52 research outputs found
Theoretical study of the absorption spectra of the sodium dimer
Absorption of radiation from the sodium dimer molecular states correlating to
Na(3s)-Na(3s) is investigated theoretically. Vibrational bound and continuum
transitions from the singlet X Sigma-g+ state to the first excited singlet A
Sigma-u+ and singlet B Pi-u states and from the triplet a Sigma-u+ state to the
first excited triplet b Sigma-g+ and triplet c Pi-g states are studied
quantum-mechanically. Theoretical and experimental data are used to
characterize the molecular properties taking advantage of knowledge recently
obtained from ab initio calculations, spectroscopy, and ultra-cold atom
collision studies. The quantum-mechanical calculations are carried out for
temperatures in the range from 500 to 3000 K and are compared with previous
calculations and measurements where available.Comment: 19 pages, 8 figures, revtex, eps
Limit on suppression of ionization in metastable neon traps due to long-range anisotropy
This paper investigates the possibility of suppressing the ionization rate in
a magnetostatic trap of metastable neon atoms by spin-polarizing the atoms.
Suppression of the ionization is critical for the possibility of reaching
Bose-Einstein condensation with such atoms. We estimate the relevant long-range
interactions for the system, consisting of electric quadrupole-quadrupole and
dipole-induced dipole terms, and develop short-range potentials based on the
Na_2 singlet and triplet potentials. The auto-ionization widths of the system
are also calculated. With these ingredients we calculate the ionization rate
for spin-polarized and for spin-isotropic samples, caused by anisotropy of the
long-range interactions. We find that spin-polarization may allow for four
orders of magnitude suppression of the ionization rate for Ne. The results
depend sensitively on a precise knowledge of the interaction potentials,
however, pointing out the need for experimental input. The same model gives a
suppression ratio close to unity for metastable xenon in accordance with
experimental results, due to a much increased anisotropy in this case.Comment: 15 pages including figures, LaTex/RevTex, uses epsfig.st
Theoretical study of the absorption spectra of the lithium dimer
For the lithium dimer we calculate cross sections for absorption of radiation
from the vibrational-rotational levels of the ground X [singlet Sigma g +]
electronic state to the vibrational levels and continua of the excited A
[singlet Sigma u +] and B [singlet Pi u] electronic states. Theoretical and
experimental data are used to characterize the molecular properties taking
advantage of knowledge recently obtained from photoassociation spectroscopy and
ultra-cold atom collision studies. The quantum-mechanical calculations are
carried out for temperatures in the range from 1000 to 2000 K and are compared
with previous calculations and measurements.Comment: 20 pages, revtex, epsf, 6 fig
DIPOLE POLARIZABILITIES OF Zn, Cd AND Hg (S)
Author Institution:Effective core potentials (ECP) are used in a calculation of the dipole polarizability of the ground states of the Zn, Cd, and Hg atoms. The trend in the magnitude of the polarizability as a function of increasing Z of the recommended values is reproduced in the calculated polarizabilities using relativistic ECP. Polarizabilities obtained with non-relativistic ECP do not reflect the observed trend and are much too large in magnitude. Compact atomic bases, useful for molecular calculations, are obtained by optimization of the function exponents with respect to both the energy and polarizability
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