1,472 research outputs found
Anomalous expansion and phonon damping due to the Co spin-state transition in RCoO_3 with R = La, Pr, Nd and Eu
We present a combined study of the thermal expansion and the thermal
conductivity of the perovskite series RCoO_3 with R = La, Nd, Pr and Eu. The
well-known spin-state transition in LaCoO_3 is strongly affected by the
exchange of the R ions due to their different ionic radii, i.e. chemical
pressure. This can be monitored in detail by measurements of the thermal
expansion, which is a highly sensitive probe for detecting spin-state
transitions. The Co ions in the higher spin state act as additional scattering
centers for phonons, therefore suppressing the phonon thermal conductivity.
Based on the analysis of the interplay between spin-state transition and heat
transport, we present a quantitative model of the thermal conductivity for the
entire series. In PrCoO_3, an additional scattering effect is active at low
temperatures. This effect arises from the crystal field splitting of the 4f
multiplet, which allows for resonant scattering of phonons between the various
4f levels.Comment: 15 pages including 5 figure
Spin-State Transition and Metal-Insulator Transition in LaEuCoO}
We present a study of the structure, the electric resistivity, the magnetic
susceptibility, and the thermal expansion of LaEuCoO. LaCoO
shows a temperature-induced spin-state transition around 100 K and a
metal-insulator transition around 500 K. Partial substitution of La by
the smaller Eu causes chemical pressure and leads to a drastic increase
of the spin gap from about 190 K in LaCoO to about 2000 K in EuCoO, so
that the spin-state transition is shifted to much higher temperatures. A
combined analysis of thermal expansion and susceptibility gives evidence that
the spin-state transition has to be attributed to a population of an
intermediate-spin state with orbital order for and without orbital
order for larger . In contrast to the spin-state transition, the
metal-insulator transition is shifted only moderately to higher temperatures
with increasing Eu content, showing that the metal-insulator transition occurs
independently from the spin-state distribution of the Co ions. Around
the metal-insulator transition the magnetic susceptibility shows a similar
increase for all and approaches a doping-independent value around 1000 K
indicating that well above the metal-insulator transition the same spin state
is approached for all .Comment: 10 pages, 6 figure
Analysis of residual content of used syringes collected from low threshold facilities in Lausanne, Switzerland.
For the first time in Switzerland, an analysis of residual contents from used syringes collected from low threshold facilities was performed. This preliminary study is part of a wider project aiming to understand patterns of injecting drug use over time.
Among the 100,000 syringes exchanged annually by the ABS foundation (Accueil Bas Seuil), 113 were collected following a purposive sampling method and analysed by gas chromatography coupled with mass spectrometry (GC-MS).
Four syringes (4% of the sample population) contained no substances take into consideration the limit of the method. Cocaine was the most commonly observed compound and was detected in 77 syringes (68%), whilst users reported syringes with cocaine among those analysed in this study. Heroin was detected in 49 syringes (43%) and reported by 53 users returning syringes; midazolam was detected in 31 syringes (27%) and reported as the medicine Dormicum(®) in 22 occurrences. No new or unusual illicit drug was detected in the sample.
The results show the presence of cocaine in more than half of the sample, an absence of new or unusual illicit drugs, as well as very few traces of methadone, which suggests that this substitution drug is rarely injected. This preliminary study also demonstrates the potential of this developed methodology for monitoring purposes. An ongoing and more systematic approach could allow to detect modifications in drug use patterns among the target population as well as the appearance of new and hazardous substances. Such systematic and timely results could allow an adaptation of harm reduction interventions
Evidence for orbital ordering in LaCoO3
We present powder and single crystal X-ray diffraction data as evidence for a
monoclinic distortion in the low spin (S=0) and intermediate spin state (S=1)
of LaCoO3. The alternation of short and long bonds in the ab plane indicates
the presence of eg orbital ordering induced by a cooperative Jahn-Teller
distortion. We observe an increase of the Jahn-Teller distortion with
temperature in agreement with a thermally activated behavior of the Co3+ ions
from a low-spin ground state to an intermediate-spin excited state.Comment: Accepted to Phys. Rev.
