evolution of PA-6/Epm/Epm-g-MA blends in a twin screw extruder

Chemical conversion and morphological evolution of PA-6/EPM/EPM-g-MA blends along a twin screw extruder were monitored by quickly collecting small samples from the melt at specific barrel locations. The results show that the MA content of all blends decreases drastically in the first zone of the extruder, i.e., upon melting of the blend components. Significant changes in morphology are also observed at this stage. A correlation between chemistry and morphology could thus be established.- (undefined

Thermal decomposition of RDX from reactive molecular dynamics

We use the recently developed reactive force field ReaxFF with molecular dynamics to study thermal induced chemistry in RDX [cyclic-[CH2N(NO2)]3] at various temperatures and densities. We find that the time evolution of the potential energy can be described reasonably well with a single exponential function from which we obtain an overall characteristic time of decomposition that increases with decreasing density and shows an Arrhenius temperature dependence. These characteristic timescales are in reasonable quantitative agreement with experimental measurements in a similar energetic material, HMX [cyclic-[CH2N(NO2)]4]. Our simulations show that the equilibrium population of CO and CO2 (as well as their time evolution) depend strongly of density: at low density almost all carbon atoms form CO molecules; as the density increases larger aggregates of carbon appear leading to a C deficient gas phase and the appearance of CO2 molecules. The equilibrium populations of N2 and H2O are more insensitive with respect to density and form in the early stages of the decomposition process with similar timescales

Ginzburg-Landau theory of the cluster glass phase

On the basis of a recent field theory for site-disordered spin glasses a Ginzburg-Landau free energy is proposed to describe the low temperatures glassy phase(s) of site-disordered magnets. The prefactors of the cubic and dominant quartic terms change gradually along the transition line in the concentration-temperature phase diagram. Either of them may vanish at certain points $(c_*, T_*)$, where new transition lines originate. The new phases are classifiedComment: 6 pages Revtex, 5 figures. To appear in J. Phys. A. Let

Psychoeducation for hypochondriasis:A comparison of a cognitive-behavioural approach and a problem-solving approach

In this study, two 6-week psychoeducational courses for hypochondriasis are compared, one based on the cognitive-behavioural approach, and the other on the problem-solving approach. Effects of both courses on hypochondriacal complaints, depression, trait anxiety, and number of problems encountered in daily life, are measured pre-treatment, posttreatment, and at 1- and 6-month follow-up. Participants (N = 48, of whom 4 dropped out), suffering from DSM-IV hypochondriasis, were randomized into one of the two course conditions. Results showed beneficial effects of both courses. Few differential treatment effects were found: in both conditions all effect measures decreased significantly over time (p <0.01). However, between- and inter-individual variability in decrease-patterns was of considerable size, leading to large deviations from the mean pattern. Acceptability and feasibility of both courses were rated highly by their respective participants. It is concluded that both courses can be considered equally beneficial and effective over time, with the effects evident immediately after treatment and maintained over the follow-up period. (c) 2006 Elsevier Ltd. All rights reserved

Energetic Materials at High Compression: First-Principles Density Functional Theory and Reactive Force Field Studies

We report the results of a comparative study of pentaerythritol tetranitrate (PETN) at high compression using classical reactive interatomic potential ReaxFF and first-principles density functional theory (DFT). Lattice parameters of PETN I, the ground state structure at ambient conditions, is obtained by ReaxFF and two different density functional methods (plane wave and LCAO pseudopotential methods) and compared with experiment. Calculated energetics and isothermal equation of state (EOS) upon hydrostatic compression obtained by DFT and ReaxFF are both in good agreement with available experimental data. Our calculations of the hydrostatic EOS at zero temperature are extended to high pressures up to 50 GPa. The anisotropic characteristics of PETN upon uniaxial compression were also calculated by both ReaxFF and DFT

Quantum-chemical calculations of dye-sensitized semiconductor nanocrystals

Quantum chemical calculations providing detailed information of dye-sensitized semiconductor nanocrystals are presented. The calculations are used to elucidate both structural and electronic properties of photoelectrochemical devices, such as environmentally friendly Dye-Sensitized Solar Cells (DSSCs), at the molecular level. Quantum chemical calculations have recently been performed on both organic and organometallic dye molecules attached to titanium dioxide (TiO2) nanocrystals via different anchor and spacer groups. Strategies to make accurate quantum chemical calculations, e.g. at the DFT level of theory, on increasingly realistic models of such dye-sensitized semiconductor interfaces are presented. The ability of different anchor and spacer groups to act as mediators of ultrafast photo-induced electron injection from the dye molecules into the semiconductor nanocrystals is, in particular, discussed in terms of calculated electronic coupling strengths, and direct comparisons with experimental information are made whenever possible. Progress in the development of multi-scale simulation techniques using so called reactive force fields is illustrated for dye-sensitized solar cell systems

Zilte landbouw Texel : een voorbeeld transitieproject 2006-2010 : eindrapport

Het project Zilte Landbouw Texel is in mei 2006 van start gegaan op het perceel nabij ‘De Petten’ op Texel. Er is gekozen om een Zilte Proeftuin aan te leggen op een nabij gelegen perceel waar gedurende twee jaar ongeveer twintig verschillende potentiële zilte gewassen zijn onderzocht op hun groei onder zoute condities en hun marktpotentie. De focus van de werkzaamheden op Texel van de Vrije Universiteit Amsterdam was gericht op Zeekool, Strandbiet, Hertshoornweegbree, Monniksbaard, Reukloze kamille en Wilde Rucola. Daarnaast heeft een langdurig onderzoek plaatsgevonden op de Afsluitdijk wat als referentie heeft gediend voor de natuurlijke groei van halofieten. In de kassen van VU zijn meerdere groei-experimenten onder gecontroleerde omstandigheden uitgevoerd, welke gebruikt zijn om de teelt van de verschillende gewassen op Texel verder te ontwikkelen. De teelt van vooral Zeekool, Zilte Rucola en Strandbiet is met succes opgeschaald en de producten zijn afgezet op de (lokale) markt. Door onder andere de promotie via verschillende kanalen en de unieke smaak van de zilte groenten is een vraag ontstaan naar de zilte gewassen die in veel gevallen het aanbod overtrof