PRELIMINARY DATA REPORT: HUMATE INJECTION AS AN ENHANCED ATTENUATION METHOD AT THE F-AREA SEEPAGE BASINS, SAVANNAH RIVER SITE

A field test of a humate technology for uranium and I-129 remediation was conducted at the F-Area Field Research Site as part of the Attenuation-Based Remedies for the Subsurface Applied Field Research Initiative (ABRS AFRI) funded by the DOE Office of Soil and Groundwater Remediation. Previous studies have shown that humic acid sorbed to sediments strongly binds uranium at mildly acidic pH and potentially binds iodine-129 (I-129). Use of humate could be applicable for contaminant stabilization at a wide variety of DOE sites however pilot field-scale tests and optimization of this technology are required to move this technical approach from basic science to actual field deployment and regulatory acceptance. The groundwater plume at the F-Area Field Research Site contains a large number of contaminants, the most important from a risk perspective being strontium-90 (Sr-90), uranium isotopes, I-129, tritium, and nitrate. Groundwater remains acidic, with pH as low as 3.2 near the basins and increasing to the background pH of approximately 5at the plume fringes. The field test was conducted in monitoring well FOB 16D, which historically has shown low pH and elevated concentrations of Sr-90, uranium, I-129 and tritium. The field test included three months of baseline monitoring followed by injection of a potassium humate solution and approximately four and half months of post monitoring. Samples were collected and analyzed for numerous constituents but the focus was on attenuation of uranium, Sr-90, and I-129. This report provides background information, methodology, and preliminary field results for a humate field test. Results from the field monitoring show that most of the excess humate (i.e., humate that did not sorb to the sediments) has flushed through the surrounding formation. Furthermore, the data indicate that the test was successful in loading a band of sediment surrounding the injection point to a point where pH could return to near normal during the study timeframe. Future work will involve a final report, which will include data trends, correlations and interpretations of laboratory data

Challenges to addressing student mental health in embedded counselling services: a survey of UK higher and further education institutions

Background: with reports continually demonstrating increased demand and severity of student mental health needs, it is important to gain a fuller understanding of the impact on embedded student counselling services. Aims: to identify (1) service similarities; (2) factors which impact on services; (3) characteristics of service users; and (4) identify the use of therapeutic technology (e.g. online self-help). Methods: an online survey was completed by 113 heads of UK student counselling services across Higher Education (HE), Further Education (FE), and Sixth Form Colleges (SFCs), to capture service data from the academic year 2013/14. Results: students predominantly received high-intensity support (e.g. Counselling) and referrals increased over 3-years. Conclusion: challenges to embedded counselling services and their implications for development are discussed

PRELIMINARY DATA REPORT: HUMATE INJECTION AS AN ENHANCED ATTENUATION METHOD AT THE F-AREA SEEPAGE BASINS, SAVANNAH RIVER SITE

A field test of a humate technology for uranium and I-129 remediation was conducted at the F-Area Field Research Site as part of the Attenuation-Based Remedies for the Subsurface Applied Field Research Initiative (ABRS AFRI) funded by the DOE Office of Soil and Groundwater Remediation. Previous studies have shown that humic acid sorbed to sediments strongly binds uranium at mildly acidic pH and potentially binds iodine-129 (I-129). Use of humate could be applicable for contaminant stabilization at a wide variety of DOE sites however pilot field-scale tests and optimization of this technology are required to move this technical approach from basic science to actual field deployment and regulatory acceptance. The groundwater plume at the F-Area Field Research Site contains a large number of contaminants, the most important from a risk perspective being strontium-90 (Sr-90), uranium isotopes, I-129, tritium, and nitrate. Groundwater remains acidic, with pH as low as 3.2 near the basins and increasing to the background pH of approximately 5at the plume fringes. The field test was conducted in monitoring well FOB 16D, which historically has shown low pH and elevated concentrations of Sr-90, uranium, I-129 and tritium. The field test included three months of baseline monitoring followed by injection of a potassium humate solution and approximately four and half months of post monitoring. Samples were collected and analyzed for numerous constituents but the focus was on attenuation of uranium, Sr-90, and I-129. This report provides background information, methodology, and preliminary field results for a humate field test. Results from the field monitoring show that most of the excess humate (i.e., humate that did not sorb to the sediments) has flushed through the surrounding formation. Furthermore, the data indicate that the test was successful in loading a band of sediment surrounding the injection point to a point where pH could return to near normal during the study timeframe. Future work will involve a final report, which will include data trends, correlations and interpretations of laboratory data

