Amorphous thin film growth: theory compared with experiment

Experimental results on amorphous ZrAlCu thin film growth and the dynamics of the surface morphology as predicted from a minimal nonlinear stochastic deposition equation are analysed and compared. Key points of this study are (i) an estimation procedure for coefficients entering into the growth equation and (ii) a detailed analysis and interpretation of the time evolution of the correlation length and the surface roughness. The results corroborate the usefulness of the deposition equation as a tool for studying amorphous growth processes.Comment: 7 pages including 5 figure

A Study to Improve Dissolved Oxygen Analysis Techniques to Facilitate Water Quality Field Survey Applications

This report describes studies made of the temperature characteristics of dissolved oxygen electrodes having a large surface area. Large area electrodes proved to have much longer lifetime between rejuvenations. Many measurements of dissolved oxygen in water need to be made in field situations where recalibration techniques would be difficult and where making temperature corrections is time consuming for operators who may be making numerous measurements. This study was directed toward design of a compensation circuit for a dissolved oxygen electrode which will give the best possible measurement over a large water temperature range of 5° - 35°C without the necessity of recalibration. Studies were made of the temperature characteristics of dissolved oxygen probes and several electronic circuits with different configurations and components are described. Experimental data using two of the circuits are reported. One method involved using an integrated circuit multiplier module. The best temperature compensation was obtained for a circuit based on a design in which two thermistors were incorporated

Extreme midlatitude cyclones and their implications for precipitation and wind speed extremes in simulations of the Maunder Minimum versus present day conditions

Extreme midlatitude cyclone characteristics, precipitation, wind speed events, their inter-relationships, and the connection to large-scale atmospheric patterns are investigated in simulations of a prolonged cold period, known as the Maunder Minimum from 1640 to 1715 and compared with today. An ensemble of six simulations for the Maunder Minimum as well as a control simulation for perpetual 1990 conditions are carried out with a coupled atmosphere-ocean general circulation model, i.e., the Climate Community System Model (CCSM). The comparison of the simulations shows that in a climate state colder than today the occurrence of cyclones, the extreme events of precipitation and wind speed shift southward in all seasons in the North Atlantic and the North Pacific. The extremes of cyclone intensity increases significantly in winter in almost all regions, which is related to a stronger meridional temperature gradient and an increase in lower tropospheric baroclinicity. Extremes of cyclone intensity in subregions of the North Atlantic are related to extremes in precipitation and in wind speed during winter. Moreover, extremes of cyclone intensity are also connected to distinct large-scale atmospheric patterns for the different subregions, but these relationships vanish during summer. Analyzing the mean 1,000hPa geopotential height change of the Maunder Minimum simulations compared with the control simulation, we find a similar pattern as the correlation pattern with the cyclone intensity index of the southern Europe cyclones. This illustrates that changes in the atmospheric high-frequency, i.e., the simulated southward shift of cyclones in the North Atlantic and the related increase of extreme precipitation and wind speed in particular in the Mediterranean in winter, are associated with large-scale atmospheric circulation change

Time of emergence of trends in ocean biogeochemistry

For the detection of climate change, not only the magnitude of a trend signal is of significance. An essential issue is the time period required by the trend to be detectable in the first place. An illustrative measure for this is time of emergence (ToE), that is, the point in time when a signal finally emerges from the background noise of natural variability. We investigate the ToE of trend signals in different biogeochemical and physical surface variables utilizing a multi-model ensemble comprising simulations of 17 Earth system models (ESMs). We find that signals in ocean biogeochemical variables emerge on much shorter timescales than the physical variable sea surface temperature (SST). The ToE patterns of <i>p</i>CO₂ and pH are spatially very similar to DIC (dissolved inorganic carbon), yet the trends emerge much faster – after roughly 12 yr for the majority of the global ocean area, compared to between 10 and 30 yr for DIC. ToE of 45–90 yr are even larger for SST. In general, the background noise is of higher importance in determining ToE than the strength of the trend signal. In areas with high natural variability, even strong trends both in the physical climate and carbon cycle system are masked by variability over decadal timescales. In contrast to the trend, natural variability is affected by the seasonal cycle. This has important implications for observations, since it implies that intra-annual variability could question the representativeness of irregularly sampled seasonal measurements for the entire year and, thus, the interpretation of observed trends

Reconstructing climate variability from Greenland ice sheet accumulation: An ERA40 study

