554 research outputs found
Giant Dielectric Permittivity of Electron-Doped Manganite Thin Films, Ca(1-x)La(x)MnO(3) ($0<= x<= 0.03)
A giant low-frequency, in-plane dielectric constant, eps~10^6, for epitaxial
thin films of Ca(1-x)La(x)MnO(3) (x<=0.03) was observed over a broad
temperature range, 4K <= T 300K. This phenomenon is attributed to an internal
barrier-layer capacitor (IBLC) structure, with insulating boundaries between
semiconducting grains. The room-temperature eps increases substantially with
electron (La) doping. The measured values of eps exceed those of conventional
two-phase IBLC materials based on (Ba,Sr)TiO(3) as well as recently discovered
CaCu(3)Ti(4)O(12) and (Li,Ti) doped NiO.Comment: 5 pages, 4 fig.s, J. Appl. Phys., Jan. 15, 2005 (in press
Providing Effective and Supportive Legal Career Guidance for Neurodivergent Law Students and Attorneys
Low-Temperature Permittivity of Insulating Perovskite Manganites
Measurements of the low-frequency (f<=100 kHz) permittivity and conductivity
at T<= 150 K are reported for La(1-x)Ca(x)MnO(3) (0<=x<=1) and
Ca(1-y)Sr(y)MnO(3) (0<=y<=0.75) having antiferromagnetic, insulating ground
states covering a broad range of Mn valencies from Mn(3+) to Mn(4+). Static
dielectric constants are determined from the low-T limiting behavior. With
increasing T, relaxation peaks associated with charge-carrier hopping are
observed in the real part of the permittivities and analyzed to determine
dopant binding energies. The data are consistent with a simple model of
hydrogenic impurity levels and imply effective masses m*/m_e~3 for the Mn(4+)
compounds. Particularly interesting is a large dielectric constant (~100)
associated with the C-type antiferromagnetic state near the composition
La(0.2)Ca(0.8)MnO(3).Comment: 6 pages, 8 figures, PRB in pres
Extreme thermopower anisotropy and interchain transport in the quasi-one-dimensional metal Li(0.9)Mo(6)O(17)
Thermopower and electrical resistivity measurements transverse to the
conducting chains of the quasi-one-dimensional metal Li(0.9)Mo(6)O(17) are
reported in the temperature range 5 K = 400 K the
interchain transport is determined by thermal excitation of charge carriers
from a valence band ~ 0.14 eV below the Fermi level, giving rise to a large,
p-type thermopower that coincides with a small, n-type thermopower along the
chains. This dichotomy -- semiconductor-like in one direction and metallic in a
mutually perpendicular direction -- gives rise to substantial transverse
thermoelectric (TE) effects and a transverse TE figure of merit among the
largest known for a single compound.Comment: PRL in press, manuscript (5pp, 4 Fig.'s) and Supplementary Material
(3pp, 3 Fig.'s
Heat Conduction and Magnetic Phase Behavior in Electron-Doped Ca_{1-x} La_x MnO_3(0 <= x <= 0.2)
Measurements of thermal conductivity (kappa) vs temperature are reported for
a series of Ca_{1-x} La_x MnO_3(0 <= x <= 0.2) specimens. For the undoped
(x=0), G-type antiferromagnetic compound a large enhancement of kappa below the
Neel temperature (T_N ~ 125 K) indicates a strong coupling of heat-carrying
phonons to the spin system. This enhancement exhibits a nonmonotonic behavior
with increasing x and correlates remarkably well with the small ferromagnetic
component of the magnetization reported previously [Neumeier and Cohn, Phys.
Rev. B 61 14319 (2000).] Magnetoelastic polaron formation appears to underly
the behavior of kappa and the magnetization at x <= 0.02.Comment: submitted to PRB; 4 pp., 4 Fig.'s, RevTex
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