RECONNAISSANCE ASSESSMENT OF CO2 SEQUESTRATION POTENTIAL IN THE TRIASSIC AGE RIFT BASIN TREND OF SOUTH CAROLINA, GEORGIA, AND NORTHERN FLORIDA

A reconnaissance assessment of the carbon dioxide (CO{sub 2}) sequestration potential within the Triassic age rift trend sediments of South Carolina, Georgia and the northern Florida Rift trend was performed for the Office of Fossil Energy, National Energy Technology Laboratory (NETL). This rift trend also extends into eastern Alabama, and has been termed the South Georgia Rift by previous authors, but is termed the South Carolina, Georgia, northern Florida, and eastern Alabama Rift (SGFAR) trend in this report to better describe the extent of the trend. The objectives of the study were to: (1) integrate all pertinent geologic information (literature reviews, drilling logs, seismic data, etc.) to create an understanding of the structural aspects of the basin trend (basin trend location and configuration, and the thickness of the sedimentary rock fill), (2) estimate the rough CO{sub 2} storage capacity (using conservative inputs), and (3) assess the general viability of the basins as sites of large-scale CO{sub 2} sequestration (determine if additional studies are appropriate). The CO{sub 2} estimates for the trend include South Carolina, Georgia, and northern Florida only. The study determined that the basins within the SGFAR trend have sufficient sedimentary fill to have a large potential storage capacity for CO{sub 2}. The deeper basins appear to have sedimentary fill of over 15,000 feet. Much of this fill is likely to be alluvial and fluvial sedimentary rock with higher porosity and permeability. This report estimates an order of magnitude potential capacity of approximately 137 billion metric tons for supercritical CO{sub 2}. The pore space within the basins represent hundreds of years of potential storage for supercritical CO{sub 2} and CO{sub 2} stored in aqueous form. There are many sources of CO{sub 2} within the region that could use the trend for geologic storage. Thirty one coal fired power plants are located within 100 miles of the deepest portions of these basins. There are also several cement and ammonia plants near the basins. Sixteen coal fired power plants are present on or adjacent to the basins which could support a low pipeline transportation cost. The current geological information is not sufficient to quantify specific storage reservoirs, seals, or traps. There is insufficient hydrogeologic information to quantify the saline nature of the water present within all of the basins. Water data in the Dunbarton Basin of the Savannah River Site indicates dissolved solids concentrations of greater than 10,000 parts per million (not potential drinking water). Additional reservoir characterization is needed to take advantage of the SGFAR trend for anthropogenic CO{sub 2} storage. The authors of this report believe it would be appropriate to study the reservoir potential in the deeper basins that are in close proximity to the current larger coal fired power plants (Albany-Arabi, Camilla-Ocilla, Alamo-Ehrhardt, and Jedburg basin)

Constraints to liberty of movement and attachment styles significantly account for well-being in three Palestinian samples

Background: Political violence and constraints on liberty of movement can have consequences for health and well-being but affect individuals differently. Objective: In three Palestinian samples, we sought to examine the relationship between key environmental and psychological factors and general and mental health, including the previously unexplored roles of constraints to liberty of movement and attachment orientation. Method: Participants (n=519) in the Occupied Palestinian Territories and Jordan completed questionnaires on constraints to liberty of movement (4-item scale devised by the authors for the purpose of the current study), attachment insecurity (Experiences in Close Relationships Scale – Short Form, Wei et al., 2007), resource loss (Conservation of Resources Evaluation scale, Hobfoll & Lilly, 1993), experience of political violence (Experience and fear of political violence, Hobfoll et al., 2011), demographics, general health (adapted from DeSalvo et al, 2006) and mental health (PHQ4 for depression, and Ballenger et al.’s, (2001) 2 item screener for anxiety). All measures were translated from English to Arabic and back-translated into English. Results: Findings from regression and mediation analyses indicated that (i) differences in general and mental health among Palestinians in the Occupied Palestinian Territories and the diaspora in Jordan, can be explained by the assessed constructs; (ii) constraints to liberty of movement, attachment avoidance, and resource loss significantly accounted for poor general health; (iii) constraints to liberty of movement, attachment anxiety, and resource loss significantly explained general anxiety symptoms; and (iv) attachment anxiety, resource loss, and experience of political violence significantly explained depression symptoms. Conclusion: Findings have theory-building implications for psychological models of human flourishing and suffering, suggesting that they are incomplete without consideration of liberty as a context, as well as implications for policymakers and champions of global health initiatives, as they highlight the psychological effects of constraints to liberty of movement on health

