Influence of SiO2, TiO2 and Fe2O3 nanoparticles on the properties of fly ash blended cement mortars

This study explores the effects of different types of nanoparticles, namely nano-SiO2 (NS), nano-TiO2 (NT), and nano-Fe2O3 (NF) on the fresh properties, mechanical properties, and microstructure of cement mortar containing fly ash as a supplementary cementitious material. These nanoparticles existed in powder form and were incorporated into the mortar at the dosages of 1%, 3%, and 5% wt.% of cement. Also, fly ash has been added into in mortars with a constant dosage of 30% wt.% of cement. Compressive and flexural strength tests were performed to evaluate the mechanical properties of the mortar specimens with different nanoparticles at three curing ages, 7, 14, and 28 days. Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) tests were conducted to study the microstructure and the hydration products of the mortars. To elucidate the effects of nanoparticles on the binder phase, additional experiments were performed on accompanying cement pastes: nanoindentation and open porosity measurements. The study shows that, if added in appropriate amounts, all nanoparticles investigated can result in significantly improved mechanical properties compared to the reference materials. However, exceeding of the optimal concentration results in clustering of the nanoparticles and reduces the mechanical properties of the composites, which is accompanied with increasing the porosity. This study provides guidelines for further improvement of concretes with blended cements through use of nanoparticles

Multi-phase modelling of multi-species transport in concrete: In case of electrochemical protection for both ASR and chloride attack

Existing reinforced concrete structures experience severe durability degradation when subjected to alkali–silica reaction (ASR) and chloride attack. A special electrochemical rehabilitation treatment, containing lithium compound anolyte, has been developed to drive lithium ions into concrete as well as remove chlorides simultaneously, for mitigating both the ASR-induced cracks and the chloride-induced corrosion. Good performance of introduced lithiums in controlling ASR-induced expansion has already been proved. Unfortunately, the migration mechanism of lithium in concrete under an external electric field is seldom investigated in existing literature. In this study, with help of the “double-multi” model, the efficiency of impregnation of lithium ions and simultaneously the removal of chloride ions through a specific electrochemical treatment are numerically evaluated, which results into the distribution profiles of all typical ionic species. The heterogeneous concrete model examines the aggregate effect, especially on the interaction with lithiums which are supposed to mitigate ASR. The ionic interaction between different species and the electrochemical reaction at electrodes are also considered. Through a relative thorough modelling of multiphase and multi-species, a systemic parametric analysis based on a series of significant factors during electrochemical treatment (e.g., current density, treatment time, temperature, cathode position and concentration of lithium solution) reveals some important tendencies of ionic electromigration in concrete, which are supposed to guide the field application

A Numerical Study of Moisture and Ionic Transport in Unsaturated Concrete by Considering Multi-ions Coupling Effect

Understanding the transport mechanisms within unsaturated porous media is essential to the durability problems associated with cement-based materials. However, the involvement of multi-ions electrochemical coupling effect, especially under unsaturated condition makes the transport mechanisms even more complex. In this study, the moisture and multi-ionic transport in unsaturated concrete have been modeled in three-dimensional cases. The contribution from both water vapor and liquid has been considered in moisture transport. By adopting the constitutive electrochemical law, the electrostatic potential induced by inherent charge imbalance was calculated. With parameter calibration, the numerical results agreed well with the experimental data, proving the validity of the presented model. Results from a parametric analysis showed that neglecting multi-ions coupling effect will lead to an underestimated chloride concentration, and saturated degree has an obvious impact on the coupling strength among different ions. In addition, the existence of coarse aggregates will not only block mass transport but also make the discrepancies between two-dimensional model and three-dimensional model results more obvious. Other findings which have not been reported in existing studies are also highlighted.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Materials and Environmen

A novel lattice model to predict chloride diffusion coefficient of unsaturated cementitious materials based on multi-typed pore structure characteristics

This paper develops a novel lattice diffusive model to quantitatively study the chloride diffusion coefficient in unsaturated cementitious materials, in which the pore voxels are redistributed to make a better representation of a real microstructure of hardened cement paste. Considering the hierarchical microstructure and different drying-wetting cycles, water distributions in multiscale pore structures are modelled and the structure characteristics of water-filled pores, including water connectivity, water tortuosity and effective porosity, are computationally extracted based on that. A lattice diffusion network is established to predict relative chloride diffusion coefficient by combining the effect of both water saturation degree and pore structure characteristics. The predicted results are validated against experimental data, and a concise analytical equation is proposed to predict the relative chloride diffusion coefficient. The equation indicated that the relative chloride diffusion coefficient is proportional to water connectivity but inversely proportional to the square of water tortuosity. Besides, the lattice model's quantitative results reveal that the water connectivity and water tortuosity are highly related to pre-water loading processes, and influenced by the gel pore fraction, which in turn will affect the relative chloride diffusion coefficient. Compared with existing equations and non-redistributed models, the present model could improve the prediction accuracy significantly.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Materials and Environmen

