Catalytic Asymmetric Spirocyclizing Diels–Alder Reactions of Enones: Stereoselective Total and Formal Syntheses of α-Chamigrene, β-Chamigrene, Laurencenone C, Colletoic Acid, and Omphalic Acid

We disclose a general catalytic enantioselective Diels–Alder reaction of exo-enones with dienes to give spirocyclanes. The obtained products feature highly congested quaternary stereogenic spirocenters and are used in concise total and formal syntheses of several sesquiterpenes, including of α-chamigrene, β-chamigrene, laurencenone C, colletoic acid, and omphalic acid. The stereo- and regioselectivities of our spirocyclizing cycloaddition are effectively controlled by strongly acidic and confined imidodiphosphorimidate catalysts. Computational studies shed light on the origin of reactivity and selectivity

Color Transparency at COMPASS energies

Pionic quasielastic knockout of protons from nuclei at 200 GeV show very large effects of color transparency as -t increases from 0 to several GeV^2. Similar effects are expected for quasielastic photoproduction of vector mesons.Comment: 9 pages, 4 figure

Non-Simplified SUSY: Stau-Coannihilation at LHC and ILC

If new phenomena beyond the Standard Model will be discovered at the LHC, the properties of the new particles could be determined with data from the High-Luminosity LHC and from a future linear collider like the ILC. We discuss the possible interplay between measurements at the two accelerators in a concrete example, namely a full SUSY model which features a small stau_1-LSP mass difference. Various channels have been studied using the Snowmass 2013 combined LHC detector implementation in the Delphes simulation package, as well as simulations of the ILD detector concept from the Technical Design Report. We investigate both the LHC and ILC capabilities for discovery, separation and identification of various parts of the spectrum. While some parts would be discovered at the LHC, there is substantial room for further discoveries at the ILC. We finally highlight examples where the precise knowledge about the lower part of the mass spectrum which could be acquired at the ILC would enable a more in-depth analysis of the LHC data with respect to the heavier states.Comment: 42 pages, 18 figures, 12 table

Networks of lexical borrowing and lateral gene transfer in language and genome evolution

Like biological species, languages change over time. As noted by Darwin, there are many parallels between language evolution and biological evolution. Insights into these parallels have also undergone change in the past 150 years. Just like genes, words change over time, and language evolution can be likened to genome evolution accordingly, but what kind of evolution? There are fundamental differences between eukaryotic and prokaryotic evolution. In the former, natural variation entails the gradual accumulation of minor mutations in alleles. In the latter, lateral gene transfer is an integral mechanism of natural variation. The study of language evolution using biological methods has attracted much interest of late, most approaches focusing on language tree construction. These approaches may underestimate the important role that borrowing plays in language evolution. Network approaches that were originally designed to study lateral gene transfer may provide more realistic insights into the complexities of language evolution

Turbulence structure near a sharp density interface

The effects of a sharp density interface and a rigid flat plate on oscillating-grid induced shear-free turbulence were investigated experimentally. A two-component laser-Doppler velocimeter was used to measure turbulence intensities in and above the density interface (with matched refractive indices) and near the rigid flat plate. Energy spectra, velocity correlations, and kinetic energy fluxes were also measured. Amplification of the horizontal turbulent velocity, coupled with a sharp reduction in the vertical turbulent velocity, was observed near both the density interface and the flat plate. These findings are in agreement with some previous results pertaining to shear-free turbulence near rigid walls (Hunt & Graham 1978) and near density interfaces (Long 1978). The results imply that, near the density interface, the turbulent kinetic energy in the vertical velocity component is only a small fraction of the total turbulent kinetic energy and indicate that the effects of the anisotropy created by the density interface or the flat plate are confined to the large turbulence scales

Design of Pre-Dumping Ring Spin Rotator with a Possibility of Helicity Switching for Polarized Positrons at the ILC

The use of polarized beams enhance the possibility of the precision measurements at the International Linear Collider (ILC). In order to preserve the degree of polarization during beam transport spin rotators are included in the current TDR ILC Lattice. In this report some advantages of using a combined spin rotator/spin flipper are discussed. A few possible lattice designs of spin flipper developed at DESY in 2012 are presented.Comment: Talk presented at the International Workshop on Future Linear Colliders (LCWS15), Whistler, Canada, 2-6 November 201

Untangling the evolution of body-part terminology in Pano: conservative versus innovative traits in body-part lexicalization

Although language-family specific traits which do not find direct counterparts outside a given language family are usually ignored in quantitative phylogenetic studies, scholars have made ample use of them in qualitative investigations, revealing their potential for identifying language relationships. An example of such a family specific trait are body-part expressions in Pano languages, which are often lexicalized forms, composed of bound roots (also called body-part prefixes in the literature) and non-productive derivative morphemes (called here body-part formatives). We use various statistical methods to demonstrate that whereas body-part roots are generally conservative, body-part formatives exhibit diverse chronologies and are often the result of recent and parallel innovations. In line with this, the phylogenetic structure of body-part roots projects the major branches of the family, while formatives are highly non-tree-like. Beyond its contribution to the phylogenetic analysis of Pano languages, this study provides significative insights into the role of grammatical innovations for language classification, the origin of morphological complexity in the Amazon and the phylogenetic signal of specific grammatical traits in language families

Lexibank, a public repository of standardized wordlists with computed phonological and lexical features

The past decades have seen substantial growth in digital data on the world’s languages. At the same time, the demand for cross-linguistic datasets has been increasing, as witnessed by numerous studies devoted to diverse questions on human prehistory, cultural evolution, and human cognition. Unfortunately, most published datasets lack standardization which makes their comparison difficult. Here, we present a new approach to increase the comparability of cross-linguistic lexical data. We have designed workflows for the computer-assisted lifting of datasets to Cross-Linguistic Data Formats, a collection of standards that make these datasets more Findable, Accessible, Interoperable, and Reusable (FAIR). We test the Lexibank workflow on 100 lexical datasets from which we derive an aggregated database of wordlists in unified phonetic transcriptions covering more than 2000 language varieties. We illustrate the benefits of our approach by showing how phonological and lexical features can be automatically inferred, complementing and expanding existing cross-linguistic datasets

\u3ci\u3eCivil Society, Conflict and Violence\u3c/i\u3e

Editors: Wolfgang Dörner and Regina A. List Chapter 6, The Law, Security and Civil Society Freedoms, co-authored by Brett Kyle, UNO faculty member. This book looks at the role that civil society organizations play in dealing with conflict and violence. The authors argue that in most of the prevalent conceptualizations the conflict dimension of civil society is either downplayed or inadequately addressed. They contend that the ability to deal with conflict is at the heart of organized civil society; in the political process, one of civil society\u27s key functions is to express and mediate between different interests, thus contributing to political decision-making. The chapters draw on detailed, empirical data from the CIVICUS Civil Society Index - a unique comparative data-set drawn from 25 countries, which has not previously been made publicly available. It examines the different ways violence has been manifested in civil societies, the meaning of violent protest and the impact of security legislation that might hinder the mediating efforts of civil society. The book offers a sophisticated comparison between conflict and post-conflict countries and an analysis of the role of civil society in conflict resolution, reconciliation and transitional justice.https://digitalcommons.unomaha.edu/facultybooks/1307/thumbnail.jp