Looking at Vector Space and Language Models for IR using Density Matrices
In this work, we conduct a joint analysis of both Vector Space and Language
Models for IR using the mathematical framework of Quantum Theory. We shed light
on how both models allocate the space of density matrices. A density matrix is
shown to be a general representational tool capable of leveraging capabilities
of both VSM and LM representations thus paving the way for a new generation of
retrieval models. We analyze the possible implications suggested by our
findings.Comment: In Proceedings of Quantum Interaction 201
Structural and chemical investigations of adapted Siemens feed rods for an optimized float zone process
The optimization of the float zone process for industrial application is a promising way to crystallize high purity silicon for high efficiency solar cells with reduced process costs. We investigated two differently produced Siemens rods which should be used as feed material for the float zone process. The aim is to identify and to improve material properties of the feed rods which have a high impact to the float zone process. We show here microstructural and chemical analysis comparing feed rods manufactured under standard conditions and under float zone adapted conditions. To resolve the growth behavior of the grains SEM/EBSD mappings are performed at different positions. TEM analyses are used to investigate the interface region between the mono- and the multicrystalline silicon within the Siemens feed rod. Additionally, drilled cores are cut out from the feed rods containing the region of the slim rod. Afterwards, the drilled cores are crystallized with the float zone process. Finally, carbon and oxygen measurements with FT-IR spectrometry on different positions of the crystallized drilled cores of the Siemens feed rods show the influence of the slim rod material to the float zone process
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Influence of slim rod material properties to the Siemens feed rod and the float zone process
The identification and understanding of material properties influencing the float zone process is important to crystallize high purity silicon for high efficiency solar cells. Also the knowledge of minimal requirements to crystallize monocrystalline silicon with the float zone process is of interest from an economic point of view. In the present study, feed rods for the float zone process composed of a central slim rod and the deposited silicon from the Siemens process are investigated. Previous studies have shown that the slim rod has a significant impact on the purity and suitability for further crystallization processes. In particular, contaminations like substitutional carbon and the presence of precipitates as well as the formation of oxide layers play an important role and are investigated in detail. For this purpose different slim rod materials were used in deposition and float zone crystallization experiments. Samples were prepared by cross sectioning and core drilling of Siemens rods, which were recrystallized with the float zone process. Recrystallized drilled cores are analyzed with FT-IR spectrometry concerning the carbon and oxygen content. To estimate the grain growth behavior on the slim rod surface in dependence of the used slim rod material, EBSD mappings inside a SEM are performed on squared and circular slim rods. TEM analysis was used to investigate the presence of an oxide layer at the interface between slim rod and deposited polycrystalline silicon. Additionally the influence of a nitrogen-containing gas atmosphere during the slim rod pulling is investigated by IR microscopy and ToF-SIMS regarding Si3N4 precipitation
Specific heat and magnetization study on single crystals of a frustrated, quasi one-dimensional oxide: Ca3Co2O6
Specific heat and magnetization measurements have been carried out under a
range of magnetic fields on single crystals of Ca3Co2O6. This compound is
composed of Ising magnetic chains that are arranged on a triangular lattice.
The intrachain and interchain couplings are ferromagnetic and
antiferromagnetic, respectively. This situation gives rise to geometrical
frustration, that bears some similarity to the classical problem of a
two-dimensional Ising triangular antiferromagnet. This paper reports on the
ordering process at low-T and the possibility of one-dimensional features at
high-T.Comment: 7 pages, 6 figures, accepted for publication in PR
Evidence for a Low-Spin to Intermediate-Spin State Transition in LaCoO3
We present measurements of the magnetic susceptibility and of the thermal
expansion of a LaCoO single crystal. Both quantities show a strongly
anomalous temperature dependence. Our data are consistently described in terms
of a spin-state transition of the Co ions with increasing temperature
from a low-spin ground state to an intermediate-spin state without (100K -
500K) and with (>500K) orbital degeneracy. We attribute the lack of orbital
degeneracy up to 500K to (probably local) Jahn-Teller distortions of the
CoO octahedra. A strong reduction or disappearance of the Jahn-Teller
distortions seems to arise from the insulator-to-metal transition around 500 K.Comment: an error in the scaling factor of Eq.(4) and consequently 2 values of
table I have been corrected. The conclusions of the paper remain unchanged.
See also: C. Zobel et al. Phys. Rev. B 71, 019902 (2005) and J. Baier et al.
Phys. Rev. B 71, 014443 (2005
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