The essential oil of Thymbra capitata and its application as a biocide on stone and derived surfaces

Many chemicals used nowadays for the preservation of cultural heritage pose a risk to both human health and the environment. Thus, it is desirable to find new and eco-friendly biocides that can replace the synthetic ones. In this regard, plant essential oils represent effective alternatives to synthetic substances for the preservation of historical monuments. Thymbra capitata (syn. Thymus capitatus) is a medicinal and aromatic plant growing in the Mediterranean area and endowed with important pharmacological properties related to its essential oil. Among them, the antimicrobial ones make the T. capitata essential oil an ideal candidate for industrial applications; for instance, as biocide for the inhibition and elimination of biological patinas of cyanobacteria and green algae on historical monuments. In the present work, we studied the chemical composition of the essential oil from T. capitata growing in Malta by gas chromatography-mass spectrometry (GC/MS). The major volatile component is the phenolic monoterpene carvacrol (73.2%), which is capable of damaging the cytoplasmic membrane and to interfere both in the growth curve and in the invasive capacity, though the contribution of minor components γ-terpinene and p-cymene cannot be disregarded. For the oil application on the stone surface, Pickering emulsions systems were prepared with an essential oil/water 1:3 mass ratio stabilized with kaolinite at 4 mass% in the presence of Laponite®; this allowed to limit the fast volatility of the oil and guaranteed a better application and an easier removal from the artefacts attacked by biodeteriogens both indoor and outdoor. This formulation caused the elimination of biodeteriogens from treated surfaces without residuals or films on artworks surface, and the effect was retained up to four months

Magnetic Raman Scattering of Insulating Cuprates

We study the $B_{1g}$ and $A_{1g}$ Raman profiles of M$_{2}$Cu$O_{4}$ (with M= La, Pr, Nd, Sm, Gd), Bi$_{2}$Sr$_{2}$Ca$_{0.5}$Y$_{0.5}$Cu$_{2}$O$_{8+y}$%, YBa$_{2}$Cu$_{3}$O$_{6.2}$ and PrBa$_{2}$Cu$_{2.7}$Al$_{0.3}$O$_{7}$ insulating cuprates within the Loudon-Fleury theory, in the framework of an extended Hubbard model for moderate on-site Coulomb interaction $U$. We calculate the non-resonant contribution to these Raman profiles by using exact diagonalization techniques and analyze two types of contributing mechanisms to the line shapes: 4-spin cyclic exchange and spin-phonon interactions. Although these interactions contribute to different parts of the spectra, together, they account for the enhanced linewidth and asymmetry of the $B_{1g}$ mode, as well as the non-negligible intensity of the $A_{1g}$ Raman line observed in these materials.Comment: 8 pages, 2 eps figures. To be published in PR

Ice/frost detection using millimeter wave radiometry

A series of ice detection tests was performed on the shuttle external tank (ET) and on ET target samples using a 35/95 GHz instrumentation radiometer. Ice was formed using liquid nitrogen and water spray inside a test enclosure containing ET spray on foam insulation samples. During cryogenic fueling operations prior to the shuttle orbiter engine firing tests, ice was formed with freon and water over a one meter square section of the ET LOX tank. Data analysis was performed on the ice signatures, collected by the radiometer, using Georgia Tech computing facilities. Data analysis technique developed include: ice signature images of scanned ET target; pixel temperature contour plots; time correlation of target data with ice present versus no ice formation; and ice signature radiometric temperature statistical data, i.e., mean, variance, and standard deviation

Excitons in insulating cuprates

We study the electronic excitations near the charge-transfer gap in insulating CuO$_2$ planes, starting from a six-band model which includes $p_\pi$ and $d_{xy}$ orbitals and Cu-O nearest-neighbor repulsion $U_{pd}$. While the low lying electronic excitations in the doped system are well described by a modified $t-J$ model, the excitonic states of the insulator include hybrid $d_{xy}-$ $p_\pi$ states of $A_{2g}$ symmetry. We also obtain excitons of symmetries $B_{1g}$ and $E_u$, and eventually $A_{1g}$, which can be explained within a one-band model. The results agree with observed optical absorption and Raman excitations.Comment: 10 pages and 3 figures in postscript format, compressed with uufile

