The rotational shear layer inside the early red-giant star KIC 4448777

We present the asteroseismic study of the early red-giant star KIC 4448777, complementing and integrating a previous work (Di Mauro et al. 2016), aimed at characterizing the dynamics of its interior by analyzing the overall set of data collected by the {\it Kepler} satellite during the four years of its first nominal mission. We adopted the Bayesian inference code DIAMOND (Corsaro \& De Ridder 2014) for the peak bagging analysis and asteroseismic splitting inversion methods to derive the internal rotational profile of the star. The detection of new splittings of mixed modes, more concentrated in the very inner part of the helium core, allowed us to reconstruct the angular velocity profile deeper into the interior of the star and to disentangle the details better than in Paper I: the helium core rotates almost rigidly about 6 times faster than the convective envelope, while part of the hydrogen shell seems to rotate at a constant velocity about 1.15 times lower than the He core. In particular, we studied the internal shear layer between the fast-rotating radiative interior and the slow convective zone and we found that it lies partially inside the hydrogen shell above $r \simeq 0.05R$ and extends across the core-envelope boundary. Finally, we theoretically explored the possibility for the future to sound the convective envelope in the red-giant stars and we concluded that the inversion of a set of splittings with only low-harmonic degree $l\leq 3$, even supposing a very large number of modes, will not allow to resolve the rotational profile of this region in detail.Comment: accepted for publication on Ap

A General Organocatalytic System for Enantioselective Radical Conjugate Additions to Enals

Herein, we report a general iminium ion-based catalytic method for the enantioselective conjugate addition of carbon-centered radicals to aliphatic and aromatic enals. The process uses an organic photoredox catalyst, which absorbs blue light to generate radicals from stable precursors, in combination with a chiral amine catalyst, which secures a consistently high level of stereoselectivity. The generality of this catalytic platform is demonstrated by the stereoselective interception of a wide variety of radicals, including non-stabilized primary ones which are generally difficult to engage in asymmetric processes. The system also served to develop organocatalytic cascade reactions that combine an iminium-ion-based radical trap with an enamine-mediated step, affording stereochemically dense chiral products in one-step

Controle pós-colheita da antracnose do maracujazeiro-amarelo com aplicação de óleo de copaíba.

O objetivo deste trabalho foi avaliar a aplicação de óleo essencial de copaíba no controle da antracnose, nos frutos do maracujazeiro-amarelo, e comparar sua ação fungicida/fungistática in vitro com o óleo resina de copaíba. No experimento in vivo, os frutos foram inoculados com uma suspensão de esporos da ordem de 106 conídios mL-1 e 1% de Tween 80, acondicionados em bandejas de polipropileno e colocados em câmara incubadora com temperatura de 25°C e 90% de umidade relativa do ar. Passadas 24 horas da inoculação, pulverizou-se óleo essencial nas seguintes concentrações: T1= 0 mL L-1; T2= 0,25 mL L-1; T3= 0,5 mL L-1; T4= 0,75 mL L-1; T5= 1,0 mL L-1, sendo avaliados a perda de massa do fruto, a severidade da antracnose e o número de lesões, ambas aos seis dias. Para o experimento in vitro, utilizou-se do meio de cultura batata-dextrose-ágar (BDA) que, após ser esterilizado em autoclave (120 ºC), recebeu óleo essencial e óleo resina de copaíba (0; 0,5; 1,0; 1,5 e 2,0 mL L-1). Após o resfriamento do meio de cultura, foi repicado para o centro da placa um disco de micélio de 12,5 mm de diâmetro de Colletotrichum gloeosporioides; e as placas, incubadas a 25°C e 90% de umidade. A aferição do crescimento micelial foi verificada com o auxílio de paquímetro analógico, após sete dias de crescimento micelial. O óleo essencial de copaíba, nas concentrações de 0,25 mL L-1 a 1.0 mL L-1, não foi eficaz no controle pós-colheita do fungo da antracnose in vivo e na perda de massa dos frutos de maracujá. O óleo resina de copaíba inibiu o crescimento de C. gloeosporioides in vitro de forma mais eficiente que o óleo essencial de copaíba