76 research outputs found
Thermodynamic properties and structural stability of thorium dioxide
Using density functional theory (DFT) calculations, we have systematically
investigated the thermodynamic properties and structural stabilities of thorium
dioxide (ThO). Based on the calculated phonon dispersion curves, we
calculate the thermal expansion coefficient, bulk modulus, and heat capacities
at different temperatures for ThO under the quasi-harmonic approximation.
All the results are in good agreement with corresponding experiments proving
the validity of our methods. Our theoretical studies can help people more
clearly understand the thermodynamic behaviors of ThO at different
temperatures. In addition, we have also studied possible defect formations and
diffusion behaviors of helium in ThO, to discuss its structural stability.
It is found that in intrinsic ThO without any Fermi energy shifts, the
interstitial Th defect other than oxygen or thorium vacancies,
interstitial oxygen, and any kinds of Frenkel pairs, is most probable to form
with an energy release of 1.74 eV. However, after upshifting the Fermi energy,
the formation of the other defects also becomes possible. For helium diffusion,
we find that only through the thorium vacancy can it happen with the small
energy barrier of 0.52 eV. Otherwise, helium atoms can hardly incorporate or
diffuse in ThO. Our results indicate that people should prevent upshifts of
the Fermi energy of ThO to avoid the formation of thorium vacancies and so
as to prevent helium caused damages.Comment: 11 pages, 11 figure
Beat-to-beat vectorcardiographic analysis of ventricular depolarization and repolarization in myocardial infarction
OBJECTIVES: Increased beat-to-beat variability in the QT interval has been associated with heart disease and mortality. The purpose of this study was to investigate the beat-to-beat spatial and temporal variations of ventricular depolarization and repolarization in vectorcardiogram (VCG) for characterising myocardial infarction (MI) patients. METHODS: Standard 12-lead ECGs of 84 MI patients (22 f, 63±12 yrs; 62 m, 56±10 yrs) and 69 healthy subjects (17 f, 42±18 yrs; 52 m, 40±13 yrs) were investigated. To extract the beat-to-beat QT intervals, a template-matching algorithm and the singular value decomposition method have been applied to synthesise the ECG data to VCG. Spatial and temporal variations in the QRS complex and T-wave loops were studied by investigating several descriptors (point-to-point distance variability, mean loop length, T-wave morphology dispersion, percentage of loop area, total cosine R-to-T). RESULTS: Point-to-point distance variability of QRS and T-loops (0.13±.04 vs. 0.10±0.04, p<0.0001 and 0.16±.07 vs. 0.13±.06, p<0.05) were significantly larger in the MI group than in the control group. The average T-wave morphology dispersion was significantly higher in the MI group than in the control group (62±8 vs. 38±16, p<.0001). Further, its beat-to-beat variability appeared significantly lower in the MI group than in the control group (12±5 v. 15±6u, p<0.005). Moreover, the average percentage of the T-loop area was found significantly lower in the MI group than the controls (46±17 vs. 55±15, p<.001). Finally, the average and beat-to-beat variability of total cosine R-to-T were not found statistically significant between both groups. CONCLUSIONS: Beat-to-beat assessment of VCG parameters may have diagnostic attributes that might help in identifying MI patients.Muhammad A. Hasan, Derek Abbott and Mathias Baumer
Urinary protein-to-creatinine ratio in pregnant women after dipstick testing: prospective observational study
Decomposition of Trichloroethylene in Water by Using Aeration and Gas-phase Photoreaction.
Photocatalytic Degradation of Trichloroethylene in Water by Using Thin-film TiO2 Prepared by Sol-gel Process.
Personality associated with depressive status in individuals with type 2 diabetes mellitus
Norio Yasui-Furukori,1,2 Hiroshi Murakami,3 Hideyuki Otaka,3 Hirofumi Nakayama,3 Masaya Murabayashi,3 Satoru Mizushiri,3 Koki Matsumura,3 Jutaro Tanabe,3 Yuki Matsuhashi,3 Miyuki Yanagimachi,3 Kazuhiko Nakamura,2 Makoto Daimon,3 Norio Sugawara1,41Department of Psychiatry, Dokkyo Medical University School of Medicine, Tochigi, Japan; 2Department of Neuropsychiatry, Hirosaki University Graduate School of Medicine, Hirosaki, Japan; 3Department of Endocrinology and Metabolism, Hirosaki University Graduate School of Medicine, Hirosaki, Japan; 4Department of Clinical Epidemiology, Translational Medical Center, National Center of Neurology and Psychiatry, Kodaira, Tokyo, JapanObjective: Type 2 diabetes mellitus (T2DM) is associated with a high prevalence of depression, and depression is influenced by personality traits; however, these psychological factors have not been well studied in individuals with T2DM. The association between the use of a 5-factor model of personality and depressive symptoms was examined in individuals with T2DM.Methods: The subjects were 435 T2DM patients (mean age 63.1±12.6 years). Depressive status and personality traits were assessed using the Center for Epidemiologic Studies Depression Scale and the Ten-Item Personality Inventory, Japanese version, respectively. Lifestyle factors and glycated hemoglobin A1c levels in the patients were also included in the analyses.Results: Among the 435 subjects with T2DM, 130 (29.9%) exhibited possible depression, and 68 (15.6%) exhibited probable depression. After adjustment for confounders, Extraversion, Agreeableness and Neuroticism were found to be significantly associated with the presence of depression. No relationships were found between depression and HbA1c.Conclusion: These findings indicate that Extraversion and Agreeableness are protective factors, and Neuroticism is a risk factor for depression in T2DM patients. Psychological therapy focusing on personality may reduce depressive symptoms. Additional studies are needed to examine the relationships between psychological factors and depressive symptoms using a longitudinal study design.Keywords: cross-sectional studies, depressive symptoms, Japanese, personality, type 2 diabete
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