Role of the synthesis route on the properties of hybrid LDH-graphene as basic catalysts

Layered double hydroxides (LDH or HT) or their derived mixed oxides present marked acid-base properties useful in catalysis, but they lead to agglomerate inducing a weak accessibility to the active sites. In this study we report the preparation and characterization of HT/Graphene (HT/rGO) nanocomposites as active and selective basic catalysts for the acetone condensation reaction. The graphene high specific surface area and structural compatibility with the HT allowed increasing the number and accessibility of the active sites and activity of this later. Two series of HT/rGO nanocomposites with 0.5 = HT/rGO = 10 mass ratio were prepared by: i) direct HT coprecipitation in the presence of GO; ii) self-assembly of preformed HT with GO. The prepared HT/rGO nanocomposites were dried either in air at 80 °C or freeze-dried. A series of characterizations showed the great influence of the preparation method and HT/rGO mass ratio on both the nanocomposite structure and catalytic activity. An optimum activity was observed for a HT/rGO = 10 catalyst. Particularly, the highest catalytic activity was found in those nanocomposites obtained by coprecipitation and freeze dried (3 times more active than bulk HT) which can be connected to their structure with a better accessibility to the basic sites.Postprint (author's final draft

Finite Length Analysis of Caching-Aided Coded Multicasting

In this work, we study a noiseless broadcast link serving $K$ users whose requests arise from a library of $N$ files. Every user is equipped with a cache of size $M$ files each. It has been shown that by splitting all the files into packets and placing individual packets in a random independent manner across all the caches, it requires at most $N/M$ file transmissions for any set of demands from the library. The achievable delivery scheme involves linearly combining packets of different files following a greedy clique cover solution to the underlying index coding problem. This remarkable multiplicative gain of random placement and coded delivery has been established in the asymptotic regime when the number of packets per file $F$ scales to infinity. In this work, we initiate the finite-length analysis of random caching schemes when the number of packets $F$ is a function of the system parameters $M,N,K$. Specifically, we show that existing random placement and clique cover delivery schemes that achieve optimality in the asymptotic regime can have at most a multiplicative gain of $2$ if the number of packets is sub-exponential. Further, for any clique cover based coded delivery and a large class of random caching schemes, that includes the existing ones, we show that the number of packets required to get a multiplicative gain of $\frac{4}{3}g$ is at least $O((N/M)^g)$. We exhibit a random placement and an efficient clique cover based coded delivery scheme that approximately achieves this lower bound. We also provide tight concentration results that show that the average (over the random caching involved) number of transmissions concentrates very well requiring only polynomial number of packets in the rest of the parameters.Comment: A shorter version appeared in the 52nd Annual Allerton Conference on Communication, Control, and Computing (Allerton), 201

On the processing of dense hetero-nanostructured metallic materials for improved strength / ductility balance by ecae and sps methods

This paper has examined some recent findings concerning the processing of fully dense hetero-nanostructured materials (i.e. consisting of nano, ultrafine and micrometric grains) which can be produced by using the interplay between heavy deformation and recrystallization. By plastic deformation of bulk materials, an improved strength/ductility balance can be obtained directly by imparting high strain deformation (by ECAE) until the occurrence of recrystallization. Using a powder metallurgy route, the strong potential of electric field assisted sintering (ECAS) techniques for producing multi-scale microstructures when a milled powder is used is demonstrated. In this case, in addition to modifying the classic processing parameters (time/temperature of SPS), altering the nature of the milled powder - by Y2O3 addition during the milling stage - is also a good way to delay the onset of recrystallization and, thereby, increase the fraction of ultrafine grains

Efficiency and Environmental Factors in the US Electricity Transmission Industry

The electricity industry in most developed countries has been restructured over recent decades with the aim of improving both service quality and firms’ performance. Regulated segments (e.g. transmission) still provide the infrastructure for the competitive segments and represent a notable amount of the total price paid by final customers. However there is a lack of empirical studies that analyze firms’ performance in the electricity transmission sector. We conduct an empirical analysis of the US electricity transmission companies for the period 2001-2009. We use stochastic frontier models that allow us to identify determinants of firms’ inefficiency and to control for weather conditions, potentially one of the most decisive uncontrollable factors in electricity transportation. Our results suggest that there is room for improvement in the performance of the US electricity transmission system. Regulators should also take into account that more adverse conditions generate higher levels of inefficiency and that achieving long-term efficiency improvements tends to deteriorate firms’ short-term relative performance