Modelling and Simulation for Concrete Durability: Mechanism and Prediction

Materials and Environmen

Influence of coarse aggregate settlement induced by vibration on long-term chloride transport in concrete: a numerical study

High-frequency vibration helps to improve the compactness of concrete, but also causes the settlement of coarse aggregates (CAs) and then affects the durability of hardened concrete. In this paper, a numerical study combining multi-phase CA settlement model and multi-component ionic transport model is performed to understand the influence of vibration-induced settlement on long-term chloride transport in concrete. Through parametric analysis, the influence mechanism of relevant factors on both chloride profile distribution and reinforcement corrosion initiation is discussed in detail. The results indicate that with the increase of vibration time, a decrease of chloride concentration appears in the bottom part of concrete specimen and a significant increase in the top part, because more CAs deposit in the bottom layer. Due to sedimentation, a more obvious fluctuation of chloride concentration along the height direction can be observed in the concrete mixed with a larger density and particle size of CAs. According to the model prediction, the corrosion of the top steel bar initiates 1.03–1.80 years earlier than that of the bottom steel bar under the same parameters. In practical engineering, special attention should be paid on the stability of fresh concrete and vibrating procedures to avoid obvious CA settlement.Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Materials and Environmen

Numerical investigation of external sulfate attack and its effect on chloride binding and diffusion in concrete

Reinforced concrete (RC) structures may suffer from serious durability problems during long-term service. To investigate the deterioration of RC structures subjected to the dual attacks of chlorides and sulfates, this study proposes a coupled model for external sulfate attack (ESA) and its effect on chloride binding and diffusion. To account for the influence of sulfate attack on chloride binding, a reduction function is proposed. The effect of sulfate-induced damage on the chloride diffusion and chloride binding is considered through a damage function. The coupled model is validated against third-party experimental data from multiple perspectives. Some important factors such as solution concentration, immersion time, curing time and water-cement ratio, as well as how these factors affect the impact of sulfate attack on chloride transport, were elaborated. The findings may bring insights to the durability design of RC structures serving in harsh environments.Accepted author manuscriptMaterials and Environmen

Numerical study on the chemical and electrochemical coupling mechanisms for concrete under combined chloride-sulfate attack

Cementitious materials exposed to marine and saline environments are commonly threatened by a combined attack of sulfate and chloride ions. This study developed a numerical framework to investigate two combined coupling mechanisms of 1) coupled solid-liquid chemical reactions for competitive chloride-sulfate attack and 2) electrostatic multi-ion coupling effect on reactive-transport mechanisms. Various chemical reactions including sulfate attack with anhydrous calcium aluminates, secondary precipitation of expansive minerals, competitive binding, and calcium leaching have been quantified. The electrostatic potential caused by multi-ions coupling was solved according to constitutive electrochemical laws. After model validation, the chemical coupling mechanisms for solid-liquid reactions during competitive chloride-sulfate binding were investigated. On this foundation, the influence of electrostatic multi-ionic coupling effects on ionic transport and its interaction with chemical coupling were disclosed. It was found that neglecting multi-ions coupling effect would result in an underestimated chemical coupling strength in competitive chloride-sulfate binding.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Materials and Environmen

An experimental and numerical investigation of coarse aggregate settlement in fresh concrete under vibration

Fresh concrete needs vibration to compact, fill the mould and reach a dense state. During the compaction process, coarse aggregates (CAs) tend to settle, affecting the homogeneity and eventually the long-term durability of hardened concrete. In this study, a 3-D, multi-phase numerical model for fresh concrete is developed for better understanding the CA settlement under vibration. The settlement rate of the CA in vibrated concrete is considered based on the Stokes law, and the calibrated rheological parameter of mixtures is determined by the segmented sieving method. The model prediction shows that the vibration time has the greatest effect on CA settlement, followed by the particle size of CAs, whereas the density of CAs and the plastic viscosity of mixtures contribute a little compared with the aforementioned factors. Through experimental tests, the validity of prediction results is well verified. The proposed model provides a new method to understand and estimate the settlement behaviour of CAs.Accepted Author ManuscriptMaterials and Environmen

Numerical study of interactive ingress of calcium leaching, chloride transport and multi-ions coupling in concrete

In circumstances with wastewater and seawater, the behavior of multi-ions including calcium, chloride and others in concrete attracts attention. The present study investigated the multiple mechanisms that could happen under the special field situation above, including calcium leaching, chloride transport and multi-ion coupling. To realize the interactive ingress of multi ions, the simulation method for the processing of the individual mechanisms and the mutual influences is adopted. The distributions of the diversified ions are analyzed with the influence of the interfacial transition zone. The time-spatial distribution of porosity and its evolution mechanisms are investigated by considering the interaction with calcium ions in both pore solution and solid phase. The results indicate that calcium leaching would dominantly speed up chloride transport due to the coarsened pore structure, while the multi ions electrochemical coupling effect would facilitate calcium leaching in the early stage but subtly delay calcium leaching in the later stage.Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Materials and Environmen