Electronic setup for fluorescence emission measurements and long-time constant-temperature maintenance of Single-Walled Carbon Nano-Tubes in water solutions

In our previous research we have observed that the fluorescence emission from water solutions of Single-Walled Carbon Nano-Tubes (SWCNT), excited by a laser with a wavelength of 830nm, diminishes with the time. We have already proved that such a fading is a function of the storage time and the storage temperature. In order to study the emission of the SWCNT as a function of these two parameters we have designed and realized a special measurement compartment with a cuvette holder where the SWCNT solutions can be measured and stored at a fixed constant temperature for periods of time as long as several weeks. To maintain the measurement setup under a constant temperature we have designed special experimental setup based on two Peltier cells with electronic temperature control

Landscapes and Fragilities

The concept of fragility provides a possibility to rank different supercooled liquids on the basis of the temperature dependence of dynamic and/or thermodynamic quantities. We recall here the definitions of kinetic and thermodynamic fragility proposed in the last years and discuss their interrelations. At the same time we analyze some recently introduced models for the statistical properties of the potential energy landscape. Building on the Adam-Gibbs relation, which connects structural relaxation times to configurational entropy, we analyze the relation between statistical properties of the landscape and fragility. We call attention to the fact that the knowledge of number, energy depth and shape of the basins of the potential energy landscape may not be sufficient for predicting fragility. Finally, we discuss two different possibilities for generating strong behavior.Comment: 17 pages, 10 figures; accepted version, minor correction

Skewness as measure of the invariance of instantaneous renormalized drop diameter distributions – Part 1: Convective vs. stratiform precipitation

Abstract. We investigate the variability of the shape of the renormalized drop diameter instantaneous distribution using of the third order central moment: the skewness. Disdrometer data, collected at Darwin Australia, are considered either as whole or as divided in convective and stratiform precipitation intervals. We show that in all cases the distribution of the skewness is strongly peaked around 0.64. This allows to identify a most common distribution of renormalized drop diameters and two main variations, one with larger and one with smaller skewness. The distributions shapes are independent from the stratiform vs. convective classification

Skewness as measure of the invariance of instantaneous renormalized drop diameter distributions – Part 2: Orographic precipitation

Abstract. Here we use the skewness parameter, and the procedure developed in the companion paper (Ignaccolo and De Michele, 2012), to investigate the variability of instantaneous renormalized spectra of rain drop diameter in presence of orographic precipitation. Disdrometer data, available at Bodega Bay and Cazadero, California, are analyzed either as a whole, or as divided (using the bright band echo) in precipitation intervals weakly and strongly influenced by orography, and compared to results obtained at Darwin, Australia. We find that also at Bodega Bay and Cazadero exists a most common distribution of the skewness values of instantaneous spectra of drop diameter, but peaked at values greater than 0.64, found at Darwin. No appreciable differences are found in the skewness distributions of precipitation weakly and strongly influenced by orography. However the renormalized drop diameter spectra of precipitation with strong orographic component have fatter right tail than precipitation with a weaker orographic component. The differences between orographic and non-orographic precipitation are investigated within the parametric space represented by number of drops, mean value and standard deviation of drop diameter. A filter is developed which is able to identify 1 min time intervals during which precipitation is mostly of orographic origin

Viscoelasticity and Stokes-Einstein relation in repulsive and attractive colloidal glasses

We report a numerical investigation of the visco-elastic behavior in models for steric repulsive and short-range attractive colloidal suspensions, along different paths in the attraction-strength vs packing fraction plane. More specifically, we study the behavior of the viscosity (and its frequency dependence) on approaching the repulsive glass, the attractive glass and in the re-entrant region where viscosity shows a non monotonic behavior on increasing attraction strength. On approaching the glass lines, the increase of the viscosity is consistent with a power-law divergence with the same exponent and critical packing fraction previously obtained for the divergence of the density fluctuations. Based on mode-coupling calculations, we associate the increase of the viscosity with specific contributions from different length scales. We also show that the results are independent on the microscopic dynamics by comparing newtonian and brownian simulations for the same model. Finally we evaluate the Stokes-Einstein relation approaching both glass transitions, finding a clear breakdown which is particularly strong for the case of the attractive glass.Comment: 12 pages; sent to J. Chem. Phy

Capgras-like syndrome in a patient with an acute urinary tract infection.

Delusional misidentification syndromes are a group of delusional phenomena in which patients misidentify familiar persons, objects, or themselves, believing that they have been replaced or transformed. In 25%-40% of cases, misidentification syndromes have been reported in association with organic illness. We report an acute episode of Capgras-like delusion lasting 8 days, focused on the idea that people were robots with human bodies, in association with an acute urinary infection. To our knowledge, this is the first case report associating urinary tract infection with Capgras-like syndrome. Awareness of the prevalence of delusional misidentification syndromes associated with acute medical illness should promote diligence on the part of clinicians in recognizing this disorder

Impact of URI Canonicalization on Memento Count

Quantifying the captures of a URI over time is useful for researchers to identify the extent to which a Web page has been archived. Memento TimeMaps provide a format to list mementos (URI-Ms) for captures along with brief metadata, like Memento-Datetime, for each URI-M. However, when some URI-Ms are dereferenced, they simply provide a redirect to a different URI-M (instead of a unique representation at the datetime), often also present in the TimeMap. This infers that confidently obtaining an accurate count quantifying the number of non-forwarding captures for a URI-R is not possible using a TimeMap alone and that the magnitude of a TimeMap is not equivalent to the number of representations it identifies. In this work we discuss this particular phenomena in depth. We also perform a breakdown of the dynamics of counting mementos for a particular URI-R (google.com) and quantify the prevalence of the various canonicalization patterns that exacerbate attempts at counting using only a TimeMap. For google.com we found that 84.9% of the URI-Ms result in an HTTP redirect when dereferenced. We expand on and apply this metric to TimeMaps for seven other URI-Rs of large Web sites and thirteen academic institutions. Using a ratio metric DI for the number of URI-Ms without redirects to those requiring a redirect when dereferenced, five of the eight large web sites' and two of the thirteen academic institutions' TimeMaps had a ratio of ratio less than one, indicating that more than half of the URI-Ms in these TimeMaps result in redirects when dereferenced.Comment: 43 pages, 8 figure

Dynamics of uniaxial hard ellipsoids

We study the dynamics of monodisperse hard ellipsoids via a new event-driven molecular dynamics algorithm as a function of volume fraction $\phi$ and aspect ratio $X_0$. We evaluate the translational $D_{trans}$ and the rotational $D_{rot}$ diffusion coefficient and the associated isodiffusivity lines in the $\phi-X_0$ plane. We observe a decoupling of the translational and rotational dynamics which generates an almost perpendicular crossing of the $D_{trans}$ and $D_{rot}$ isodiffusivity lines. While the self intermediate scattering function exhibits stretched relaxation, i.e. glassy dynamics, only for large $\phi$ and $X_0 \approx 1$, the second order orientational correlator $C_2(t)$ shows stretching only for large and small $X_0$ values. We discuss these findings in the context of a possible pre-nematic order driven glass transition.Comment: accepted by Phys. Rev. Let