Effect of Co doping and hydrostatic pressure on SrFe2As2

We report a pressure study on electron doped SrFe$_{2-x}$Co$_x$As$_2$ by electrical-resistivity ($\rho$) and magnetic-susceptibility ($\chi$) experiments. Application of either external pressure or Co substitution rapidly suppresses the spin-density wave ordering of the Fe moments and induces superconductivity in SrFe$_2$As$_2$. At $x=0.2$ the broad superconducting (SC) dome in the $T-p$ phase diagram exhibits its maximum $T_{c,{\rm max}}=20$ K at a pressure of only $p_{\rm max}\approx 0.75$ GPa. In SrFe$_{1.5}$Co$_{0.5}$As$_2$ no superconductivity is observed anymore up to 2.8 GPa. Upon increasing the Co concentration the maximum of the SC dome shifts toward lower pressure accompanied by a decrease in the value of $T_{c,{\rm max}}$. Even though, superconductivity is induced by both tuning methods, Co substitution leads to a much more robust SC state. Our study evidences that in SrFe$_{2-x}$Co$_x$As$_2$ both, the effect of pressure and Co-substitution, have to be considered in order to understand the SC phase-diagram and further attests the close relationship of SrFe$_2$As$_2$ and its sister compound BaFe$_2$As$_2$.Comment: 6 pages, 6 figure

Competition of local-moment ferromagnetism and superconductivity in Co-substituted EuFe2As2

In contrast to SrFe2As2, where only the iron possesses a magnetic moment, in EuFe2As2 an additional large, local magnetic moment is carried by Eu2+. Like SrFe2As2, EuFe2As2 exhibits a spin-density wave transition at high temperatures, but in addition the magnetic moments of the Eu2+ order at around 20 K. The interplay of pressure-induced superconductivity and the Eu2+ order leads to a behavior which is reminiscent of re-entrant superconductivity as it was observed, for example, in the ternary Chevrel phases or in the rare-earth nickel borocarbides. Here, we study the delicate interplay of the ordering of the Eu2+ moments and superconductivity in EuFe1.9Co0.1As2, where application of external pressure makes it possible to sensitively tune the ratio of the magnetic (T_C) and the superconducting (T_{c,onset}) critical temperatures. We find that superconductivity disappears once T_C > T_{c,onset}.Comment: 4 pages, 4 figures, submitted to the proceedings of SCES201

Microscopic magnetic modeling for the SS=1/2 alternating chain compounds Na3_3Cu2_2SbO6_6 and Na2_2Cu2_2TeO6_6

The spin-1/2 alternating Heisenberg chain system Na$_3$Cu$_2$SbO$_6$ features two relevant exchange couplings: $J_{1a}$ within the structural Cu$_2$O$_6$ dimers and $J_{1b}$ between the dimers. Motivated by the controversially discussed nature of $J_{1a}$, we perform extensive density-functional-theory (DFT) calculations, including DFT+$U$ and hybrid functionals. Fits to the experimental magnetic susceptibility using high-temperature series expansions and quantum Monte Carlo simulations yield the optimal parameters $J_{1a}$ = $-$217 K and $J_{1b}$ = 174 K with the alternation ratio $\alpha = J_{1a}/J_{1b} \simeq$ $-$1.25. For the closely related system Na$_2$Cu$_2$TeO$_6$, DFT yields substantially enhanced $J_{1b}$, but weaker $J_{1a}$. The comparative analysis renders the buckling of the chains as the key parameter altering the magnetic coupling regime. Numerical simulation of the dispersion relations of the alternating chain model clarify why both antiferromagnetic and ferrromagnetic $J_{1a}$ can reproduce the experimental magnetic susceptibility data.Comment: published version: 11 pages, 8 figures, 5 tables + Supplemental materia

Crystal water induced switching of magnetically active orbitals in CuCl2

The dehydration of CuCl2*2(H2O) to CuCl2 leads to a dramatic change in magnetic behavior and ground state. Combining density functional electronic structure and model calculations with thermodynamical measurements we reveal the microscopic origin of this unexpected incident -- a crystal water driven switching of the magnetically active orbitals. This switching results in a fundamental change of the coupling regime from a three-dimensional antiferromagnet to a quasi one-dimensional behavior. CuCl2 can be well described as a frustrated J1-J2 Heisenberg chain with ferromagnetic exchange J1 and J2/J1 ~ -1.5 for which a helical ground state is predicted.Comment: 6 pages, 5 figures, 1 table (PRB, accepted

