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Tandem Chloropalladation/Cyclization and Dearomative Cyclization toward Functionalized Tricyclic Bridged [3.2.1] Skeleton Compounds
A palladium-catalyzed tandem reaction
is reported that involves
chloropalladation/cyclization and dearomative cyclization to construct
a tricyclic bridged [3.2.1] carbocyclic-skeleton and oxa- and aza-skeletons.
In this domino process, a level of ring strain and other competitive
reactions, i.e., protonolysis, β-hydride elimination, and chlorination
of the C–Pd bond, were suppressed to the lowest level under
mild reaction conditions