Sediment Properties: E-Area Completion Project

To accommodate a future need for additional waste disposal facilities at the Savannah River Site, the Solid Waste Management Division (SWMD) designated nine additional plots for development (Kasraii 2007; SRS 2010); these plots are collectively known as the E Area Completion Project (ECP). Subsurface samples were collected from ECP plots 6, 7, 8 and 9 (Figure 1) for chemical and physical property analyses to support Performance Assessment (PA) and Special Analyses (SA) modeling. This document summarizes the sampling and analysis scheme and the resultant data, and provides interpretations of the data particularly in reference to existing soil property data. Analytical data in this document include: gamma log, cone penetrometer log, grain size (sieve and hydrometer), water retention, saturated hydraulic conductivity (falling head permeameter), porosity, dry bulk density, total organic carbon, x-ray diffraction, and x-ray fluorescence data. SRNL provided technical and safety oversight for the fieldwork, which included completion of eight soil borings, four geophysical logs, and the collection of 522 feet of core and 33 Shelby tubes from ECP plots 6, 7, 8, and 9. Boart Longyear provided sonic drilling and logging services. Two soil borings were completed at each location. The first set of boreholes extended into (but did not fully penetrate) the Warley Hill Formation. These boreholes were continuously cored, then geophysically (gamma ray) logged. The recovered core was split, photographed, and described; one half of the core was archived at SRS's Core Lab facilities, and the remaining half was consumed as necessary for testing at SRS and off-site labs. Core descriptions and geophysical data were used to calculate target elevations for Shelby tube samples, which were obtained from the second set of boreholes. Shelby tubes were shipped to MACTEC Engineering and Consulting Inc. (MACTEC) in Atlanta for physical property testing. SRNL deployed their Site Characterization and Analysis Penetrometer System (SCAPS) cone penetrometer test (CPT) truck at ECP plots 6, 7, 8 and 9 to collect inferred lithology data for the vadose zone. Results from this study are used to make recommendations for future modeling efforts involving the ECP plots. The conceptual model of the ECP hydrogeology differs from the conceptual model of the current ELLWF disposal area in that for the ECP plots, the topography (ground surface) is generally lower in elevation; The Upland and top of Tobacco Road lithostratigraphic units are missing (eroded); The water table occurs lower in elevation (i.e., it occurs in lower stratigraphic units); and the Tan Clay Confining Zone (TCCZ) often occurs within the vadose zone (rather than in the saturated zone). Due to the difference in the hydrogeology between the current ELLWF location and the ECP plots, different vadose zone properties are recommended for the ECP plots versus the properties recommended by Phifer et al. (2006) for the current disposal units. Results from this study do not invalidate or conflict with the current PA's use of the Upper and Lower Vadose Zone properties as described by Phifer et al. (2006) for the current ELLWF disposal units. The following modeling recommendations are made for future modeling of the ECP plots where vadose zone properties are required: (1) If a single vadose zone property is preferred, the properties described by Phifer et al. (2006) for the Upper Vadose Zone encompass the general physical properties of the combined sands and clays in the ECP vadose zone sediments despite the differences in hydrostratigraphic units. (2) If a dual zone system is preferred, a combination of the Lower Zone properties and the Clay properties described by Phifer et al. (2006) are appropriate for modeling the physical properties of the ECP vadose zone. The Clay properties would be assigned to the Tan Clay Confining Zone (TCCZ) and any other significant clay layers, while the Lower Zone properties would be assigned for the remainder of the vadose zone. No immediate updates or changes are recommended for the saturated zone properties for modeling of the ECP plots. The hydrogeology and saturated hydraulic conductivity values resulting from the ECP work are consistent with existing data for the area. The following recommendations are provided for consideration in future work: (1) When the database is next updated, we recommend checking/refining hydrostratigraphic interpretations (picks) in addition to revising physical property data for both the vadose zone and saturated zone. (2) Results from this work suggest that separate ECP vadose zone properties may be appropriate for the various ECP plots. Consideration should be given to the fact that the plots toward the northwest (ECP plots 6, 7 and 8) all have the TCCZ within the vadose zone whereas the TCCZ occurs within the saturated zone to the east (ECP plot 9). (3) Further data may be needed at ECP plot 7

