464 research outputs found
Low temperature dielectric relaxation study of aqueous solutions of diethylsulfoxide
In the present work, dielectric spectra of mixtures of diethylsulfoxide
(DESO) and water are presented, covering a concentration range of 0.2 - 0.3
molar fraction of DESO. The measurements were performed at frequencies between
1 Hz and 10 MHz and for temperatures between 150 and 300 K. It is shown that
DESO/water mixtures have strong glass-forming abilities. The permittivity
spectra in these mixtures reveal a single relaxation process. It can be
described by the Havriliak-Negami relaxation function and its relaxation times
follow the Vogel-Fulcher-Tammann law, thus showing the typical signatures of
glassy dynamics. The concentration dependence of the relaxation parameters,
like fragility, broadening, and glass temperature, are discussed in detail.Comment: 20 pages, 5 figure
Apparent giant dielectric constants, dielectric relaxation, and ac-conductivity of hexagonal perovskites La1.2Sr2.7BO7.33 (B = Ru, Ir)
We present a thorough dielectric investigation of the hexagonal perovskites
La1.2Sr2.7IrO7.33 and La1.2Sr2.7RuO7.33 in a broad frequency and temperature
range, supplemented by additional infrared measurements. The occurrence of
giant dielectric constants up to 10^5 is revealed to be due to electrode
polarization. Aside of dc and ac conductivity contributions, we detect two
intrinsic relaxation processes that can be ascribed to ionic hopping between
different off-center positions. In both materials we find evidence for charge
transport via hopping of localized charge carriers. In the infrared region,
three phonon bands are detected, followed by several electronic excitations. In
addition, these materials provide further examples for the occurrence of a
superlinear power law in the broadband ac conductivity, which recently was
proposed to be a universal feature of all disordered matter.Comment: 8 pages, 7 figure
Nonlinear dielectric response at the excess wing of glass-forming liquids
We present nonlinear dielectric measurements of glass-forming glycerol and
propylene carbonate applying electrical fields up to 671 kV/cm. The
measurements extend to sufficiently high frequencies to allow for the
investigation of the nonlinear behavior in the regime of the so-far mysterious
excess wing, showing up in the loss spectra of many glass formers as a second
power law at high frequencies. Surprisingly, we find a complete lack of
nonlinear behavior in the excess wing, in marked contrast to the
alpha-relaxation where, in agreement with previous reports, a strong increase
of dielectric constant and loss is found.Comment: 8 pages (including 3 pages Supplementary Information), 4 + 1 figures.
Revised according to suggestions of referee
Non-intrinsic origin of the Colossal Dielectric Constants in CaCu3Ti4O12
The dielectric properties of CaCu3Ti4O12, a material showing colossal values
of the dielectric constant, were investigated in a broad temperature and
frequency range extending up to 1.3 GHz. A detailed equivalent circuit analysis
of the results and two crucial experiments, employing different types of
contacts and varying sample thickness, provide clear evidence that the
apparently high values of the dielectric constant in CaCu3Ti4O12 are
non-intrinsic and due to electrode polarization effects. The intrinsic
properties of CaCu3Ti4O12 are characterized by charge transport via hopping of
localized charge carriers and a relatively high dielectric constant of the
order of 100.Comment: 4 pages, 4 figure
Multiferroicity and colossal magneto-capacitance in Cr-thiospinels
The sulfur based Cr-spinels RCr2S4 with R = Cd and Hg exhibit the coexistence
of ferromagnetic and ferroelectric properties together with a pronounced
magnetocapacitive coupling. While in CdCr2S4 purely ferromagnetic order is
established, in HgCr2S4 a bond-frustrated magnetic ground state is realized,
which, however, easily can be driven towards a ferromagnetic configuration in
weak magnetic fields. This paper shall review our recent investigation for both
compounds. Besides the characterization of the magnetic properties, the complex
dielectric permittivity was studied by means of broadband dielectric
spectroscopy as well as measurements of polarization hysteresis and
pyro-currents. The observed colossal magneto-capacitive effect at the magnetic
transition seems to be driven by an enormous variation of the relaxation
dynamics.Comment: 10 pages, 11 figure
Multiferroic behavior in CdCr2X4 (X = S, Se)
The recently discovered multiferroic material CdCr2S4 shows a coexistence of
ferromagnetism and relaxor ferroelectricity together with a colossal
magnetocapacitive effect. The complex dielectric permittivity of this compound
and of the structurally related CdCr2Se4 was studied by means of broadband
dielectric spectroscopy using different electrode materials. The observed
magnetocapacitive coupling at the magnetic transition is driven by enormous
changes of the relaxation dynamics induced by the development of magnetic
order
Dielectric and conductivity relaxation in mixtures of glycerol with LiCl
We report a thorough dielectric characterization of the alpha relaxation of
glass forming glycerol with varying additions of LiCl. Nine salt concentrations
from 0.1 - 20 mol% are investigated in a frequency range of 20 Hz - 3 GHz and
analyzed in the dielectric loss and modulus representation. Information on the
dc conductivity, the dielectric relaxation time (from the loss) and the
conductivity relaxation time (from the modulus) is provided. Overall, with
increasing ion concentration, a transition from reorientationally to
translationally dominated behavior is observed and the translational ion
dynamics and the dipolar reorientational dynamics become successively coupled.
