First results on Martian carbon monoxide from Herschel/HIFI observations

We report on the initial analysis of Herschel/HIFI carbon monoxide (CO) observations of the Martian atmosphere performed between 11 and 16 April 2010. We selected the (7–6) rotational transitions of the isotopes ^(13)CO at 771 GHz and C^(18)O and 768 GHz in order to retrieve the mean vertical profile of temperature and the mean volume mixing ratio of carbon monoxide. The derived temperature profile agrees within less than 5 K with general circulation model (GCM) predictions up to an altitude of 45 km, however, show about 12–15 K lower values at 60 km. The CO mixing ratio was determined as 980 ± 150 ppm, in agreement with the 900 ppm derived from Herschel/SPIRE observations in November 2009

HIFI observations of water in the atmosphere of comet C/2008 Q3 (Garradd)

High-resolution far-infrared and sub-millimetre spectroscopy of water lines is an important tool to understand the physical and chemical properties of cometary atmospheres.We present observations of several rotational ortho- and para-water transitions in comet C/2008 Q3 (Garradd) performed with HIFI on Herschel. These observations have provided the first detection of the 2_(12)−1_(01) (1669 GHz) ortho and 1_(11)−0_(00) (1113 GHz) para transitions of water in a cometary spectrum. In addition, the ground-state transition 1_(10)−1_(01) at 557 GHz is detected and mapped. By detecting several water lines quasi-simultaneously and mapping their emission we can constrain the excitation parameters in the coma. Synthetic line profiles are computed using excitation models which include excitation by collisions, solar infrared radiation, and radiation trapping. We obtain the gas kinetic temperature, constrain the electron density profile, and estimate the coma expansion velocity by analyzing the map and line shapes. We derive water production rates of 1.7−2.8 × 10^(28) s^(−1) over the range r_h = 1.83−1.85 AU

Observations of pre-stellar cores

Our understanding of the physical and chemical structure of pre-stellar cores, the simplest star-forming sites, has significantly improved since the last IAU Symposium on Astrochemistry (South Korea, 1999). Research done over these years has revealed that major molecular species like CO and CS systematically deplete onto dust grains at the interior of pre-stellar cores, while species like N2H+ and NH3 survive in the gas phase and can usually be detected towards the core centers. Such a selective behaviour of molecular species gives rise to a differentiated (onion-like) chemical composition, and manifests itself in molecular maps as a dichotomy between centrally peaked and ring-shaped distributions. From the point of view of star-formation studies, the identification of molecular inhomogeneities in cores helps to resolve past discrepancies between observations made using different tracers, and brings the possibility of self-consistent modelling of the core internal structure. Here I present recent work on determining the physical and chemical structure of two pre-stellar cores, L1498 and L1517B, using observations in a large number of molecules and Monte Carlo radiative transfer analysis. These two cores are typical examples of the pre-stellar core population, and their chemical composition is characterized by the presence of large freeze out holes in most molecular species. In contrast with these chemically processed objects, a new population of chemically young cores has started to emerge. The characteristics of its most extreme representative, L1521E, are briefly reviewed.Comment: 10 pages, 5 figures. To appear in IAU 231 conf. proc. "Astrochemistry: Recent Successes and Current Challenges," eds. D.C. Lis, G.A. Blake, and E. Herbs

Water production in comet 81P/Wild 2 as determined by Herschel/HIFI

The high spectral resolution and sensitivity of Herschel/HIFI allows for the detection of multiple rotational water lines and accurate determinations of water production rates in comets. In this Letter we present HIFI observations of the fundamental 1_(10)–1_(01) (557 GHz) ortho and 1_(11)–0_(00) (1113 GHz) para rotational transitions of water in comet 81P/Wild 2 acquired in February 2010. We mapped the extent of the water line emission with five point scans. Line profiles are computed using excitation models which include excitation by collisions with electrons and neutrals and solar infrared radiation. We derive a mean water production rate of 1.0 × 10^(28) molecules s^(−1) at a heliocentric distance of 1.61 AU about 20 days before perihelion, in agreement with production rates measured from the ground using observations of the 18-cm OH lines. Furthermore, we constrain the electron density profile and gas kinetic temperature, and estimate the coma expansion velocity by fitting the water line shapes

The Distribution of Deuterium in the ISM: One Nucleon is Never Enough

The tendency for deuterium to be concentrated into the cold dense regions of the galaxy is due to the lower ground state energy of the heavier molecules. Such chemical fractionation leads to [D/H] values as high as 1! In turn this allows the detection of species such as ND_3, H_2D^+ and D_2H^+. The fraction of the interstellar medium (ISM) with such large deuteration is hard to estimate, but may be sufficient to cause both spatially variable and generally low [D/H] values in the diffuse ISM

Discovery of Water Vapor in the High-redshift Quasar APM 08279+5255 at z = 3.91

We report a detection of the excited 2_(20)-2_(11) rotational transition of para-H_2O in APM 08279+5255 using the IRAM Plateau de Bure Interferometer. At z = 3.91, this is the highest-redshift detection of interstellar water to date. From large velocity gradient modeling, we conclude that this transition is predominantly radiatively pumped and on its own does not provide a good estimate of the water abundance. However, additional water transitions are predicted to be detectable in this source, which would lead to an improved excitation model. We also present a sensitive upper limit for the hydrogen fluoride (HF) J = 1-0 absorption toward APM 08279+5255. While the face-on geometry of this source is not favorable for absorption studies, the lack of HF absorption is still puzzling and may be indicative of a lower fluorine abundance at z = 3.91 compared with the Galactic interstellar medium

The CHESS spectral survey of star forming regions: Peering into the protostellar shock L1157-B1 - II. Shock dynamics

Context. The outflow driven by the low-mass class 0 protostar L1157 is the prototype of the so-called chemically active outflows. The bright bowshock B1 in the southern outflow lobe is a privileged testbed of magneto-hydrodynamical (MHD) shock models, for which dynamical and chemical processes are strongly interdependent. Aims. We present the first results of the unbiased spectral survey of the L1157-B1 bowshock, obtained in the framework of the key program “Chemical HErschel Surveys of star forming regions” (CHESS). The main aim is to trace the warm and chemically enriched gas and to infer the excitation conditions in the shock region. Methods. The CO 5-4 and o-H2_O 1_(10)–1_(01) lines have been detected at high-spectral resolution in the unbiased spectral survey of the HIFI-band 1b spectral window (555–636 GHz), presented by Codella et al. in this volume. Complementary ground-based observations in the submm window help establish the origin of the emission detected in the main-beam of HIFI and the physical conditions in the shock. Results. Both lines exhibit broad wings, which extend to velocities much higher than reported up to now. We find that the molecular emission arises from two regions with distinct physical conditions : an extended, warm (100 K), dense (3 × 10^5 cm^(-3)) component at low-velocity, which dominates the water line flux in Band 1; a secondary component in a small region of B1 (a few arcsec) associated with high-velocity, hot (>400 K) gas of moderate density ((1.0–3.0) × 10^4 cm^(-3)), which appears to dominate the flux of the water line at 179μm observed with PACS. The water abundance is enhanced by two orders of magnitude between the low- and the high-velocity component, from 8 × 10^(-7) up to 8 × 10^(-5). The properties of the high-velocity component agree well with the predictions of steady-state C-shock models