Mechanical Behavior of Hybrid Connectors for Rapid-Assembling Steel-Concrete Composite Beams

In order to achieve a kind of shear connector suitable for rapid-assembling steel-concrete composite beams, a new type of hybrid shear connectors is proposed, in which the concrete slab with prefabricated circular holes and the steel beam with welded studs are installed and positioned, and then epoxy mortar is filled in the prefabricated hole to fix the studs. To study the mechanical behavior of these hybrid connectors, test on 18 push-out specimens with different prefabricated circular holes are carried out. ABAQUS finite element software is adopted to verify the relationship between the numerical simulation and experiment, influences of the epoxy mortar strength and prefabricated circular holes diameter are studied. The results show that filling epoxy mortar in the prefabricated hole is beneficial to improve the stiffness and bearing capacity of the specimen; the change of epoxy mortar strength has a certain impact on the bearing capacity and stiffness of the hybrid connector; In the case of the same strength of the filling material, the size of the prefabricated circular holes diameter directly affects the stiffness and bearing capacity of the shear stud. The shear capacity equations proposed by considering the epoxy mortar strength and prefabricated holes diameter, and it has a wide applicability

Synergistically Enhanced Optical Limiting Property of Graphene Oxide Hybrid Materials Functionalized with Pt Complexes

Recently, graphene-based materials have become well-known nonlinear optical materials for the potential application of laser protection. Two new graphene oxide–platinum  complex (GO–Pt) hybrid materials (GO–Pt-1, GO–Pt-2) have been fabricated through covalent modification and electrostatic adsorption of different Pt complexes with GO. The structural and photophysical properties of the resultant hybrid materials were studied. The nonlinear optical properties and optical power limiting (OPL) performance of Pt complexes, GO, and GO–Pt hybrid materials were investigated by using <i>Z</i>-scan measurements at 532 nm. At the same transmittance, the results illustrate that functionalization of GO makes GO–Pt hybrid materials possess better nonlinear optical properties and OPL performance than individual Pt complexes and GO due to a combination of nonlinear scattering, nonlinear absorption, and photoinduced electron and energy transfer between GO and Pt complex moieties. Furthermore, the nonlinear optics and OPL performance of GO–Pt-2 are better than those of GO–Pt-1, due to not only the excellent optical limiting of Pt-2 and more molecules per area of GO but also the way of combination of Pt-2 and GO