2 research outputs found
Synthesis and reactions of aminopropenes, which contains functional groups
Π ΡΠ°ΠΌΠΊΠ°Ρ
Π΄Π°Π½Π½ΠΎΠΉ ΡΠ°Π±ΠΎΡΡ ΠΎΡΡΡΠ΅ΡΡΠ²Π»Π΅Π½ ΡΠΈΠ½ΡΠ΅Π· Π΅Π½Π°ΠΌΠΈΠ½ΠΎΠ², ΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠΈΡ
ΠΎΡΡΠ°ΡΠΊΠΈ ΠΏΠ΅ΡΠ²ΠΈΡΠ½ΡΡ
, Π²ΡΠΎΡΠΈΡΠ½ΡΡ
, ΡΡΠ΅ΡΠΈΡΠ½ΡΡ
Π°ΠΌΠΈΠ½ΠΎΠ², Π° ΡΠ°ΠΊΠΆΠ΅ Π°ΠΌΠΈΠ΄Π½ΡΡ ΠΈ ΡΠΈΠΎΠ°ΠΌΠΈΠ΄Π½ΡΡ Π³ΡΡΠΏΠΏΡ. ΠΡΠΎΠ²Π΅Π΄Π΅Π½ΠΎ ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠ½ΠΎΠ΅ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠ΅ ΡΡΡΡΠΊΡΡΡΡ ΠΏΠΎΠ»ΡΡΠ΅Π½Π½ΡΡ
ΡΠΎΠ΅Π΄ΠΈΠ½Π΅Π½ΠΈΠΉ Ρ ΠΏΠΎΠΌΠΎΡΡΡ ΡΠΏΠ΅ΠΊΡΡΠ°Π»ΡΠ½ΡΡ
ΠΌΠ΅ΡΠΎΠ΄ΠΎΠ², Π²ΠΊΠ»ΡΡΠ°Ρ ΠΌΠ°ΡΡ-ΡΠΏΠ΅ΠΊΡΡΡ, ΠΠ-ΡΠΏΠ΅ΠΊΡΡΡ, ΡΠΏΠ΅ΠΊΡΡΡ Π―ΠΠ 1Π ΠΈ 13Π‘, Π° ΡΠ°ΠΊΠΆΠ΅ ΡΠ΅Π½ΡΠ³Π΅Π½ΠΎΡΡΡΡΠΊΡΡΡΠ½ΡΠΉ Π°Π½Π°Π»ΠΈΠ·. ΠΠ·ΡΡΠ΅Π½Π° ΡΠ΅Π°ΠΊΡΠΈΡ ΠΎΠΊΠΈΡΠ»ΠΈΡΠ΅Π»ΡΠ½ΠΎΠΉ ΡΠΈΠΊΠ»ΠΈΠ·Π°ΡΠΈΠΈ ΠΏΡΠΎΠΏΠ΅Π½ΡΠΈΠΎΠ°ΠΌΠΈΠ΄ΠΎΠ² ΠΈ ΠΏΠΎΠ»ΡΡΠ΅Π½ ΡΡΠ΄ Π½ΠΎΠ²ΡΡ
2,5-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎΠΈΠ·ΠΎΡΠΈΠ°Π·ΠΎΠ»ΠΈΠΌΠΈΠ½ΠΈΠ΅Π²ΡΡ
ΡΠΎΠ»Π΅ΠΉ. ΠΠ·ΡΡΠ΅Π½ΠΎ Π²Π·Π°ΠΈΠΌΠΎΠ΄Π΅ΠΉΡΡΠ²ΠΈΠ΅ Π΅Π½Π°ΠΌΠΈΠ½ΠΎΠ² Ρ ΠΠΠΠ.In this work, the synthesis of enamines containing residues of primary, secondary, tertiary amines as well as the amide and thioamide group has been done. A comprehensive study of the structure for the synthesized compounds has been made by spectral methods including mass spectra, IR, 1H and 13C NMR, and X-ray analysis. The reaction of oxidative cyclization of propentioamides has been investigated and as a result it was obtained a series of
2,5-dihydroizotiazoliminiun salts. The interaction of enamines with DMAD has been studied.ΠΡΠΎΠ³ΡΠ°ΠΌΠΌΠ° ΡΠ°Π·Π²ΠΈΡΠΈΡ Π£ΡΠ€Π£ Π½Π° 2013 Π³ΠΎΠ΄ (ΠΏ.1.2.2.3
Unexpected result for the acylation of arylhydrazonoethanethioamides
The acylation of arylhydrazonoethanethioamides containing primary amino group did not yield acylthioamides as expected. Surprisingly, the cyclic 5-acylimino-2,5-dihydro-1,2,3-thiadiazoles were obtained. The formation of thiadiazoles in this reaction was explained by the higher ability of arylhydrazono-N-acylthioacetamide intermediates to be oxidized comparing to their precursors. The presence of pseudobicyclic aromatic structure in the reaction product was a main factor favoring the formation of 1,2,3-thiadiazole ring. Β© 2013 Elsevier Ltd. All rights reserved