16 research outputs found
Nanoshaped CuO/CeO<sub>2</sub> Materials: Effect of the Exposed Ceria Surfaces on Catalytic Activity in N<sub>2</sub>O Decomposition Reaction
This study reports a thorough investigation
of nanosized CuO/CeO<sub>2</sub> materials as an efficient catalyst
for decomposition of N<sub>2</sub>O, which is a strong greenhouse
gas largely produced by chemical
industry. Effect of terminating CeO<sub>2</sub> crystalline planes
({100}, {110}, and {111}) on the behavior of CuO dispersed over CeO<sub>2</sub> nanocubes, nanorods and polyhedral crystallites was examined
in detail by using a variety of catalyst characterization techniques.
The 4 wt % Cu was found as the most advantageous metal loading, whereas
higher Cu content resulted in lower dispersion and formation of significantly
less active, segregated bulk CuO phase. It was discovered that CuO/CeO<sub>2</sub> solids should enable both excessive oxygen mobility on the
catalyst surface as well as formation of highly reducible Cu defect
sites, in order to ensure high intrinsic activity. Detailed studies
further revealed that CeO<sub>2</sub> morphology needs to be tailored
to expose {100} and {110} high-energy surface planes, as present in
CeO<sub>2</sub> nanorods. Oxygen mobility and regeneration of active
Cu phase on these surface planes is easier, which in turn facilitates
higher catalytic activity through the recombination of surface oxygen
atoms and desorption as molecular oxygen that replenishes active sites
for subsequent catalytic cycles. As a consequence, CuO supported on
CeO<sub>2</sub> nanorods demonstrated lower activation energy (87
kJ/mol) in N<sub>2</sub>O decomposition reaction compared to catalysts
based on CeO<sub>2</sub> nanocubes (102 kJ/mol) or polyhedral CeO<sub>2</sub> (92 kJ/mol)