This gives rise to the prospect that by adding ions to dipolar glass formers,
dielectric spectroscopy may directly couple to the translational degrees of
freedom determining the glass transition, even in frequency regimes where
usually strong decoupling is observed.Comment: 8 pages, 7 figure
Broadband dielectric response of CaCu3Ti4O12: From dc to the electronic transition regime
We report on phonon properties and electronic transitions in CaCu3Ti4O12, a
material which reveals a colossal dielectric constant at room temperature
without any ferroelectric transition. The results of far- and mid-infrared
measurements are compared to those obtained by broadband dielectric and
millimeter-wave spectroscopy on the same single crystal. The unusual
temperature dependence of phonon eigenfrequencies, dampings and ionic plasma
frequencies of low lying phonon modes are analyzed and discussed in detail.
Electronic excitations below 4 eV are identified as transitions between full
and empty hybridized oxygen-copper bands and between oxygen-copper and
unoccupied Ti 3d bands. The unusually small band gap determined from the
dc-conductivity (~200 meV) compares well with the optical results.Comment: 7 pages, 8 figure
Colossal magnetocapacitance and colossal magnetoresistance in HgCr2S4
We present a detailed study of the dielectric and charge transport properties
of the antiferromagnetic cubic spinel HgCr2S4. Similar to the findings in
ferromagnetic CdCr2S4, the dielectric constant of HgCr2S4 becomes strongly
enhanced in the region below 60 - 80 K, which can be ascribed to polar
relaxational dynamics triggered by the onset of ferromagnetic correlations. In
addition, the observation of polarization hysteresis curves indicates the
development of ferroelectric order below about 70 K. Moreover, our
investigations in external magnetic fields up to 5 T reveal the simultaneous
occurrence of magnetocapacitance and magnetoresistance of truly colossal
magnitudes in this material.Comment: 4 pages, 4 figure
Debye relaxation and 250 K anomaly in glass forming monohydroxy alcohols
A previous dielectric, near-infrared (NIR), and nuclear magnetic resonance
study on the hydrogen-bonded liquid 2-ethyl-1-hexanol [C. Gainaru et al., Phys.
Rev. Lett. 107, 118304 (2011)] revealed anomalous behavior in various static
quantities near 250 K. To check whether corresponding observations can be made
for other monohydroxy alcohols as well, these experimental methods were applied
to such substances with 5, 6, 7, 8, and 10 carbon atoms in their molecular
backbone. All studied liquids exhibit a change of behavior near 250 K which is
tentatively ascribed to effects of hydrogen bond cooperativity. By analyzing
the NIR band intensities, a linear cluster size is derived that agrees with
estimates from dielectric spectroscopy. All studied alcohols, except
4-methyl-3-heptanol, display a dominant Debye-like peak. Furthermore, neat
2-ethyl-1-butanol exhibits a well resolved structural relaxation in its
dielectric loss spectrum which so far has only been observed for diluted
monohydroxy alcohols.Comment: 39 pages including 12 figure
- …