Removal of Iodide From Groundwater Using Silver Chloride-White Paper

Releases from the F and H Area Seepage Basins on the Savannah River Site (SRS) have caused groundwater plumes that contain a variety of contaminants. These plumes are releasing contaminants into Fourmile Branch, which is a small tributary of the Savannah River. The metallic contaminant releases to the branch are being controlled by base injection. The base injection targets cationic contaminants and was not intended to reduce the concentration of I-129 in groundwater. SRS and the regulatory agencies believe it is appropriate to investigate remedial alternatives that could reduce the I-129. The Savannah River Site Area Closures Projects (ACP) and the Savannah River National Laboratory (SRNL) are developing an innovative in situ treatment for I-129 using silver chloride (AgCl). The proposed AgCl amendment has a very small particle size and is designed to be injected into the contaminated aquifer to capture I-129. The solubility of AgI is several orders of magnitude lower than the solubility of AgCl. Thus, when I-129 comes in contact with AgCl it forms silver iodide (AgI), which is very stable and essentially insoluble in water. SRNL has been performing bench-scale column tests on the effectiveness of silver chloride to capture iodine in an aqueous solution. These initial tests evaluate silver chloride in four different particle sizes; 4-5 millimeters (standard reagent silver chloride), approximately 1 millimeters (sieved reagent silver chloride), approximately 2 micrometers (ultra fine grind without a grinding agent), and <1 micrometer (ultra fine grind with a grinding agent). The first two experiments with macro-sized particles were proof of principle tests. In these the AgCl was mechanically mixed into a portion of the soil filling the columns. The last two were to test the effectiveness of injecting particles suspended in an aqueous solution--the ability to inject the particles, their retention in the column and their effectiveness at removing dissolved iodide from solution. The amendments for these two columns were obtained from a private company specializing in ultra-fine grinding of materials. They were ground in propylene glycol because when ground in water silver metal electroplated onto the steel grinding equipment. Table 1 shows the list of columns and the amendment characteristics. The results of these column experiments demonstrate that solid silver chloride is highly effective at removing dissolved iodine from water and should be an effective amendment for removing I-129 from groundwater. Based on known groundwater chemistry and the reaction of AgCl with I- to produce AgI, the only interference will be natural dissolved stable iodine (I-127). Millings et al. (2002) reported a maximum I-127 concentration of 2.2 ug/L in groundwater from well P-27D, a background water table well near F-Area. The concentration of dissolved iodide used in these experiments is approximately 4500 times this natural concentration. Therefore, a AgCl amendment in the subsurface at the same concentration used in these experiments, might effectively remove I-129 for up to 4500 times the number of pore volumes of groundwater as observed here. This assumes homogeneous distribution of the amendment and no occlusion by other minerals in the subsurface. The only reliable way to evaluate these effects is by trial in the field. The column studies also suggest that the amendment is readily injectable into sediments, but will not be highly mobile. The fact that the effluent from Column 4 shows no iodide breakthrough after nearly 11 pore volumes indicates that some of the injected AgCl was trapped in the column. A mass balance on iodide reacted so far suggests that a minimum of 0.056 grams of silver chloride was trapped in the column to react with the iodide. This is 5.6% of the mass injected. Assume the 1-foot column represents the first foot of sediment in the subsurface into which the amendment is injected. If 5.6% of the AgCl particles are trapped in each subsequent foot of sediment through which the injectate moves, at 100 feet the concentration of particles will be 3% of the injection concentration. This is the maximum possible concentration indicated by these column studies, because far more AgCl may have been trapped in the column. Continued data collection will tell how much more. Dissolved silver concentrations from the silver chloride amendment will be low. Effluent from Column 1 was analyzed for dissolved silver and the concentrations were below the detection limit of 0.2 mg/L

Student mental health profiles and barriers to help seeking: When and why students seek help for a mental health concern

Background The student mental health landscape in higher education requires preventative strategies that maintain daily functioning as well as early intervention to respond to episodes of mental ill-health. As a community, this requires capturing the needs of students in the general university population as well as those using counselling and psychological wellbeing services. Aims This cross-sectional study aimed to characterise the mental health profile of students in the general university population and identify barriers to help seeking. Methods A total of 1,956 students from five UK universities completed an online questionnaire comprising the CCAPS-34 and open-ended questions about their mental health concerns and intentions to seek help. Mental health profiles were explored using mixed factorial ANOVAs and post hoc simple effect analyses. Help-seeking behaviours and intentions were identified using conceptual content analysis. Results Distinctive mental health profiles emerged across faculties and help-seeking behaviours. Content analysis identified students’ help-seeking experiences, intentions, preferences and barriers. Conclusions Characterising the mental health profile of students outside of support services, as well as their barriers to seeking help, provides a rich understanding for shaping preventative policies and service provision. Doing so will respond to student mental health needs before they require clinical intervention

