Agronomic approaches for the remediation of contaminated soils

Contaminated soils can only be efficiently managed if proper procedures are adopted for evaluating the risks due to contamination as well as the actual volume of contaminated soil [...

The Ecoremed protocol for an integrated agronomic approach to characterization and remediation of contaminated soils

Definition of a site as contaminated: Problems related to agricultural soils Massimo Fagnano.......... pp. 1-5 Geography of soil contamination for characterization and precision remediation of potentially contaminated sites Giuliano Langella, Antonietta Agrillo, Angelo Basile, Roberto De Mascellis, Piero Manna, Pierpaolo Moretti, Florindo Antonio Mileti, Fabio Terribile, Simona Vingiani.......... pp. 6-15 Assessing the bioavailability of potentially toxic elements in soil: A proposed approach Claudia Rocco, Diana Agrelli, Maria Tafuro, Antonio Giandonato Caporale, Paola Adamo.......... pp. 16-22 Use of the native vascular flora for risk assessment and management of an industrial contaminated soil Donato Visconti, Nunzio Fiorentino, Adriano Stinca, Ida Di Mola, Massimo Fagnano.......... pp. 23-33 Assisted phytoremediation for restoring soil fertility in contaminated and degraded land Nunzio Fiorentino, Mauro Mori, Vincenzo Cenvinzo, Luigi Giuseppe Duri, Laura Gioia, Donato Visconti, Massimo Fagnano.......... pp. 34-44 Bioassays for evaluation of sanitary risks from food crops cultivated in potentially contaminated sites Luigi Giuseppe Duri, Nunzio Fiorentino, Eugenio Cozzolino, Lucia Ottaiano, Diana Agrelli Massimo Fagnano.......... pp. 45-52 Responses of bacterial community structure and diversity to soil eco-friendly bioremediation treatments of two multi-contaminated fields Valeria Ventorino, Vincenza Faraco, Ida Romano, Olimpia Pepe.......... pp. 53-58 Monitoring and modelling the role of phytoremediation to mitigate non-point source cadmium pollution and groundwater contamination at field scale Mario Palladino, Paolo Nasta, Alessandra Capolupo, Nunzio Romano.......... pp. 59-6

CliFEM - Climate Forcing and Erosion Modelling in the Sele River Basin (Southern Italy)

Abstract. This study presents a revised and scale-adapted Foster-Meyer-Onstad model (Foster et al., 1977) for the transport of soil erosion sediments under scarce input data, with the acronym CliFEM (Climate Forcing and Erosion Modelling). This new idea was addressed to develop a monthly time scale invariant Net Erosion model (NER), with the aim to consider the different erosion processes operating at different time scales in the Sele River Basin (South Italy), during 1973–2007 period. The sediment delivery ratio approach was applied to obtain an indirect estimate of the gross erosion too. The examined period was affected by a changeable weather regime, where extreme events may have contributed to exacerbate soil losses, although only the 19% of eroded sediment was delivered at outlet of the basin. The long-term average soil erosion was very high (73 Mg ha−1 per year ± 58 Mg ha−1). The estimate of monthly erosion showed catastrophic soil losses during the soil tillage season (August–October), with consequent land degradation of the hilly areas of the Sele River Basin

Agronomic approaches for characterization, remediation, and monitoring of contaminated sites

With a view to conserving or improving soil ecosystem services, environment-friendly techniques, such as bio- and phytoremediation, can effectively be used for the characterization, risk assessment, and remediation of contaminated agricultural sites. Polyannual vegetation (meadows, poplar, and cane stands) is widely considered the most efficient tool for remediation (extraction of bioavailable fraction of contaminants), for undertaking safety measures (reducing the mobility of contaminants towards other environmental compartments), and for restoring the ecosystem services of contaminated agricultural sites (biomass production, groundwater protection, C storage, landscape quality improvement, and cultural and educational services). The roles of agronomic approaches will be reviewed by focusing on the various steps in the whole remediation process: (i) detailed environmental characterization; (ii) phytoremediation for reducing risks for the environment and human health; (iii) agronomic management for improving efficiency of phytoremediation; and (iv) biomass recycling in the win-win perspective of the circular economy

