Estimating global geodetic parameters using SLR observations to Galileo, GLONASS, BeiDou, GPS, and QZSS

Abstract All Galileo, GLONASS, QZSS, and BeiDou satellites are equipped with laser retroreflector arrays dedicated to satellite laser ranging (SLR). Using SLR data to new GNSS systems allows for estimating global geodetic parameters, such as Earth rotation parameters, global scale, and geocenter coordinates. In this study, we evaluate the quality of global geodetic parameters estimated on a basis of SLR tracking of new GNSS satellites and the combined solution based on SLR observations to GNSS and LAGEOS. We show that along with a progressive populating of Galileo orbital planes, the quality of geocenter components based on SLR–GNSS data has been improved to the level of 6 and 15 mm for equatorial and polar geocenter components, respectively. The scale of the reference frame and the geocenter coordinates in the combined LAGEOS + GNSS solutions are dominated by the LAGEOS data. Some noncore SLR stations provide by far more observations to GNSS than to LAGEOS, e.g., Russian and Chinese stations dedicated to supporting GLONASS and BeiDou constellations. The number of solutions for these stations can be increased by up to 40%, whereas the station coordinate repeatability can be improved from about 20–30 mm to the level of 15–20 mm when considering both SLR to LAGEOS and SLR to GNSS

Silver(I) complex with 2-amino-4,4α-dihydro-4α,7-dimethyl-3<i>H</i>-phenoxazin-3-one (Phx-1) ligand: crystal structure, vibrational spectra and biological studies

<p>The first metal complex of Phx-1 ligand, bis(2-amino-4,4α-dihydro-4α,7-dimethyl-3<i>H</i>-phenoxazin-3-one)nitratosilver(I), [Ag(Phx-1)₂NO₃], has been obtained and investigated by single crystal X-ray diffraction and vibrational spectroscopy methods. The Ag⁺ is bonded to heterocyclic nitrogen atoms of two organic ligands and one oxygen atom of a nitrate anion. The Phx-1 ligand coordination mode is supported by IR and Raman spectra, interpreted with the help of theoretical DFT studies. The antibacterial activity of the ligand and its Ag(I) complex as well as some reference compounds were screened against Gram-positive and Gram-negative bacteria, applying microdilution procedures. High sensitivity to the studied complex was found for <i>Rhodococcus erythropolis</i> and <i>Bacillus licheniformis</i> strains. Modified Phx-1 ligand preparation procedures are also presented.</p