Montagem e caracterização elétrica de pilhas a combustível de óxido sólido (PaCOS) Assembly and electrical characterization of solid oxide fuel cell stacks

<abstract language="eng">This paper is focused on a review of the design features and the electrochemistry characterization of anode-supported planar SOFC. Studies and results of metallic alloy interconnectors and recovery for protection against corrosion and for contact layer are showed. Moreover a discussion of examples of measurements of impedance spectrometry, according to the literature and our experimental results are made. For the anode supported fuel cells the power density varies from 0.1 to 0.5 Wcm², according to results in the literature (showed in this paper). For electrolyte supported fuel cell the power density can be 10 Wcm-2 for high temperatures. An English-Portuguese glossary of most used terms in SOFC stack is given for greater clarity and to introduce new terms to the reader

Synthesis and characterization of NiO-YSZ for SOFCs

Nickel oxide and yttria-stabilized zirconia ceramic materials were prepared by three methods: physical mixture, a modified Pechini route, and impregnation with Ni(NO3)2·6H2O. Temperature-programmed reduction (TPR) analysis showed the presence of different reduction peaks for each sample and that the reduction temperature was influenced by the employed preparation procedure. Nickel oxide species are completely reduced at temperatures up to 1000 °C and their temperature-programmed reduction profiles indicated that a higher temperature reduction corresponds to a higher calcination temperature. Furthermore, the composites synthesized through impregnation presented nickel oxide species more easily reducible than those prepared by the two other methods. Scanning electron microscopy and X-ray photoelectron spectroscopy (XPS) evidenced a larger nickel oxide coating on yttria-stabilized zirconia for the composite synthesized through the impregnation method. The electrical conductivity of impregnation sample was 117 S cm-1 at 850 °C, a value three times higher than that of the physical mixture.Fil: Martins, R. F.. Universidade Federal de Minas Gerais; BrasilFil: Brant, Márcia Caldeira. Universidade Federal de Minas Gerais; BrasilFil: Domingues, Rosana Zacarias. Universidade Federal de Minas Gerais; BrasilFil: Paniago, Roberto M.. Universidade Federal de Minas Gerais; BrasilFil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Matencio, Túlio. Universidade Federal de Minas Gerais; Brasi