A 94/183 GHz multichannel radiometer for Convair flights

A multichannel 94/183 GHz radiometer was designed, built, and installed on the NASA Convair 990 research aircraft to take data for hurricane penetration flights, SEASAT-A underflights for measuring rain and water vapor, and Nimbus-G underflights for new sea ice signatures and sea surface temperature data (94 GHz only). The radiometer utilized IF frequencies of 1, 5, and 8.75 GHz about the peak of the atmospheric water vapor absorption line, centered at 183.3 GHz, to gather data needed to determine the shape of the water molecule line. Another portion of the radiometer operated at 94 GHz and obtained data on the sea brightness temperature, sea ice signatures, and on areas of rain near the ocean surface. The radiometer used a multiple lens antenna/temperature calibration technique using 3 lenses and corrugated feed horns at 94 GHz and 183 GHz. Alignment of the feed beams at 94 GHz and 183 GHz was accomplished using a 45 deg oriented reflecting surface which permitted simultaneous viewing of the feeds on alternate cycles of the chopping intervals

A geographic information method for managing urban energy use

This paper presents a geographical information method to support urban-level energy policies. It proposes using a geographical information system to store, display, edit, share and analyse geographical information for territorial decision-making. The method was used to help develop a sustainable energy action plan for the municipality of Randazzo in Sicily, Italy, by providing an accurate representation of actual energy consumption. Based on this case study, the use of a geographical information system appears to be a suitable support tool for both developing and managing sustainable energy action plans, regardless of the geographical area or context. This method will help municipalities estimate and monitor the energy consumption of residential, commercial and industrial buildings and, by taking into account the approaches of different stakeholders, help develop more accurate models for reducing urban carbon dioxide emissions

Strain engineering in Ge/GeSn core/shell nanowires

Strain engineering in Sn-rich group IV semiconductors is a key enabling factor to exploit the direct band gap at mid-infrared wavelengths. Here, we investigate the effect of strain on the growth of GeSn alloys in a Ge/GeSn core/shell nanowire geometry. Incorporation of Sn content in the 10-20 at.% range is achieved with Ge core diameters ranging from 50nm to 100nm. While the smaller cores lead to the formation of a regular and homogeneous GeSn shell, larger cores lead to the formation of multi-faceted sidewalls and broadened segregation domains, inducing the nucleation of defects. This behavior is rationalized in terms of the different residual strain, as obtained by realistic finite element method simulations. The extended analysis of the strain relaxation as a function of core and shell sizes, in comparison with the conventional planar geometry, provides a deeper understanding of the role of strain in the epitaxy of metastable GeSn semiconductors

A 94/183 GHz aircraft radiometer system for Project Storm Fury

A radiometer design suitable for use in NASA's WB-57F aircraft to collect data from severe storm regions was developed. The design recommended was a 94/183 GHz scanning radiometer with 3 IF channels on either side of the 183.3 GHz water vapor line and a single IF channel for a low loss atmospheric window channel at 94 GHz. The development and construction of the 94/183 GHz scanning radiometer known as the Advanced Microwave Moisture Sounder (AMMS) is presented. The radiometer scans the scene below the aircraft over an angle of + or - 45 degrees with the beamwidth of the scene viewed of approximately 2 degrees at 94 GHz and 1 degree at 183 GHz. The AMMS data collection system consists of a microcomputer used to store the radiometer data on the flight cartridge recorder, operate the stepper motor driven scanner, and collect housekeeping data such as thermistor temperature readings and aircraft time code

Temperature dependence of single particle excitations in a S=1 chain: exact diagonalization calculations compared to neutron scattering experiments

Exact diagonalization calculations of finite antiferromagnetic spin-1 Heisenberg chains at finite temperatures are presented and compared to a recent inelastic neutron scattering experiment for temperatures T up to 7.5 times the intrachain exchange constant J. The calculations show that the excitations at the antiferromagnetic point q=1 and at q=0.5 remain resonant up to at least T=2J, confirming the recent experimental observation of resonant high-temperature domain wall excitations. The predicted first and second moments are in good agreement with experiment, except at temperatures where three-dimensional spin correlations are most important. The ratio of the structure factors at q=1 and at q=0.5 is well predicted for the paramagnetic infinite-temperature limit. For T=2J, however, we found that the experimentally observed intensity is considerably less than predicted. This suggests that domain wall excitations on different chains interact up to temperatures of the order of the spin band width.Comment: 9 pages revtex, submitted to PR

Charge-density waves in the Hubbard chain: evidence for 4k_F instability

Charge density waves in the Hubbard chain are studied by means of finite-temperature Quantum Monte Carlo simulations and Lanczos diagonalizations for the ground state. We present results both for the charge susceptibilities and for the charge structure factor at densities \rho=1/6 and 1/3; for \rho=1/2 (quarter filled) we only present results for the charge structure factor. The data are consistent with a 4k_F instability dominating over the 2k_F one, at least for sufficiently large values of the Coulomb repulsion, U. This can only be reconciled with the Luttinger liquid analyses if the amplitude of the 2k_F contribution vanishes above some U^*(\rho).Comment: RevTeX, 4 two-column pages with 7 colour figures embedded in tex