368 research outputs found
Electronic properties of alkali-metal loaded zeolites -- a "supercrystal" Mott insulator
First-principles band calculations are performed for the first time for an
open-structured zeolite (LTA) with guest atoms (potassium) introduced in their
cages. A surprisingly simple band structure emerges, which indicates that this
system may be regarded as a "supercrystal", where each cluster of guest atoms
with diameter 10\AA acts as a "superatom" with well-defined - and
-like orbitals, which in turn form the bands around the Fermi energy. The
calculated Coulomb and exchange energies for these states turn out to be in the
strongly-correlated regime. With the dynamical mean-field theory we show the
system should be on the Mott-insulator side, and, on a magnetic phase diagram
for degenerate-orbital systems, around the ferromagnetic regime, in accord with
experimental results. We envisage this class of systems can provide a new
avenue for materials design.Comment: 4 pages, 4 figure
Magnetodielectric detection of magnetic quadrupole order in Ba(TiO)Cu(PO) with CuO square cupolas
In vortex-like spin arrangements, multiple spins can combine into emergent
multipole moments. Such multipole moments have broken space-inversion and
time-reversal symmetries, and can therefore exhibit linear magnetoelectric (ME)
activity. Three types of such multipole moments are known: toroidal, monopole,
and quadrupole moments. So far, however, the ME-activity of these multipole
moments has only been established experimentally for the toroidal moment. Here,
we propose a magnetic square cupola cluster, in which four corner-sharing
square-coordinated metal-ligand fragments form a noncoplanar buckled structure,
as a promising structural unit that carries an ME-active multipole moment. We
substantiate this idea by observing clear magnetodielectric signals associated
with an antiferroic ME-active magnetic quadrupole order in the real material
Ba(TiO)Cu(PO). The present result serves as a useful guide for
exploring and designing new ME-active materials based on vortex-like spin
arrangements.Comment: 4 figure
2 Novel deletions of the sterol 27-hydroxylase gene in a Chinese Family with Cerebrotendinous Xanthomatosis
<p>Abstract</p> <p>Background</p> <p>Cerebrotendinous xanthomatosis (CTX) is a rare lipid-storage disease. We investigated the clinic manifestation, histopathology and sterol 27-hydroxylase gene (CYP27A1) in a Chinese family with Cerebrotendinous Xanthomatosis (CTX).</p> <p>Case Presentation</p> <p>A 36-year-old female with typical CTX clinical manifestation had Spindle-shaped lipid crystal clefts in xanthomas and "onion-like demyelination" in sural nerve. The patient was compound heterozygote carrying two deletions in exon 1 (c.73delG) and exon 2 (c.369_375delGTACCCA). The family memebers were carriers.</p> <p>Conclusions</p> <p>A Chinese family with Cerebrotendinous Xanthomatosis had typical clinical manifestation. CYP27A1 mutations were found in the proband and all other family members.</p
Signatures of the excitonic memory effects in four-wave mixing processes in cavity polaritons
We report the signatures of the exciton correlation effects with finite
memory time in frequency domain degenerate four-wave mixing (DFWM) in
semiconductor microcavity. By utilizing the polarization selection rules, we
discriminate instantaneous, mean field interactions between excitons with the
same spins, long-living correlation due to the formation of biexciton state by
excitons with opposite spins, and short-memory correlation effects in the
continuum of unbound two-exciton states. The DFWM spectra give us the relative
contributions of these effects and the upper limit for the time of the
exciton-exciton correlation in the unbound two-exciton continuum. The obtained
results reveal the basis of the cavity polariton scattering model for the DFWM
processes in high-Q GaAs microcavity.Comment: 11 pages, 1 figur
Electron-phonon renormalization of the absorption edge of the cuprous halides
Compared to most tetrahedral semiconductors, the temperature dependence of
the absorption edges of the cuprous halides (CuCl, CuBr, CuI) is very small.
CuCl and CuBr show a small increase of the gap with increasing
temperature, with a change in the slope of vs. at around 150 K: above
this temperature, the variation of with becomes even smaller. This
unusual behavior has been clarified for CuCl by measurements of the low
temperature gap vs. the isotopic masses of both constituents, yielding an
anomalous negative shift with increasing copper mass. Here we report the
isotope effects of Cu and Br on the gap of CuBr, and that of Cu on the gap of
CuI. The measured isotope effects allow us to understand the corresponding
temperature dependences, which we also report, to our knowledge for the first
time, in the case of CuI. These results enable us to develop a more
quantitative understanding of the phenomena mentioned for the three halides,
and to interpret other anomalies reported for the temperature dependence of the
absorption gap in copper and silver chalcogenides; similarities to the behavior
observed for the copper chalcopyrites are also pointed out.Comment: 14 pages, 5 figures, submitted to Phys. Rev.
Common carotid intima media thickness and ankle-brachial pressure index correlate with local but not global atheroma burden:a cross sectional study using whole body magnetic resonance angiography
Common carotid intima media thickness (CIMT) and ankle brachial pressure index (ABPI) are used as surrogate marker of atherosclerosis, and have been shown to correlate with arterial stiffness, however their correlation with global atherosclerotic burden has not been previously assessed. We compare CIMT and ABPI with atheroma burden as measured by whole body magnetic resonance angiography (WB-MRA).50 patients with symptomatic peripheral arterial disease were recruited. CIMT was measured using ultrasound while rest and exercise ABPI were performed. WB-MRA was performed in a 1.5T MRI scanner using 4 volume acquisitions with a divided dose of intravenous gadolinium gadoterate meglumine (Dotarem, Guerbet, FR). The WB-MRA data was divided into 31 anatomical arterial segments with each scored according to degree of luminal narrowing: 0 = normal, 1 = <50%, 2 = 50-70%, 3 = 70-99%, 4 = vessel occlusion. The segment scores were summed and from this a standardized atheroma score was calculated.The atherosclerotic burden was high with a standardised atheroma score of 39.5±11. Common CIMT showed a positive correlation with the whole body atheroma score (β 0.32, p = 0.045), however this was due to its strong correlation with the neck and thoracic segments (β 0.42 p = 0.01) with no correlation with the rest of the body. ABPI correlated with the whole body atheroma score (β -0.39, p = 0.012), which was due to a strong correlation with the ilio-femoral vessels with no correlation with the thoracic or neck vessels. On multiple linear regression, no correlation between CIMT and global atheroma burden was present (β 0.13 p = 0.45), while the correlation between ABPI and atheroma burden persisted (β -0.45 p = 0.005).ABPI but not CIMT correlates with global atheroma burden as measured by whole body contrast enhanced magnetic resonance angiography in a population with symptomatic peripheral arterial disease. However this is primarily due to a strong correlation with ilio-femoral atheroma burden
Bulk superconductivity in Pb-substituted BiS-based compounds studied by hard-x-ray spectroscopy
In this study, we investigate the bulk electronic structure of Pb-substituted
LaOFBiS single crystals, using two types of hard-x-ray
spectroscopy. High-energy-resolution fluorescence-detected x-ray absorption
spectroscopy revealed a spectral change at low temperatures. Using density
functional theory (DFT) simulations, we find that the temperature-induced
change originates from a structural phase transition, similar to the
pressure-induced transition in LaOFBiS. This finding
suggests that the mechanism of bulk superconductivity induced by Pb
substitution is the same as that under high pressure. Furthermore, a novel
low-valence state with a mixture of divalent and trivalent Bi ions is
discovered using hard x-ray photoemission spectroscopy with the aid of DFT
calculations.Comment: 8 pages, 6 figures, 1 tabl
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