Effects of different fertilizers on quantity and quality of silage corn

Different fertilizers, ammonia sulfate and urea (MIN), Fertil 12.5 (ORG) and Azoslow (ORG-MIN) were compared in a silage corn crop. Total biomass yield was above 55.0 t ha-1 for all fertilizers. Azoslow showed the highest dry matter content (40.8%). No differences among the fertilizers were found in protein content (4.9% on average) at waxy ripening, with the control showing the lowest value (3.9%). There were also no differences in silage quality among the fertilizers. The N budget was estimated in order to quantify the residual nitrogen amounts at harvest and the efficiency of fertilizers

Biofuel production with castor bean: A win-win strategy for marginal land

The urgency to reduce resource depletion and waste production is expected to lead to an economy based on renewable resources. Biofuels, for instance, are a great green alternative to fossil fuel, but they are currently derived from edible vegetable oils such as soybean, palm, and sunflower. Concerns have been raised about the social-economic implication and ecological impacts of biodiesel production. Cultivating new lands as biodiesel feedstock rather than food supply, with the consequent increase in food prices, leads to so-called indirect land-use change (ILUC). Establishing bioenergy crops with phytoremediation ability on contaminated soils offers multiple benefits such as improving soil properties and ecosystem services, decreasing soil erosion, and diminishing the dispersion of potentially toxic elements (PTEs) into the environment. Castor bean is an unpalatable, high-biomass plant, and it has been widely demonstrated to possess phytoremediation capability for several PTEs. Castor bean can grow on marginal lands not suitable for food crops, has multiple uses as a raw material, and is already used in biodiesel production. These characteristics make it perfect for sustainable biodiesel production. Linking biofuel production with environmental remediation can be considered a win-win strategy

Health-related internet use among adolescents with uncontrolled persistent asthma

Objectives To describe internet use for health information among adolescents with uncontrolled persistent asthma, and to examine whether health-related internet use is associated with responsibility for home asthma management. Methods We analyzed baseline data from the School-Based Asthma Care for Teens (SB-ACT) Trial, which included adolescents (12–16 years) in an urban school district who had uncontrolled persistent asthma per caregiver report. We asked adolescents whether they had ever used the Internet to look for health or medical information (Y/N). Teens then described family responsibility for 9 asthma management tasks (e.g. full caregiver responsibility, shared responsibility, or full teen responsibility). We examined responsibility sum scores in addition to responsibility for individual management tasks. We used bivariate and multivariate analyses to compare health-related internet use with participant characteristics, teen-reported asthma symptoms, and management responsibility. Results We examined data for 425 adolescents (mean age 13.4 years). Almost half (45%) reported seeking health information on the Internet. In adjusted analyses, health-related internet use was strongly associated with teen responsibility (sum score and tasks relating to carrying and using medications); internet use was also more likely among teens who were older, female, or reported uncontrolled disease. Conclusions Adolescents with persistent asthma who share responsibility for home management or report uncontrolled disease are more likely to seek health information online. Future interventions to support teens who co-manage asthma should work to engage patients in both clinical and digital spaces, and ensure that all patients can access accurate, patient-centered asthma information when needed

Potentially toxic element availability and risk assessment of cadmium dietary exposure after repeated croppings of brassica juncea in a contaminated agricultural soil

