1 research outputs found
Robust Cage-Based Zinc–Organic Frameworks Derived Dual-Doped Carbon Materials for Supercapacitor
Electrochemical
double layer capacitors can store electrical energy
by accumulating electrolyte ions on the electrode surface and are
playing an important role in renewable energy sources due to their
high power density and superior durability. Owing to the excellent
electrical, mechanical, and thermal characteristics, three-dimensional
multiporous carbon nanomaterials are catching considerable attention
which could lead to the high-rate supercapacitor performance. Here,
we present a stable 1.7 nm cage-based metal–organic framework
(<b>BMM-9</b>, [Zn<sub>2</sub>(TPO)<sub>4/3</sub>(dabco)·Solvent])
with high porosity of 62.4%. On the other hand, after the thermal
treatment at high temperature, the three-dimensional MOF-derived micro/mesoporous
carbon material <b>BMM-9-900</b> acts as dual-doped active electrode
materials and shows a capacitance of 182.8 F g<sup>–1</sup> at a current density of 1 A g<sup>–1</sup>, and a capacity
retention of 98.5% over 1000 cycles. Given the well-established structural
tunability, these outcomes will shed light on a new generation of
MOF-derived supercapacitors whose active materials can be tunable
at the molecular level