Hydrodynamic friction of fakir-like super-hydrophobic surfaces

A fluid droplet located on a super-hydrophobic surface makes contact with the surface only at small isolated regions, and is mostly in contact with the surrounding air. As a result, a fluid in motion near such a surface experiences very low friction, and super-hydrophobic surfaces display strong drag-reduction in the laminar regime. Here we consider theoretically a super-hydrophobic surface composed of circular posts (so called fakir geometry) located on a planar rectangular lattice. Using a superposition of point forces with suitably spatially-dependent strength, we derive the effective surface slip length for a planar shear flow on such a fakir surface as the solution to an infinite series of linear equations. In the asymptotic limit of small surface coverage by the posts, the series can be interpreted as Riemann sums, and the slip length can be obtained analytically. For posts on a square lattice, our analytical results are in excellent quantitative agreement with previous numerical computations

Effective velocity boundary condition at a mixed slip surface

This paper studies the nature of the effective velocity boundary conditions for liquid flow over a plane boundary on which small free-slip islands are randomly distributed. It is found that, to lowest order in the area fraction $\beta$ covered by free-slip regions with characteristic size $a$, a macroscopic Navier-type slip condition emerges with a slip length of the order of $a\beta$. The study is motivated by recent experiments which suggest that gas nano-bubbles may form on solid walls and may be responsible for the appearance of a partial slip boundary conditions for liquid flow. The results are also relevant for ultra-hydrophobic surfaces exploiting the so-called ``lotus effect''.Comment: 14 pages, 1 figur

Electro-osmosis on anisotropic super-hydrophobic surfaces

We give a general theoretical description of electro-osmotic flow at striped super-hydrophobic surfaces in a thin double layer limit, and derive a relation between the electro-osmotic mobility and hydrodynamic slip-length tensors. Our analysis demonstrates that electro-osmotic flow shows a very rich behavior controlled by slip length and charge at the gas sectors. In case of uncharged liquid-gas interface, the flow is the same or inhibited relative to flow in homogeneous channel with zero interfacial slip. By contrast, it can be amplified by several orders of magnitude provided slip regions are uniformly charged. When gas and solid regions are oppositely charged, we predict a flow reversal, which suggests a possibility of huge electro-osmotic slip even for electro-neutral surfaces. On the basis of these observations we suggest strategies for practical microfluidic mixing devices. These results provide a framework for the rational design of super-hydrophobic surfaces.Comment: 4 pages, 4 figures; submitted to PRL Revised version: several references added, typos corrected. Supplementary file was restructured, the second part of the original EPAPS was removed and is supposed to be published as a separate pape

Enhanced diffusion by reciprocal swimming

Purcell's scallop theorem states that swimmers deforming their shapes in a time-reversible manner ("reciprocal" motion) cannot swim. Using numerical simulations and theoretical calculations we show here that in a fluctuating environment, reciprocal swimmers undergo, on time scales larger than that of their rotational diffusion, diffusive dynamics with enhanced diffusivities, possibly by orders of magnitude, above normal translational diffusion. Reciprocal actuation does therefore lead to a significant advantage over non-motile behavior for small organisms such as marine bacteria

Statics and dynamics of a cylindrical droplet under an external body force

We study the rolling and sliding motion of droplets on a corrugated substrate by Molecular Dynamics simulations. Droplets are driven by an external body force (gravity) and we investigate the velocity profile and dissipation mechanisms in the steady state. The cylindrical geometry allows us to consider a large range of droplet sizes. The velocity of small droplets with a large contact angle is dominated by the friction at the substrate and the velocity of the center of mass scales like the square root of the droplet size. For large droplets or small contact angles, however, viscous dissipation of the flow inside the volume of the droplet dictates the center of mass velocity that scales linearly with the size. We derive a simple analytical description predicting the dependence of the center of mass velocity on droplet size and the slip length at the substrate. In the limit of vanishing droplet velocity we quantitatively compare our simulation results to the predictions and good agreement without adjustable parameters is found.Comment: Submitted to the Journal of Chemical Physic

Gas Enrichment at Liquid-Wall Interfaces

Molecular dynamics simulations of Lennard-Jones systems are performed to study the effects of dissolved gas on liquid-wall and liquid-gas interfaces. Gas enrichment at walls is observed which for hydrophobic walls can exceed more than two orders of magnitude when compared to the gas density in the bulk liquid. As a consequence, the liquid structure close to the wall is considerably modified, leading to an enhanced wall slip. At liquid-gas interfaces gas enrichment is found which reduces the surface tension.Comment: main changes compared to version 1: flow simulations are included as well as different types of gase