Re-analysis data covering the period 1958–2001 are used to investigate the relationship between regional, inter-annual snow accumulation variability over the Greenland Ice Sheet (GrIS) and large scale circulation patterns, cyclone frequency, and strength. Four regions of the GrIS have been identified that are highly independent with respect to accumulation variability. Accumulation indices of three of these regions are associated with distinct large-scale circulation patterns: Central-western GrIS reveals an inverse relationship with a NAO-like pattern, the south-west a positive correlation with a high pressure bridge from central North Atlantic to Scandinavia, and the south-eastern GrIS a positive correlation with a high-pressure anomaly over the Greenland Sea. These large-scale patterns also impact European climate in different ways. Accumulation variability in north-eastern GrIS, however, is dominated by cyclones originating from the Greenland Sea. Thus, Greenland ice core accumulation records offer the potential to reconstruct various large-scale circulation patterns and regional storm activity

Impact-driven effects in thin-film growth: steering and transient mobility at the Ag(110) surface

Low-energy atomic impacts on the Ag(110) surface are investigated by molecular dynamics simulations based on reliable many-body semiempirical potentials. Trajectory deflections (steering) caused by the atom-surface interaction are observed, together with impact-following, transient-mobility effects. Such processes are quantitatively analysed and their dependence on the initial kinetic energy and on the impinging direction is discussed. A clear influence of the surface anisotropy on both steering and transient mobility effects is revealed by our simulations for the simple isolated-atom case and in the submonolayer-growth regime. For the latter case, we illustrate how steering and transient mobility affect the film morphology at the nanoscale.Comment: 7 pages, 9 figure

Steering effect on the shape of islands for homoepitaxial growth of Cu on Cu(100)

The steering effect on the growth of islands is investigated by combining molecular dynamics (MD) and kinetic Monte Carlo (KMC) simulations. Dynamics of depositing atoms and kinetics of atoms on a substrate are realized by MD and KMC, respectively. The reported experimental results on the asymmetric island growth [van Dijken {\it et al.}, Phys. Rev. Lett. {\bf 82}, 4038 (1999).] is well reproduced. A salient phenomenon, the reversal of the asymmetry, is found as the island size increases, and attributed to the asymmetric flux on the lower terrace of island.Comment: 5 figur

Extratropical cyclone statistics during the last millennium and the 21st century

Extratropical cyclones in winter and their characteristics are investigated in depth for the Atlantic European region, as they are responsible for a significant part of the rainfall and extreme wind and/or precipitation-induced hazards. The analysis is based on a seamless transient simulation with a state-of-the-art fully coupled Earth system model from 850 to 2100&thinsp;CE. The Representative Concentration Pathway 8.5 (RCP8.5) scenario is used in the 21st century. During the Common Era, cyclone characteristics show pronounced variations on interannual and decadal timescales, but no external forcing imprint is found prior to 1850. Thus, variations of extratropical cyclone characteristics are mainly caused by internal variability of the coupled climate system. When anthropogenic forcing becomes dominant in the 20th century, a decrease of the cyclone occurrences mainly over the Mediterranean and a strong increase of extreme cyclone-related precipitation become detectable. The latter is due to thermodynamics as it follows the Clausius–Clapeyron relation. An important finding, though, is that the relation between temperature and extreme cyclone-related precipitation is not always controlled by the Clausius–Clapeyron relation, which suggests that dynamical processes can play an important role in generating extreme cyclone-related precipitation – for example, in the absence of anomalously warm background conditions. Thus, the importance of dynamical processes, even on decadal timescales, might explain the conundrum that proxy records suggest enhanced occurrence of precipitation extremes during rather cold periods in the past.</p

The influence of regional circulation patterns on wet and dry mineral dust and sea salt deposition over Greenland

Annually resolved ice core records from different regions over the Greenland ice sheet (GrIS) are used to investigate the spatial and temporal variability of calcium (Ca2+, mainly from mineral dust) and sodium (Na+, mainly from sea salt) deposition. Cores of high common inter-annual variability are grouped with an EOF analysis, resulting in regionally representative Ca2+ and Na+ records for northeastern and central Greenland. Utilizing a regression and validation method with ERA-40 reanalysis data, these common records are associated with distinct regional atmospheric circulation patterns over the North American Arctic, Greenland, and Central to Northern Europe. These patterns are interpreted in terms of transport and deposition of the impurities. In the northeastern part of the GrIS sea salt records reflect the intrusion of marine air masses from southeasterly flow. A large fraction of the Ca2+ variability in this region is connected to a circulation pattern suggesting transport from the west and dry deposition. This pattern is consistent with the current understanding of a predominantly Asian source of the dust deposited over the GrIS. However, our results also indicate that a significant fraction of the inter-annual dust variability in NE and Central Greenland is determined by the frequency and intensity of wet deposition during the season of high atmospheric dust loading, rather than representing the variability of the Asian dust source and/or long-range transport to Greenland. The variances in the regional proxy records explained by the streamfunction patterns are high enough to permit reconstructions of the corresponding regional deposition regimes and the associated circulation pattern