Creep of plasma sprayed zirconia

Specimens of plasma-sprayed zirconia thermal barrier coatings with three different porosities and different initial particle sizes were deformed in compression at initial loads of 1000, 2000, and 3500 psi and temperatures of 1100 C, 1250 C, and 1400 C. The coatings were stabilized with lime, magnesia, and two different concentrations of yttria. Creep began as soon as the load was applied and continued at a constantly decreasing rate until the load was removed. Temperature and stabilization had a pronounced effect on creep rate. The creep rate for 20% Y2O3-80% ZrO2 was 1/3 to 1/2 that of 8% Y2O3-92% ZrO2. Both magnesia and calcia stabilized ZrO2 crept at a rate 5 to 10 times that of the 20% Y2O3 material. A near proportionality between creep rate and applied stress was observed. The rate controlling process appeared to be thermally activated, with an activation energy of approximately 100 cal/gm mole K. Creep deformation was due to cracking and particle sliding

The Subcolonization and Buildup of \u3ci\u3eTetrastichus Julis,\u3c/i\u3e (Hymenoptera: Eulophidae) a Larval Parasitoid of the Cereal Leaf Beetle, (Coleoptera: Chrysomelidae) in the Lower Peninsula of Michigan

Following initial establishment of the parasitoid, Tetrastichus julis (Walker), at a carefully managed field nursery, releases of parasitized Oulema melanopus larvae were made by Michigan county agents at preselected sites throughout the lower peninsula during 1970-74. A follow-up recovery program during 1971-75 revealed continued dispersion and population increase for T. julis. An independent census verified the increasing rates of parasitism

Method of preparing zinc orthotitanate pigment

Zinc orthotitanate suitable for use as a pigment for spacecraft thermal control coatings is prepared by heating a slightly zinc deficient reaction mixture of precipitated oxalates of zinc and titanium. The reaction mixture can be formed by coprecipitation of zinc and titanium oxalates from chloride solution or by mixing separately precipitated oxalates. The mixture is first heated to 400 to 600 C to remove volatiles and is then rapidly heated at 900 to 1200 C. Zinc orthotitanate produced by this method exhibits the very fine particle size needed for thermal control coatings as well as stability in a space environment

Two-channel Kondo physics in tunnel-coupled double quantum dots

We investigate theoretically the possibility of observing two-channel Kondo (2CK) physics in tunnel-coupled double quantum dots (TCDQDs), at both zero and finite magnetic fields; taking the two-impurity Anderson model (2AIM) as the basic TCDQD model, together with effective low-energy models arising from it by Schrieffer-Wolff transformations to second and third order in the tunnel couplings. The models are studied primarily using Wilson's numerical renormalization group. At zero-field our basic conclusion is that while 2CK physics arises in principle provided the system is sufficiently strongly-correlated, the temperature window over which it could be observed is much lower than is experimentally feasible. This finding disagrees with recent work on the problem, and we explain why. At finite field, we show that the quantum phase transition known to arise at zero-field in the two-impurity Kondo model (2IKM), with an essentially 2CK quantum critical point, persists at finite fields. This raises the prospect of access to 2CK physics by tuning a magnetic field, although preliminary investigation suggests this to be even less feasible than at zero field.Comment: 10 pages, 8 figures. Version as published in PR

Study of the normal and pathological intestinal flora of infants and very young children

The aim has been to ascertain the bacteriological conditions obtaining in the intestine of infants and young children, in health, and when suffering from diarrhoea. The healthy children have been divided into classes according to the nature of the feeding -- breast fed children, bottle fed children, and children on a mixed. diet. The flora of the children suffering from diarrhoea has been studied and by a comparison with normal cases, an attempt Was made to arrive at conclusions as to the cause of diarrhoea. The cases of diarrhoea studied were not cases of Epidemic Summer Diarrhoea. They occurred during the very cold and wet summer of 1912, and during the winter following. I hesitate, however, to call them cases of Sporadic Diarrhoea, as there was some evidence that some cases had derived infection from others, or that some common factor was at, work. All through, as was suggested to me by Dr. Ritchie, I have endeavoured_ to study the flora as a whole, and tried not to be seduced into the particular study of one group of organisms to the exclusion of others. This has involved the formulation and practice of a somewhat lengthy scheme of routine examination. A total of 56 specimens has been examined. Of these, 11 are not included in the present thesis as they were used while studying means of isolation in order to formulate a satisfactory routine examination. 3 others are not included as they were older children suffering from intestinal indigestion. 21 cases free from diarrhoea, and which always had been free from diarrhoea were put through the routine examination. These cases throughout the thesis I have called normal. I wish to say that by this I mean completely free from diarrhoea. Many of the children were not healthy. 14 cases suffering from diarrhoea have been studied, and in addition 4 specimens from cases convalescent, or recovered, from diarrhoea have been obtained, as well as the specimens obtained from the same cases while the diarrhoea was at its worst. A specimen of faeces and a catheter specimen of urine were also obtained from 3 cases of Coli Pyelitis with the object of comparing the colon bacilli of urine and faeces

Plasma-sprayed self-lubricating coatings

One of the most important criterion for acceptable commercial application of a multiple phase composition is uniformity and reproducibility. This means that the performance characteristics of the coat - e.g., its lubricating properties, bond strength to the substrate, and thermal properties - can be readily predicted to give a desired performance. The improvement of uniformity and reproducibility of the coats, the oxidation behavior at three temperature ranges, the effect of bond coat and the effect of preheat treatment as measured by adhesive strength tests, coating examination procedures, and physical property measurements were studied. The following modifications improved the uniformity and reproducibility: (1) changes and closer control in the particle size range of the raw materials used, (2) increasing the binder content from 3.2% to 4.1% (dried weight), and (3) analytical processing procedures using step by step checking to assure consistency

Interplay between Kondo physics and spin-orbit coupling in carbon nanotube quantum dots

We investigate the influence of spin-orbit coupling on the Kondo effects in carbon nanotube quantum dots, using the numerical renormalization group technique. A sufficiently large spin-orbit coupling is shown to destroy the SU(4) Kondo effects at zero magnetic field, leaving only two SU(2) Kondo effects in the one- and three-electron Coulomb blockade valleys. On applying a finite magnetic field, two additional, spin-orbit induced SU(2) Kondo effects arise in the three- and two-electron valleys. Using physically realistic model parameters, we calculate the differential conductance over a range of gate voltages, temperatures and fields. The results agree well with measurements from two different experimental devices in the literature, and explain a number of observations that are not described within the standard framework of the SU(4) Anderson impurity model.Comment: 15 pages, 11 figure