Enhancement of the upper critical field in codoped iron-arsenic high-temperature superconductors

We present the first study of codoped iron-arsenide superconductors of the 122 family (Sr/Ba)_(1-x)K_xFe_(2-y)Co_yAs_2 with the purpose to increase the upper critical field H_c2 compared to single doped (Sr/Ba)Fe_2As_2 materials. H_c2 was investigated by measuring the magnetoresistance in high pulsed magnetic fields up to 64 T. We find, that H_c2 extrapolated to T = 0 is indeed enhanced significantly to ~ 90 T for polycrystalline samples of Ba_0.55K_0.45Fe_1.95Co_0.05As_2 compared to ~75 T for Ba_0.55K_0.45Fe_2As_2 and BaFe_1.8Co_0.2As_2 single crystals. Codoping thus is a promising way for the systematic optimization of iron-arsenic based superconductors for magnetic-field and high-current applications.Comment: 7 pages, 5 figures, submitted to Journal of Applied Physic

Unconventional magnetism in multivalent charge-ordered YbPtGe2_2 probed by 195^{195}Pt- and 171^{171}Yb-NMR

Detailed $^{195}$Pt- and $^{171}$Yb nuclear magnetic resonance (NMR) studies on the heterogeneous mixed valence system YbPtGe$_2$ are reported. The temperature dependence of the $^{195}$Pt-NMR shift $^{195}K(T)$ indicates the opening of an unusual magnetic gap below 200\,K. $^{195}K(T)$ was analyzed by a thermal activation model which yields an isotropic gap $\Delta/k_B \approx 200$\,K. In contrast, the spin-lattice relaxation rate $^{195}$($1/T_1$) does not provide evidence for the gap. Therefore, an intermediate-valence picture is proposed while a Kondo-insulator scenario can be excluded. Moreover, $^{195}$($1/T_1$) follows a simple metallic behavior, similar to the reference compound YPtGe$_2$. A well resolved NMR line with small shift is assigned to divalent $^{171}$Yb. This finding supports the proposed model with two sub-sets of Yb species (di- and trivalent) located on the Yb2 and Yb1 site of the YbPtGe$_2$ lattice.Comment: Submitted in Physical Review B (Rapid Communication

Superconductivity in the New Platinum Germanides MPt4Ge12 (M = Rare-earth and Alkaline-earth Metals) with Filled Skutterudite Structure

New germanium-platinum compounds with the filled-skutterudite crystal structure were synthesized. The structure and composition were investigated by X-ray diffraction and microprobe analysis. Magnetic susceptibility, specific heat, and electrical resistivity measurements evidence superconductivity in LaPt4Ge12 and PrPt4Ge12 below 8.3K. The parameters of the normal and superconducting states were established. Strong coupling and a crystal electric field singlet groundstate is found for the Pr compound. Electronic structure calculations show a large density of states at the Fermi level. Similar behavior with lower T_c was observed for SrPt4Ge12 and BaPt4Ge12.Comment: RevTeX, 4 figures, submitted to Physical Review Letters July 12, 200

Scaling Study and Thermodynamic Properties of the cubic Helimagnet FeGe

The critical behavior of the cubic helimagnet FeGe was obtained from isothermal magnetization data in very close vicinity of the ordering temperature. A thorough and consistent scaling analysis of these data revealed the critical exponents $\beta=0.368$, $\gamma=1.382$, and $\delta=4.787$. The anomaly in the specific heat associated with the magnetic ordering can be well described by the critical exponent $\alpha=-0.133$. The values of these exponents corroborate that the magnetic phase transition in FeGe belongs to the isotropic 3D-Heisenberg universality class. The specific heat data are well described by ab initio phonon calculations and confirm the localized character of the magnetic moments.Comment: 10 pages, 8 figure

Interpreting Safety Outcomes: Waymo's Performance Evaluation in the Context of a Broader Determination of Safety Readiness

This paper frames recent publications from Waymo within the broader context of the safety readiness determination for an Automated Driving System (ADS). Starting from a brief overview of safety performance outcomes reported by Waymo (i.e., contact events experienced during fully autonomous operations), this paper highlights the need for a diversified approach to safety determination that complements the analysis of observed safety outcomes with other estimation techniques. Our discussion highlights: the presentation of a "credibility paradox" within the comparison between ADS crash data and human-derived baselines; the recognition of continuous confidence growth through in-use monitoring; and the need to supplement any aggregate statistical analysis with appropriate event-level reasoning