Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates

This tutorial review highlights the organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium/azolium enolates. The generation and synthetic utility of these powerful intermediates is highlighted through their application in various methodologies including aldol-lactonisations, Michael-lactonisations/lactamisations and [2,3]-rearrangements.Publisher PDFPeer reviewe

Exact Quantum States for all Two-Dimensional Dilaton Gravity Theories

It is shown that the recently obtained quantum wave functionals in terms of the CJZ variables for generic 2d dilaton gravity are equivalent to the previously reported exact quantum wave functionals in geometrical variables. A third representation of these exact quantum states is also presented

Interface Collisions

We provide a theoretical framework to analyze the properties of frontal collisions of two growing interfaces considering different short range interactions between them. Due to their roughness, the collision events spread in time and form rough domain boundaries, which defines collision interfaces in time and space. We show that statistical properties of such interfaces depend on the kinetics of the growing interfaces before collision, but are independent of the details of their interaction and of their fluctuations during the collision. Those properties exhibit dynamic scaling with exponents related to the growth kinetics, but their distributions may be non-universal. These results are supported by simulations of lattice models with irreversible dynamics and local interactions. Relations to first passage processes are discussed and a possible application to grain boundary formation in two-dimensional materials is suggested.Comment: Paper with 12 pages and 2 figures; supplemental material with 4 pages and 3 figure

Spinning Relativistic Particle in an External Electromagnetic Field

The Hamiltonian formulation of the motion of a spinning relativistic particle in an external electromagnetic field is considered. The approach is based on the introduction of new coordinates and their conjugated momenta to describe the spin degrees of freedom together with an appropriate set of constraints in the Dirac formulation. For particles with gyromagnetic ratio $g=2$, the equations of motion do not predict any deviation from the standard Lorentz force, while for $g \neq 2$ an additional force, which corresponds to the magnetic dipole force, is obtained.Comment: Latex file, 11 page

Vegetation and peat characteristics of restiad bogs on Chatham Island (Rekohu), New Zealand

Restiad bogs dominated by Sporadanthus traversii on Chatham Island, New Zealand, were sampled to correlate vegetation patterns and peat properties, and to compare with restiad systems dominated by Sporadanthus ferrugineus and Empodisma minus in the Waikato region, North Island, New Zealand. Classification and ordination resulted in five groups that reflected a disturbance gradient. The largest S. traversii group, which comprised plots from central, relatively intact bogs, had the lowest levels of total nitrogen (mean 1.20 mg cm-3), total phosphorus (mean 0.057 mg cm-3), total potassium (mean 0.083 mg cm-3), and available phosphorus (mean 18.6 μg cm-3). Modification by drainage, stock, and fires resulted in a decline of S. traversii and an increase of Gleichenia dicarpa fern cover, together with elevated peat nutrient levels and higher bulk density. Compared with peat dominated by Sporadanthus ferrugineus or Empodisma minus in relatively unmodified Waikato restiad bogs, Chatham Island peat under S. traversii has significantly higher total potassium, total nitrogen, available phosphorus, bulk density, and von Post decomposition indices, and significantly lower pH. Sporadanthus traversii and Empodisma minus have similar ecological roles in restiad bog development, occupying a relatively wide nutrient range, and regenerating readily from seed after fire. Despite differences in root morphology, S. traversii and E. minus are the major peat formers in raised restiad bogs on Chatham Island and in Waikato, respectively, and could be regarded as ecological equivalents

Impact of the Redheaded Pine Sawfly (Hymenoptera: Diprionidae) on Young Red Pine Plantations

The ecology of the redheaded pine sawfly was studied relative to its impact on red pine plantations. An ecological model, which formed the basis for socioeconomic analysis, was constructed. Because the sawfly prefers trees under moisture stress, damage is most severe in stands growing on sand blows, where there is competition for moisture from bracken fern and hardwoods, and where soils are too moist, too shallow, or too compacted. Outbreaks also appear to be related to dry years. The sawfly has a variable impact on multiple-use values. Because it injures the least productive trees in a stand, timber is only indirectly affected. Small openings created by tree mortality after an outbreak may provide edge \u27Wildlife habitat. The sawfly has both negative and positive effects on recreationists, depending upon the type of recreation; it may be a nuisance to campers, but may positively influence hunting. Preventive sawfly management involves proper site selection for red pine