973 research outputs found
Mesoporous carbon nitride-silica composites by a combined sol-gel/thermal condensation approach and their application as photocatalysts
Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Mesoporous carbon nitrides, silicas and their composites have been prepared by a combined sol–gel and thermal condensation approach. Precursors for the carbon nitride (cyanamide) and silica (TEOS) are mixed and condensed simultaneously. After condensation and heat treatment it is observed that the carbon nitride and silica formed highly interpenetrating mesophases which leads either to the formation of mesoporous carbon nitride or silica after selective removal of one of the phases. Importantly, the carbon nitride preserves its graphitic stacking even in the spatial confinement introduced by the surrounding silica phase. As both precursors are liquids this approach allows convenient shaping into thin and thick films or monoliths of mesoporous carbon nitrides. Enhanced photocatalytic activity is observed for the production of hydrogen from water when these mesoporous carbon nitrides are applied as photocatalyst in comparison to the bulk, but also to other mesoporous carbon nitrides, prepared by the reported two-step, hard templating approach.BMBF, 03IS2071D, Light2Hydroge
Piezo-Polymer-Composite Unimorph Actuators for Active Cancellation of Flow Instabilities Across Airfoils
Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.This article presents a smart device for active cancellation of flow instabilities. An array of two piezo unimorph actuators fabricated in piezo-polymer-composite technology is combined with a thin silicone membrane to mimic a movable wall with a closed surface. By locally displacing the thin membrane, a surface wave is generated that interferes with naturally occurring flow instabilities within the boundary layer of an airfoil. Using flow sensors and an intelligent control enables a destructive interference and therefore, an attenuation of natural flow instabilities. This leads to a delay of transition. The boundary layer remains laminar which means drag is reduced. Within the next pages, the setup of the device with actuators, membrane, sensors, and control is introduced. The main focus of this article is on actuator design, modeling, and implementation for wind tunnel experiments. Results of actuator characterization are presented. The non-linear behavior of the piezoactuator (harmonic distortions and impact of high electric fields) is investigated in detail. This study concludes with the results obtained in wind tunnel experiments which prove the functionality of the presented approach. A maximal attenuation of natural occurring flow instabilities of 80% is achieved.DFG, SPP 1207, Strömungsbeeinflussung in der Natur und Techni
Aid conditionalities, international Good Manufacturing Practice standards and local production rights: a case study of local production in Nepal
© 2015 Brhlikova et al. This is an Open Access article distributed under the terms of the Creative Commons Attribution License
(http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium,
provided the original work is properly credited. The Creative Commons Public Domain Dedication waiver (http://
creativecommons.org/publicdomain/zero/1.0/) applies to the data made available in this article, unless otherwise stated.This work was supported by the Economic and Social Research Council and
the Department for International Development [RES-167-25-0110] through
the collaborative research project
Tracing Pharmaceuticals in South Asia
(2006
–
2009). In addition to the authors of this paper, the project team
included: Soumita Basu, Gitanjali Priti Bhatia, Erin Court, Abhijit Das, Stefan
Ecks, Patricia Jeffery, Roger Jeffery, Rachel Manners, and Liz Richardson.
Martin Chautari (Kathmandu) and the Centre for Health and Social Justice
(New Delhi) provided resources drawn upon in writing this paper but are
not responsible for the views expressed, nor are ESRC or DFID.
Ethical review was provided by the School of Social and Political Science at
the University of Edinburgh, and ethical approval in Nepal for the study
granted by the Nepal Health Research Council (NHRC)
Nonlocal electromagnetic fields near a metal/vacuum interface
A nonlocal formalism is developed to describe the fields at the surface of an electron gas subjected to an incident electromagnetic wave. The electron gas is confined to a semi-infinite half space by an infinite potential barrier; the positive lattice of ions is taken to be a jellium. The response tensor of the electron gas is separated into contributions from the bulk metal and the surface of the metal. A relationship is found between the tensor elements of the bulk contribution to the response and the Lindhard dielectric functions;Specific attention is given to the physical differences in the fieldsresulting from the semi-classical specular scattering model, aRandom Phase Approximation with self-consistent wave functions,and the fully quantum mechanical infinite barrier model. Thesurface-region fields can be understood in terms of elementaryexcitations of the electron gas. The inverse longitudinal dielectric;function and the energy loss function are discussed. Thepossibility of a collective, longitudinal surface mode is presented;(\u271)DOE Report IS-T-1041. This work was performed under ContractNo. W-7405-eng-82 with the Department of Energy
Role of deep levels and interface states in the capacitance characteristics of all‐sputtered CuInSe2/CdS solar cell heterojunctions
All‐sputtered CuInSe2/CdS solar cellheterojunctions have been analyzed by means of capacitance‐frequency (C‐F) and capacitance‐bias voltage (C‐V) measurements. Depending on the CuInSe2 layer composition, two kinds of heterojunctions were analyzed: type 1 heterojunctions (based on stoichiometric or slightly In‐rich CuInSe2 layers) and type 2 heterojunctions (based on Cu‐rich CuInSe2 layers). In type 1 heterojunctions, a 80‐meV donor level has been found. Densities of interface states in the range 101 0–101 1 cm2 eV− 1 (type 1) and in the range 101 2–101 3 cm− 2 eV− 1 (type 2) have been deduced. On the other hand, doping concentrations of 1.6×101 6 cm− 3 for stoichiometric CuInSe2 (type 1 heterojunction) and 8×101 7 cm− 3 for the CdS (type 2 heterojunction) have been deduced from C‐Vmeasurements
Approche structurée pour les modèles d'index 2 à entrée dérivée
International audienceThis paper reveals a practical manner to deal with the control design of dynamical systems governed by input derivative index-2 first order differential algebraic equations. This class of dynamical model embeds a polynomial which results in a infinite gain in high frequencies. The idea is grounded on the construction of an adequate SISO controller structure to make possible the control design on a model presenting both rational and a first order polynomial parts. The design approach then leads to a controller in a rational form without any algebraic constrain, which can be implemented on a real-time target. Application for gust load control of a complex aeroservoelastic aircraft dynamical model, which naturally embeds an input derivative action, illustrates the approach, using an H∞-norm minimization performance objective
Orbit Determination of Close Binary Systems using Lucky Imaging
We present relative positions of visual binaries observed during 2009 with
the FastCam "lucky-imaging" camera at the 1.5-m Carlos Sanchez Telescope (TCS)
at the Observatorio del Teide. We obtained 424 CCD observations (averaged in
198 mean relative positions) of 157 binaries with angular separations in the
range 0.14-15.40", with a median separation of 0.51". For a given system, each
CCD image represents the sum of the best 10-25% images from 1000-5000
short-exposure frames. Derived internal errors were 7 mas in r and 1.2^{\circ}
(9 mas) in q. When comparing to systems with very well-known orbits, we find
that the rms deviation in r residuals is 23 mas, while the rms deviation in q
residuals is 0.73 deg/r. We confirmed 18 Hipparcos binaries and we report new
companions to BVD 36 A and J 621 B. For binaries with preliminary orbital
parameters, the relative radial velocity was estimated as well. We also present
four new revised orbits computed for LDS 873, BU 627 A-BC, BU 628 and HO 197
AB. This work is the first results on visual binaries using the FastCam
lucky-imaging camera.Comment: 23 pages, 10 figures, 14 tables, accepted August 18th, 2011, to be
published in MNRA
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