Sediment Properties: E-Area Completion Project

To accommodate a future need for additional waste disposal facilities at the Savannah River Site, the Solid Waste Management Division (SWMD) designated nine additional plots for development (Kasraii 2007; SRS 2010); these plots are collectively known as the E Area Completion Project (ECP). Subsurface samples were collected from ECP plots 6, 7, 8 and 9 (Figure 1) for chemical and physical property analyses to support Performance Assessment (PA) and Special Analyses (SA) modeling. This document summarizes the sampling and analysis scheme and the resultant data, and provides interpretations of the data particularly in reference to existing soil property data. Analytical data in this document include: gamma log, cone penetrometer log, grain size (sieve and hydrometer), water retention, saturated hydraulic conductivity (falling head permeameter), porosity, dry bulk density, total organic carbon, x-ray diffraction, and x-ray fluorescence data. SRNL provided technical and safety oversight for the fieldwork, which included completion of eight soil borings, four geophysical logs, and the collection of 522 feet of core and 33 Shelby tubes from ECP plots 6, 7, 8, and 9. Boart Longyear provided sonic drilling and logging services. Two soil borings were completed at each location. The first set of boreholes extended into (but did not fully penetrate) the Warley Hill Formation. These boreholes were continuously cored, then geophysically (gamma ray) logged. The recovered core was split, photographed, and described; one half of the core was archived at SRS's Core Lab facilities, and the remaining half was consumed as necessary for testing at SRS and off-site labs. Core descriptions and geophysical data were used to calculate target elevations for Shelby tube samples, which were obtained from the second set of boreholes. Shelby tubes were shipped to MACTEC Engineering and Consulting Inc. (MACTEC) in Atlanta for physical property testing. SRNL deployed their Site Characterization and Analysis Penetrometer System (SCAPS) cone penetrometer test (CPT) truck at ECP plots 6, 7, 8 and 9 to collect inferred lithology data for the vadose zone. Results from this study are used to make recommendations for future modeling efforts involving the ECP plots. The conceptual model of the ECP hydrogeology differs from the conceptual model of the current ELLWF disposal area in that for the ECP plots, the topography (ground surface) is generally lower in elevation; The Upland and top of Tobacco Road lithostratigraphic units are missing (eroded); The water table occurs lower in elevation (i.e., it occurs in lower stratigraphic units); and the Tan Clay Confining Zone (TCCZ) often occurs within the vadose zone (rather than in the saturated zone). Due to the difference in the hydrogeology between the current ELLWF location and the ECP plots, different vadose zone properties are recommended for the ECP plots versus the properties recommended by Phifer et al. (2006) for the current disposal units. Results from this study do not invalidate or conflict with the current PA's use of the Upper and Lower Vadose Zone properties as described by Phifer et al. (2006) for the current ELLWF disposal units. The following modeling recommendations are made for future modeling of the ECP plots where vadose zone properties are required: (1) If a single vadose zone property is preferred, the properties described by Phifer et al. (2006) for the Upper Vadose Zone encompass the general physical properties of the combined sands and clays in the ECP vadose zone sediments despite the differences in hydrostratigraphic units. (2) If a dual zone system is preferred, a combination of the Lower Zone properties and the Clay properties described by Phifer et al. (2006) are appropriate for modeling the physical properties of the ECP vadose zone. The Clay properties would be assigned to the Tan Clay Confining Zone (TCCZ) and any other significant clay layers, while the Lower Zone properties would be assigned for the remainder of the vadose zone. No immediate updates or changes are recommended for the saturated zone properties for modeling of the ECP plots. The hydrogeology and saturated hydraulic conductivity values resulting from the ECP work are consistent with existing data for the area. The following recommendations are provided for consideration in future work: (1) When the database is next updated, we recommend checking/refining hydrostratigraphic interpretations (picks) in addition to revising physical property data for both the vadose zone and saturated zone. (2) Results from this work suggest that separate ECP vadose zone properties may be appropriate for the various ECP plots. Consideration should be given to the fact that the plots toward the northwest (ECP plots 6, 7 and 8) all have the TCCZ within the vadose zone whereas the TCCZ occurs within the saturated zone to the east (ECP plot 9). (3) Further data may be needed at ECP plot 7

Congratulations, It’s a Boy! Bench-Marking Children’s Perceptions of the Robokind Zeno-R25

This paper explores three fundamental attributes of the Robokind Zeno-R25 (its status as person or machine, its ‘gender’, and intensity of its simulated facial expressions) and their impact on children’s perceptions of the robot, using a one-sample study design. Results from a sample of 37 children indicate that the robot is perceived as being a mix of person and machine, but also strongly as a male figure. Children could label emotions of the robot’s simulated facial-expressions but perceived intensities of these expressions varied. The findings demonstrate the importance of establishing fundamentals in user views towards social robots in supporting advanced arguments of social human-robot interaction