Phytoextraction of potentially toxic elements (PTEs) is eco-friendly and cost-effective for remediating agricultural contaminated soils, but plants can only take up bioavailable forms of PTEs, thus meaning that bioavailability is the key for the feasibility of this technique. With the aims to assess the phytoextraction efficiency on an agricultural soil contaminated by Cr, Zn, Cd, and Pb and the changes induced by plants in PTE bioavailability and in human health risk due to dietary exposure, in this work we carried out a mesocosm experiment with three successive croppings of Brassica juncea, each followed by Rocket salad as bioindicator. Brassica juncea extracted more Zn and Cd than Cr and Pb, significantly reducing, after three repeated croppings, the bioavailable element concentrations in soil as a result of plant uptake and soil pH changes. For Cd, this reduction did not bring the bioavailable amounts obtained by soil extraction with NH4NO3 below the trigger value of 0.1 mg kg−1 set by some European countries. Nevertheless, the Hazard Quotient for Cd in Rocket salad decreased across three repeated croppings of Brassica juncea. This indicated the beginning of a re-equilibration process between soil PTE forms of different bioavailability, that are in a dynamic equilibrium, thus stressing the need to monitor the possible regeneration of the most readily bioavailable pool

Use of giant reed (Arundo donax L.) to control soil erosion and improve soil quality in a marginal degraded area

Soil erosion is one of the biggest environmental problems throughout European Union causing considerable soil losses. Vegetation cover provides an important soil protection against runoff and soil erosion. To this aim, unlike annual crops, perennial plants have the advantage of covering soil for a longer time and reducing soil erodibility thanks to SOM increase due to litter effect and to reduction of soil disturbance (no-tillage). Two experiments were carried out in marginal hilly areas (10% slope) of Southern Italy: i) long-term experiment in which it was evaluated the effect of two fertilization doses (N: 100 and 50 kg N ha−1 from urea) on Arundo donax L. biomass production as well as its effect on soil erosion; ii) three-year experiment to evaluate the soil cover capacity of the giant reed by analysing the plant leaf area index (LAI). Results of the two experiments showed a good soil protection of Arundo donax L. that reduced soil losses by 78% as compared to fallow and showed soil erosion reduction not different from permanent meadow thanks to the soil covering during the period with the highest rain erosivity and to the reduction in soil erodibility. The protective effect of Arundo donax L. from rain erosivity was also confirmed by LAI analysis that showed a good soil covering of giant reed in the above mentioned period, even during the initial yield increasing phase following crop transplant. According to biomass yield, from the fifteen year of cultivation in a low fertile inland hilly area of Southern Italy, giant reed was characterized by a yield-decreasing phase that resulted postponed as compared to more fertile environments thus ensuring a longstanding soil protection from soil erosion. In addition, the higher nitrogen fertilization dose (100 kg ha−1 of N) allowed interesting biomass yield as compared to the lower dose (50 kg N ha−1) and kept constant SOC along the year of experimentation due to an improved contribution of leaf fall, root exudates and root turnover to soil. o

Inherent Metal Elements in Biomass Pyrolysis: A Review

One of the main drawbacks of using biomass as pyrolysis feedstock consists of the huge variability of the different biomass resources which undermines the viability of downstream processes. Inherent inorganic elements greatly contribute to enhance the compositional variability issues due to their catalytic effect (especially alkali and alkaline earth metals (AAEMs)) and the technical problems arising due to their presence. Due to the different pretreatments adopted in the experimental investigations as well as the different reactor configurations and experimental conditions, some mechanisms involving interactions between these elements and the biomass organic fraction during pyrolysis are still debated. This is the reason why predicting the results of these interactions by adapting the existing kinetic models of pyrolysis is still challenging. In this work, the most prominent experimental works of the last 10 years dealing with the catalytic effects of biomass inherent metals on the pyrolysis process are reviewed. Reaction pathways, products distributions and characteristics, and impacts on the products utilization are discussed with a focus on AAEMs and on potential toxic metallic elements in hyperaccumulator plants. The literature findings are discussed in relation to the applied laboratory procedures controlling the concentration of inherent inorganic elements, their capability of preserving the chemical integrity of the main organic components, and the ability of resembling the inherent inorganic elements in the raw biomass. The goal is to reveal possible experimental inconsistencies and to provide a clear scheme of the reaction pathways altered by the presence of inherent inorganics. This analysis paves the way for the examination of the proposed modifications of the existing models aiming at capturing the effect of inorganics on pyrolysis kinetics. Finally, the most relevant shortcomings and bottlenecks in existing experimental and modeling approaches are analyzed and directions for further studies are suggested