Integrated waveguide and nanostructured sensor platform for surface-enhanced Raman spectroscopy

Limitations of current sensors include large dimensions, sometimes limited sensitivity and inherent single-parameter measurement capability. Surface-enhanced Raman spectroscopy can be utilized for environment and pharmaceutical applications with the intensity of the Raman scattering enhanced by a factor of 106. By fabricating and characterizing an integrated optical waveguide beneath a nanostructured precious metal coated surface a new surface-enhanced Raman spectroscopy sensing arrangement can be achieved. Nanostructured sensors can provide both multiparameter and high-resolution sensing. Using the slab waveguide core to interrogate the nanostructures at the base allows for the emission to reach discrete sensing areas effectively and should provide ideal parameters for maximum Raman interactions. Thin slab waveguide films of silicon oxynitride were etched and gold coated to create localized nanostructured sensing areas of various pitch, diameter, and shape. These were interrogated using a Ti:Sapphire laser tuned to 785-nm end coupled into the slab waveguide. The nanostructured sensors vertically projected a Raman signal, which was used to actively detect a thin layer of benzyl mercaptan attached to the sensors

Performance of three-photon PET imaging: Monte Carlo simulations

We have recently introduced the idea of making use of three-photon positron annihilations in positron emission tomography. In this paper the basic characteristics of the three-gamma imaging in PET are studied by means of Monte Carlo simulations and analytical computations. Two typical configurations of human and small animal scanners are considered. Three-photon imaging requires high energy resolution detectors. Parameters currently attainable by CdZnTe semiconductor detectors, the technology of choice for the future development of radiation imaging, are assumed. Spatial resolution is calculated as a function of detector energy resolution and size, position in the field of view, scanner size, and the energies of the three gamma annihilation photons. Possible ways to improve the spatial resolution obtained for nominal parameters: 1.5 cm and 3.2 mm FWHM for human and small animal scanners, respectively, are indicated. Counting rates of true and random three-photon events for typical human and small animal scanning configurations are assessed. A simple formula for minimum size of lesions detectable in the three-gamma based images is derived. Depending on the contrast and total number of registered counts, lesions of a few mm size for human and sub mm for small animal scanners can be detected

Numerical analysis of suction embedded plate anchors in structured clay

As offshore energy developments move towards deeper water, moored floating production facilities are increasingly preferred to fixed structures. Anchoring systems are therefore of great interest to engineers working on deep water developments. Suction embedded plate anchors (SEPLAs) are rapidly becoming a popular solution, possessing a more accurate and predictable installation process compared to traditional alternatives. In this paper, finite element analysis has been conducted to evaluate the ultimate pullout capacity of SEPLAs in a range of post-keying configurations. Previous numerical studies of anchor pullout capacity have generally treated the soil as an elastic-perfectly plastic medium. However, the mechanical behaviour of natural clays is affected by inter-particle bonding, or structure, which cannot be accounted for using simple elasto-plastic models. Here, an advanced constitutive model formulated within the kinematic hardening framework is used to accurately predict the degradation of structure as an anchor embedded in a natural soft clay deposit is loaded to its pullout capacity. In comparison with an idealised, non-softening clay, the degradation of clay structure due to plastic strains in the soil mass results in a lower pullout capacity factor, a quantity commonly used in design, and a more complex load–displacement relationship. It can be concluded that clay structure has an important effect on the pullout behaviour of plate anchors.Peer ReviewedPostprint (author's final draft

Competition between Pressure and Gravity Confinement in Lyman-Alpha Forest Observations

A break in the distribution function of Ly$\alpha$ clouds (at a typical redshift of $2.5$) has been reported by Petitjean et al. (1993). This feature is what would be expected from a transition between pressure confinement and gravity confinement (as predicted in Charlton, Salpeter, and Hogan (1993)). The column density at which the feature occurs has been used to determine the external confining pressure, $\sim 10 {\rm cm}^{-3} {\rm K}$, which could be due to a hot, intergalactic medium. For models that provide a good fit to the data, the contribution of the gas in clouds to $\Omega$ is small. The specific shape of the distribution function at the transition (predicted by models to have a non-monotonic slope) can serve as a diagnostic of the distribution of dark matter around Ly$\alpha$ forest clouds, and the present data already eliminate certain models.Comment: 10 pages plain TeX, 2 figures available upon request, submitted to ApJ Letters, PSU-jc-