Concerted [4 + 2] and Stepwise (2 + 2) Cycloadditions of Tetrafluoroethylene with Butadiene: DFT and DLPNO-UCCSD(T) Explorations.

Tetrafluoroethylene and butadiene form the 2 + 2 cycloadduct under kinetic control, but the Diels-Alder cycloadduct is formed under thermodynamic control. Borden and Getty showed that the preference for 2 + 2 cycloaddition is due to the necessity for syn-pyramidalization of the two CF2 groups in the 4 + 2 transition state. We have explored the full potential energy surface for the concerted and stepwise reactions of tetrafluoroethylene and butadiene with density functional theory, DFT (B3LYP and M06-2X), DLPNO-UCCSD(T), and CASSCF-NEVPT2 methods and with the distortion/interaction-activation strain model to explain the energetics of different pathways. The 2 + 2 cycloadduct is formed by an anti-transition state followed by two rotations and a final bond formation transition state. Energetics are compared to the reaction of maleic anhydride and ethylene

Nucleon Mass Splitting at Finite Isospin Chemical Potential

We investigate nucleon mass splitting at finite isospin chemical potential in the frame of two flavor Nambu--Jona-Lasinio model. It is analytically proved that, in the phase with explicit isospin symmetry breaking the proton mass decreases and the neutron mass increases linearly in the isospin chemical potential.Comment: 3 pages and no figure

Use of hydraulic rating to set environmental flows in the Zhangxi River, China

Ningbo city, China, is a rapidly growing residential and industrial centre, with a current population of 4 million. Its development has required a major water supply expansion programme providing 400,000 m3 of water per day from the upper reaches of the Zhangxi River by means of a cascade of reservoirs. Water resources management is achieved through operation of two major reservoirs, Jiaokou (75 million m3) and Zhougongzhai (93 million m3). Water is released from the reservoirs, via turbines (generating hydropower), for local industry, irrigated agriculture and public supply along the lower reaches of the River and to maintain the river ecosystem. Surveys of local residents along the Zhangxi River showed its important role in aspects of life, social activity, culture and leisure. Analysis of ecological monitoring data demonstrated the diverse nature of fish, plants and invertebrates within the river. Some elements of the ecosystem have a high local economic value to local people. This paper reports an assessment of the environmental flow needed to support key species in the river ecosystem. It employs hydraulic ratings to define sections of the river where flow velocity reaches 0.5 ms-1, required to stimulate spawning of the moonlight fish, an economically important and indicator species in the river. In two out of 6 cross-sections studied, flow releases from the reservoirs meet the needs of fish. The reservoirs reduce flood flows, which may lead to a loss of deep pools that are essential for the fish to survive during winter month

Investigation of Geological Anomalies at Pile Foundation Location in Urban Karst Areas Using Single Borehole Radar

Karst geological anomalies at pile locations significantly affect the bearing capacity and construction safety of the piles, posing a significant challenge for urbanization. Borehole geophysical methods are required to extend the detection range and identify karst voids that are at pole locations and near drilled boreholes. In this paper, we developed a near offset and small diameter single borehole ground penetration radar (GPR) prototype. A signal processing method combining complex signal analysis by Hilbert transform (HT) and medium filtering was suggested to differentiate the weak backscattered wave from borehole background noise. A controlled horizontal borehole experiment was used to demonstrate the applicability of the prototype and the advantages of the signal analysis method prior to application in a real project. The controlled test presented three typical wave events corresponding to a soil–rock interface, rock fractures, and karst voids. Field tests were conducted at a freeway bridge extension project in an urban karst area. Multiple karst voids, sinkholes, rock fractures, and integrated bedrock were identified by analysis of four typical detection scenarios. The remediation of the karst voids and a rotary bored piling with real-time steel casing construction strategy were designed based on the investigation results. The construction feedback demonstrates that single borehole radar detection is effective for the investigation of anomalies at pile locations in urban karst areas

The ACS Fornax Cluster Survey. III. Globular Cluster Specific Frequencies of Early-Type Galaxies

The globular cluster (GC) specific frequency ($S_N$), defined as the number of GCs per unit galactic luminosity, represents the efficiency of GC formation (and survival) compared to field stars. Despite the naive expectation that star cluster formation should scale directly with star formation, this efficiency varies widely across galaxies. To explore this variation we measure the z-band GC specific frequency ($S_{N,z}$) for 43 early-type galaxies (ETGs) from the Hubble Space Telescope (HST)/Advanced Camera for Surveys (ACS) Fornax Cluster Survey. Combined with the homogenous measurements of $S_{N,z}$ in 100 ETGs from the HST/ACS Virgo Cluster Survey from Peng et al. (2008), we investigate the dependence of $S_{N,z}$ on mass and environment over a range of galaxy properties. We find that $S_{N,z}$ behaves similarly in the two galaxy clusters, despite the clusters' order-of-magnitude difference in mass density. The $S_{N,z}$ is low in intermediate-mass ETGs ($-20<M_z<-23$), and increases with galaxy luminosity. It is elevated at low masses, on average, but with a large scatter driven by galaxies in dense environments. The densest environments with the strongest tidal forces appear to strip the GC systems of low-mass galaxies. However, in low-mass galaxies that are not in strong tidal fields, denser environments correlate with enhanced GC formation efficiencies. Normalizing by inferred halo masses, the GC mass fraction, $\eta=(3.36\pm0.2)\times10^{-5}$, is constant for ETGs with stellar masses $\mathcal{M}_\star \lesssim 3\times10^{10}M_\odot$, in agreement with previous studies. The lack of correlation between the fraction of GCs and the nuclear light implies only a weak link between the infall of GCs and the formation of nuclei.Comment: 16 pages, 7 figures, 6 tables; accepted by Ap