Analytical approaches for analysis of safety of modern food packaging: A review

Nowadays, food packaging is a crucial tool for preserving food quality and has become an inseparable part of our daily life. Strong consumer demand and market trends enforce more advanced and creative forms of food packaging. New packaging development requires safety evaluations that always implicate the application of complex analytical methods. The present work reviews the development and application of new analytical methods for detection of possible food contaminants from the packaging origin on the quality and safety of fresh food. Among food contaminants migrants, set-off migrants from printing inks, polymer degradation products, and aromatic volatile compounds can be found that may compromise the safety and organoleptic properties of food. The list of possible chemical migrants is very wide and includes antioxidants, antimicrobials, intentionally added substances (IAS), non-intentionally added substances (NIAS), monomers, oligomers, and nanoparticles. All this information collected prior to the analysis will influence the type of analyzing samples and molecules (analytes) and therefore the selection of a convenient analytical method. Different analytical strategies will be discussed, including techniques for direct polymer analysis

Application of SERS to the determination of butylated hydroxyanisole in edible and essential oils

Surface-enhanced Raman scattering (SERS) has been applied to the determination of the antioxidant butylated hydroxyanisole (BHA), commonly used in fatty foods and oils to prevent their oxidation. The use of SERS Raman microscopy with an inexpensive homemade silver substrate allowed the direct determination of BHA in oils without any sample handling. Several edible and essential oils (used as flavorings) have been considered for this purpose. The experimental conditions, the peculiarities of each type of oil, and the characteristics of silver substrate, including scanning electron microscopy (SEM) analysis, are shown and discussed

Methodology of Testing Shot Blasting Machines in Industrial Conditions

Shot blasting machines are widely used for automated surface treatment and finishing of castings. In shot blasting processes the stream of shots is generated and shaped by blasting turbines, making up a kinetic and dynamic system comprising a separating rotor, an adapting sleeve and a propelling rotor provided with blades. The shot blasting performance- i.e. the quality of shot treated surfaces depends on the actual design and operational parameters of the unit whilst the values of relevant parameters are associated with the geometry of turbine components and the level of its integration with the separator system. The circulation of the blasting medium becomes the integrating factor of the process line, starting from the hopper, through the propeller turbine, casting treatment, separation of contaminated abrasive mixture, to its recycling and reuse.Inferior quality of the abrasive agent (shot) and insufficient purity of the abrasive mixture are responsible for low effectiveness of shot blasting. However, most practitioners fail to fully recognise the importance of proper diagnostics of the shot blasting process in industrial conditions. The wearing of major machine components and of the blasting agent and quality of shot treated surfaces are often misinterpreted, hence the need to take into account all factors involved in the process within the frame of a comprehensive methodology.This paper is an attempt to formulate and apply the available testing methods to the engineering practice in industrial conditions

Mapping the Northern Galactic Disk Warp with Classical Cepheids

We present an updated three dimensional map of the Milky Way based on a sample of 2431 classical Cepheid variable stars, supplemented with about 200 newly detected classical Cepheids from the OGLE survey. The new objects were discovered as a result of a dedicated observing campaign of the ≈280 square degree extension of the OGLE footprint of the Galactic disk during 2018-2019 observing seasons. These regions cover the main part of the northern Galactic warp that has been deficient in Cepheids so far. We use direct distances to the sample of over 2390 classical Cepheids to model the distribution of the young stellar population in the Milky Way and recalculate the parameters of the Galactic disk warp. Our data show that its northern part is very prominent and its amplitude is ≈10% larger than that of the southern part. By combining Gaia astrometric data with the Galactic rotation curve and distances to Cepheids from our sample, we construct a map of the vertical component of the velocity vector for all Cepheids in the Milky Way disk. We find large-scale vertical motions with amplitudes of 10-20 km/s, such that Cepheids located in the northern warp exhibit large positive vertical velocity (toward the north Galactic pole), whereas those in the southern warp - negative vertical velocity (toward the south Galactic pole)

