Cooper pair delocalization in disordered media

We discuss the effect of disorder on the coherent propagation of the bound state of two attracting particles. It is shown that a result analogous to the Anderson theorem for dirty superconductors is also valid for the Cooper problem, namely, that the pair wave function is extended beyond the single-particle localization length if the latter is large. A physical justification is given in terms of the Thouless block-scaling picture of localization. These arguments are supplemented by numerical simulations. With increasing disorder we find a transition from a regime in which the interaction delocalizes the pair to a regime in which the interaction enhances localization.Comment: 5 pages, RevTex with 2 figures include

Non-magnetic impurities in two- and three- dimensional Heisenberg antiferromagnets

In this paper we study in a large-S expansion effects of substituting spins by non-magnetic impurities in two- and three- dimensional Heisenberg antiferromagnets in a weak magnetic field. In particular, we demonstrate a novel mechanism where magnetic moments are induced around non-magnetic impurities when magnetic field is present. As a result, Curie-type behaviour in magnetic susceptibility can be observed well below the Neel temperature, in agreement with what is being observed in $La_2Cu_{1-x}Zn_{x}O_4$ and $Sr(Cu_{1-x}Zn_x)_2O_3$ compounds.Comment: Latex fil

Magnetic ordering in Sr2RuO4 induced by nonmagnetic impurities

We report unusual effects of nonmagnetic impurities on the spin-triplet superconductor Sr2RuO4. The substitution of nonmagnetic Ti4+ for Ru4+ induces localized-moment magnetism characterized by unexpected Ising anisotropy with the easy axis along the interlayer c direction. Furthermore, for x(Ti) > 0.03 magnetic ordering occurs in the metallic state with the remnant magnetization along the c-axis. We argue that the localized moments are induced in the Ru4+ and/or oxygen ions surrounding Ti4+ and that the ordering is due to their interaction mediated by itinerant Ru-4d electrons with strong spin fluctuations.Comment: 5 pages, 4figure

Structure and Unprecedented Reactivity of a Mononuclear Nonheme Cobalt(III) Iodosylbenzene Complex

A mononuclear nonheme cobalt(III) iodosylbenzene complex, [CoIII(TQA)(OIPh)(OH)]2+ (1), is synthesized and characterized structurally and spectroscopically. While 1 is a sluggish oxidant in oxidation reactions, it becomes a competent oxidant in oxygen atom transfer reactions, such as olefin epoxidation, in the presence of a small amount of proton. More interestingly, 1 shows a nucleophilic reactivity in aldehyde deformylation reaction, demonstrating that 1 has an amphoteric reactivity. Another interesting observation is that 1 can be used as an oxygen atom donor in the generation of high-valent metal-oxo complexes. To our knowledge, we present the first crystal structure of a CoIII iodosylbenzene complex and the unprecedented reactivity of metal-iodosylarene adduct

Enhancement of electronic anomalies in iron-substituted La_2-x_Sr_x_Cu_1-y_Fe_y_O_4_ around x=0.22

We have measured the temperature dependences of Rho and Chi for Fe-substituted La_2-x_Sr_x_Cu_1-y_Fe_y_O_4_ in the overdoped regime, in order to investigate Fe-substitution effects on electronic properties around x=0.22. From the Rho measurements, it has been found around x=0.22 that the values of Rho are large at room temperature and that Rho exhibits a pronounced upturn at low temperatures. Moreover, from the Rho and Chi measurements, it has been found that T_c_ is anomalously depressed around x=0.22. These results indicate that the electronic anomalies around x=0.22 are enhanced by Fe substitution, which might be related to the development of stripe correlations by Fe substitution.Comment: 7 pages, 3 figure

Spin Dynamics near the Superconductor-to-Insulator Transition in Impurity-Doped YBa2Cu4O8

We studied low-frequency spin dynamics near the impurity-induced superconductor-to-insulator transition for underdoped high-Tc superconductor YBa2(Cu1-xMx)4O8 (M=Ni, Zn) using the Cu nuclear quadrupole resonance (NQR) spin-echo technique. We observed remarkable suppression of the normal-state pseudo spin-gap and a loss of Cu NQR spectrum intensity at low temperatures around the critical impurity concentration.Comment: 6 pages, 4 figures. To be published in J. Phys. Soc. Jpn. Vol.70, No.7 (2001

Charge Localization from Local Destruction of Antiferromagnetic Correlation in Zn-doped YBa2Cu3O7-d

The in-plane normal-state resistivity of Zn-doped YBa2Cu3O7-d single crystals is measured down to low temperatures by suppressing superconductivity with magnetic fields up to 18 T. Substitution of Cu with Zn in the CuO2 planes is found to induce carrier localization at low temperatures in "clean" samples with kF l > 5, where the mean free path l is larger than the electron wave length and thus localization is not normally expected. The destruction of the local antiferromagnetic correlation among Cu spins by Zn is discussed to be the possible origin of this unusual charge localization.Comment: 4 pages of LaTeX (revtex and epsf) including 4 postscript figure

Finite temperature transport at the superconductor-insulator transition in disordered systems

I argue that the incoherent, zero-frequency limit of the universal crossover function in the temperature-dependent conductivity at the superconductor-insulator transition in disordered systems may be understood as an analytic function of dimensionality of system d, with a simple pole at d=1. Combining the exact result for the crossover function in d=1 with the recursion relations in d=1+\epsilon, the leading term in the Laurent series in the small parameter \epsilon for this quantity is computed for the systems of disordered bosons with short-range and Coulomb interactions. The universal, low-temperature, dc critical conductivity for the dirty boson system with Coulomb interaction in d=2 is estimated to be 0.69 (2e)^2 /h, in relatively good agreement with many experiments on thin films. The next order correction is likely to somewhat increase the result, possibly bringing it closer to the self-dual value.Comment: 9 pages, LaTex, no figure

Unusual T_c variation with hole concentration in Bi_2Sr_{2-x}La_xCuO_{6+\delta}

We have investigated the $T_c$ variation with the hole concentration $p$ in the La-doped Bi 2201 system, Bi$_2$Sr$_{2-x}$La$_x$CuO$_{6+\delta}$. It is found that the Bi 2201 system does not follow the systematics in $T_c$ and $p$ observed in other high-$T_c$ cuprate superconductors (HTSC's). The $T_c$ vs $p$ characteristics are quite similar to what observed in Zn-doped HTSC's. An exceptionally large residual resistivity component in the inplane resistivity indicates that strong potential scatterers of charge carriers reside in CuO$_2$ planes and are responsible for the unusual $T_c$ variation with $p$, as in the Zn-doped systems. However, contrary to the Zn-doped HTSC's, the strong scatter in the Bi 2201 system is possibly a vacancy in the Cu site.Comment: RevTeX, 3 figures, to be published in the Physical Review

N-(4-Ferrocenylphenyl)benzamide

In the title compound, [Fe(C5H5)(C18H14NO)], the unsubstituted cyclo­penta­dienyl ring is disordered over two sets of sites with occupancy ratio of 0.55 (1):0.45 (1). One conformation has the rings eclipsed and the other staggered. An intra­molecular C—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, inter­molecular C—H⋯O and N—H⋯O hydrogen bonds lead to R 2 1(7) ring motifs. The mol­ecules are linked into polymeric chains extending along the b axis