1 research outputs found
Structural Modification of Xanthate Collectors To Enhance the Flotation Selectivity of Chalcopyrite
A modified
xanthate compound similar to xanthogen formates, <i>S</i>-benzoyl <i>O</i>-isobutyl xanthate (BIBX), was
designed by introducing a carbonyl and a benzyl group into the xanthate
structure. The preparation, recovery performance, and mechanism of
adsorption of this compound to chalcopyrite is discussed. BIBX was
synthesized using a one-pot approach with superior efficiency, which
has important commercial implications. BIBX’s performance in
the recovery of and mechanism of adsorption to chalcopyrite was investigated
via flotation tests, adsorption quantity measurements, FTIR spectroscopy,
X-ray photoelectron spectroscopy (XPS), and density functional theory
(DFT) calculations. The results show that BIBX displays a substantially
stronger collecting ability toward chalcopyrite than sodium isobutyl
xanthate and <i>O</i>-isopropyl-<i>N</i>-ethylthionocarbamate.
Moreover, BIBX displays superior selectivity for chalcopyrite compared
to pyrite. The adsorption data indicate that BIBX can be applied under
slightly acidic or alkaline conditions. BIBX behaves like a bidentate
ligand, bonding with the chalcopyrite copper through the thiol sulfur
and carbonyl oxygen atoms. These findings are supported by FTIR and
XPS data. DFT calculations predict two distinct adsorption geometries,
one with one Cu atom to form a six-membered ring complex and another
with two Cu atoms to form an “irregular pentagon”-shaped
complex