Over 78 000 RR Lyrae Stars in the Galactic Bulge and Disk from the OGLE Survey

We present an upgrade of the OGLE Collection of RR Lyrae stars in the Galactic bulge and disk. The size of our sample has been doubled and reached 78 350 RR Lyr variables, of which 56 508 are fundamental-mode pulsators (RRab stars), 21 321 pulsate solely in the first-overtone (RRc stars), 458 are classical double-mode pulsators (RRd stars), and 63 are anomalous RRd variables (including six triple-mode pulsators). For all the newly identified RR Lyr stars, we publish time-series photometry obtained during the OGLE Galaxy Variability Survey. We present the spatial distribution of RR Lyr stars on the sky, provide a list of globular clusters hosting RR Lyr variables, and discuss the Petersen diagram for multimode pulsators. We find new RRd stars belonging to a compact group in the Petersen diagram (with period ratios P₁₀/P_F ≈ 0.74 and fundamental-mode periods P_F ≈ 0.44 d) and we show that their spatial distribution is roughly spherically symmetrical around the Milky Way center

Polylactide-based films with the addition of poly(ethylene glycol) and extract of propolis—physico-chemical and storage properties

Polymeric films based on polylactide (PLA) with the addition of poly(ethylene glycol) (PEG) and a chloroformic extract of propolis were obtained. In the case of the studied films, polylactide (PLA) played the role of polymeric matrix and poly(ethylene glycol) was used as a plasticizer, while the extract of propolis was incorporated as a compound that could significantly affect the properties of the obtained materials, especially the water vapour permeation rate and the stability of the food products. Moreover, changes in structure, morphology, mechanical and storage properties as well as differences in colour, thickness and transparency after introducing propolis into the PLA–PEG system were determined. Based on the obtained results, it was established that the addition of the chloroformic extract of propolis significantly influences the most important properties taken into account during food packaging. It was also noticed that films with incorporated propolis were characterised by a significant improvement in the water vapour barrier property. Moreover, the obtained results prove that packaging containing a chloroformic propolis extract allow for the maintenance of the quality of the fruit stored for an extended period of time. To summarise, the application of a chloroformic propolis extract enables the formation of packaging materials that extend the shelf life of stored food products

Assessing the acute and chronic toxicity of exposure to naturally occurring oil sands deposits to aquatic organisms using Daphnia magna

In the Athabasca region, the oil sands are located at or near the surface making open-pit mining viable. In addition, the Athabasca River and its tributaries flow through these oil sands deposits, thereby receiving bitumen-associated contaminants through natural fluvial erosional and weathering processes. A key knowledge gap has been related to understanding both the magnitude and significance of the toxicological and ecological effects on aquatic organisms exposed to naturally occurring bitumen entering fluvial systems. Using the Daphnia magna model system, this study assessed the ecotoxicological effects of exposure to bitumen-elutriate treatments that simulated the early stages of fluvial/erosional exposure conditions. No significant among-site differences were observed in the survival of D. magna after 48 h exposure to elutriates produced from a 24 h extraction cycle, and chemical analysis indicated low concentration of a complex mixture of hydrocarbon and metal contaminants. In contrast, the same elutriates impaired reproduction and growth after a 21-day chronic exposure. F1 neonates from the chronic tests were tested for sensitivity to the reference substance potassium dichromate, revealing a decrease in their sensitivity. Inter-generational effects were also observed, with a significant decrease in subsequent neonate production, when daphnids were moved to a clean medium. Supplemental acute toxicity assays using 48 and 72 h bitumen extraction cycles progressively increased daphnid mortality after a 48-h exposure to the respective elutriates. This indicates that bitumen-associated contaminants are being liberated after initial input and fluvial washing (24 h), highlighting the need for future work to assess toxicity responses and associated elutriate water chemistry of a longer fluvial exposure time-series. This work contributes to our understanding of the possible effects of natural bitumen exposure on riverine aquatic ecosystems, providing new information to inform the delineation of baseline conditions to assess environmental change and the design of future regional effects-based monitoring programs.publishe