72,440 research outputs found
Reconciling visions and realities of virtual working: findings from the UK chemicals industry
The emergence of advanced technologies such as Grid computing will, some suggest, allow the final realisation of visions of virtual organisations. This will, according to its advocates, have entirely positive impacts, creating communities of experts, increasing flexibility, reducing the need for travel and making communications more efficient by crossing boundaries of time and space. Such predictions about future patterns of virtual working are, unfortunately, rarely grounded in real working practices, and often neglect to account for both the rich and varied interpretations that may exist of what constitutes virtual working and the constraints and concerns of those who would do it. This chapter gives attention to the consequences of different views over what virtuality might mean in practice and, in particular, considers virtuality in relation to customer and supplier relationships in a competitive and commercial context. The discussion is based upon a three year study that investigated contrasting visions of what was technically feasible and might be organisationally desirable in the UK Chemicals industry. Through interviews with managers and staff of companies both large and small that research provided insights into the different meanings that organisations attribute to the virtuality of work and to the acceptability of potential implementations of a middleware technology. It was found that interpretations of virtuality amongst the potential users and participants were strongly influenced by established work practices and by previous experiences of relationships-at-a-distance with suppliers and customers. There was a sharp contrast with the enthusiastic visions of virtual working that were already being encapsulated in the middleware by the technical developers; visions of internet-only interaction were perceived as rigid, alienating from well-established ways of working with suppliers and customers and unworkable. In this chapter we shall capture these differences by making a distinction amongst compet
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Intellectual Property Topics in Open University Distance-Taught Courses
Patents lie at the heart of engineering as a permanent and ongoing record of invention. We have taught the subject for about 5 years in both UG and PG courses, written from scratch owing to the absence of textbooks aimed specifically at engineers. Most practising engineers develop patent skills on the job rather than through conventional courses. But there is a need to present such courses as early as possible in the engineering curriculum, so that graduates have a flying start in their first employment
Interoperability between Multimedia Collections for Content and Metadata-Based Searching
Artiste is a European project developing a cross-collection search system for art galleries and museums. It combines image content retrieval with text based retrieval and uses RDF mappings in order to integrate diverse databases. The test sites of the Louvre, Victoria and Albert Museum, Uffizi Gallery and National Gallery London provide their own database schema for existing metadata, avoiding the need for migration to a common schema. The system will accept a query based on one museum’s fields and convert them, through an RDF mapping into a form suitable for querying the other collections. The nature of some of the image processing algorithms means that the system can be slow for some computations, so the system is session-based to allow the user to return to the results later. The system has been built within a J2EE/EJB framework, using the Jboss Enterprise Application Server
Spin-dependent charge recombination along para-phenylene molecular wires
We have used an efficient new quantum mechanical method for radical pair
recombination reactions to study the spin-dependent charge recombination along
PTZ--Ph--PDI molecular wires. By comparing our
results to the experimental data of E. Weiss {\em et al.} [J. Am. Chem. Soc.
{\bf 126}, 5577 (2004)], we are able to extract the spin-dependent (singlet and
triplet) charge recombination rate constants for wires with . These
spin-dependent rate constants have not been extracted previously from the
experimental data because they require fitting its magnetic field-dependence to
the results of quantum spin dynamics simulations. We find that the triplet
recombination rate constant decreases exponentially with the length of the
wire, consistent with the superexchange mechanism of charge recombination.
However, the singlet recombination rate constant is nearly independent of the
length of the wire, suggesting that the singlet pathway is dominated by an
incoherent hopping mechanism. A simple qualitative explanation for the
different behaviours of the two spin-selective charge recombination pathways is
provided in terms of Marcus theory. We also find evidence for a magnetic
field-independent background contribution to the triplet yield of the charge
recombination reaction, and suggest several possible explanations for it. Since
none of these explanations is especially compelling given the available
experimental evidence, and since the result appears to apply more generally to
other molecular wires, we hope that this aspect of our study will stimulate
further experimental work.Comment: 12 pages, 10 figure
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