Visualization of Charge Dynamics when Water Droplets Bounce on a Hydrophobic Surface

Visualizing the motion of water droplets and understanding their electrification behavior holds significance for applications related to droplet transport, self-cleaning, and anti-icing/deicing and for providing a comprehensive explanation of the solid–liquid triboelectrification mechanism. Here, by constructing microcolumnar structures on the polytetrafluoroethylene surface, a water droplet-based single electrode triboelectric nanogenerator was fabricated for visualizing charge dynamics when a water droplet bounces on a hydrophobic surface. The motion state of the water droplet is closely linked to its electrification behavior through the integration of a high-speed camera and an ammeter. The electrification behavior stemming from the bounce of the water droplet is dynamically captured in real-time. The results show that the magnitude and polarity of the electrical signal have strong dependence on the motion state of the water droplet. For instance, when a water droplet approaches or moves away from the substrate in a single direction, a unipolar electrical signal is generated. However, when the water droplet reaches its limit in the initial motion direction, it signifies a static equilibrium state, resulting in the electrical signal being at zero. Furthermore, we examine the impact of factors such as impact speed, drop contact area, contact line spreading/retraction speed, and impact angle on electrification. Finally, based on the close relationship between poly­(ethylene oxide) (PEO) droplet bounce dynamics and electrical signals, the bouncing details of PEO droplets with different concentrations are tracked by electrical signals. This study digitally presents the whole process of droplet bounce in situ and provides a means for monitoring and tracking droplet movement

Visualization of Charge Dynamics when Water Droplets Bounce on a Hydrophobic Surface

Visualizing the motion of water droplets and understanding their electrification behavior holds significance for applications related to droplet transport, self-cleaning, and anti-icing/deicing and for providing a comprehensive explanation of the solid–liquid triboelectrification mechanism. Here, by constructing microcolumnar structures on the polytetrafluoroethylene surface, a water droplet-based single electrode triboelectric nanogenerator was fabricated for visualizing charge dynamics when a water droplet bounces on a hydrophobic surface. The motion state of the water droplet is closely linked to its electrification behavior through the integration of a high-speed camera and an ammeter. The electrification behavior stemming from the bounce of the water droplet is dynamically captured in real-time. The results show that the magnitude and polarity of the electrical signal have strong dependence on the motion state of the water droplet. For instance, when a water droplet approaches or moves away from the substrate in a single direction, a unipolar electrical signal is generated. However, when the water droplet reaches its limit in the initial motion direction, it signifies a static equilibrium state, resulting in the electrical signal being at zero. Furthermore, we examine the impact of factors such as impact speed, drop contact area, contact line spreading/retraction speed, and impact angle on electrification. Finally, based on the close relationship between poly­(ethylene oxide) (PEO) droplet bounce dynamics and electrical signals, the bouncing details of PEO droplets with different concentrations are tracked by electrical signals. This study digitally presents the whole process of droplet bounce in situ and provides a means for monitoring and tracking droplet movement

Scalable Production of Hydrophilic Graphene Nanosheets via in Situ Ball-Milling-Assisted Supercritical CO₂ Exfoliation

The scalable production of large quantities of defect-free graphene nanosheets (GNs) with low cost and excellent properties is essential for practical applications. Despite the highly intense research of this area, the mass production of graphene nanosheets with high solubility remains a key challenge. In the present work, we propose a scalable exfoliation process for hydrophilic GNs by ball-milling-assisted supercritical CO₂ exfoliation in the presence of poly­(vinylpyrrolidone) via the synergetic effect of chemical peeling and mechanical shear forces. The exfoliation difficulty has been reduced due to the intercalation effects of supercritical CO₂ molecules. With the ball-milling assistance, the modifier has been introduced onto the edge or/and surface of the GNs. The process results in hydrophilic GNs with little damage to the in-plane structure. The GNs can be dispersed in various solvents with a concentration of up to 0.854 mg/mL (water) and remain stable for several months

In Situ Imaging the Oxygen Reduction Reactions of Solid State Na–O₂ Batteries with CuO Nanowires as the Air Cathode

We report real time imaging of the oxygen reduction reactions (ORRs) in all solid state sodium oxygen batteries (SOBs) with CuO nanowires (NWs) as the air cathode in an aberration-corrected environmental transmission electron microscope under an oxygen environment. The ORR occurred in a distinct two-step reaction, namely, a first conversion reaction followed by a second multiple ORR. In the former, CuO was first converted to Cu₂O and then to Cu; in the latter, NaO₂ formed first, followed by its disproportionation to Na₂O₂ and O₂. Concurrent with the two distinct electrochemical reactions, the CuO NWs experienced multiple consecutive large volume expansions. It is evident that the freshly formed ultrafine-grained Cu in the conversion reaction catalyzed the latter one-electron-transfer ORR, leading to the formation of NaO₂. Remarkably, no carbonate formation was detected in the oxygen cathode after cycling due to the absence of carbon source in the whole battery setup. These results provide fundamental understanding into the oxygen chemistry in the carbonless air cathode in all solid state Na–O₂ batteries

In Situ Imaging the Oxygen Reduction Reactions of Solid State Na–O₂ Batteries with CuO Nanowires as the Air Cathode

We report real time imaging of the oxygen reduction reactions (ORRs) in all solid state sodium oxygen batteries (SOBs) with CuO nanowires (NWs) as the air cathode in an aberration-corrected environmental transmission electron microscope under an oxygen environment. The ORR occurred in a distinct two-step reaction, namely, a first conversion reaction followed by a second multiple ORR. In the former, CuO was first converted to Cu₂O and then to Cu; in the latter, NaO₂ formed first, followed by its disproportionation to Na₂O₂ and O₂. Concurrent with the two distinct electrochemical reactions, the CuO NWs experienced multiple consecutive large volume expansions. It is evident that the freshly formed ultrafine-grained Cu in the conversion reaction catalyzed the latter one-electron-transfer ORR, leading to the formation of NaO₂. Remarkably, no carbonate formation was detected in the oxygen cathode after cycling due to the absence of carbon source in the whole battery setup. These results provide fundamental understanding into the oxygen chemistry in the carbonless air cathode in all solid state Na–O₂ batteries

In Situ Imaging the Oxygen Reduction Reactions of Solid State Na–O₂ Batteries with CuO Nanowires as the Air Cathode

We report real time imaging of the oxygen reduction reactions (ORRs) in all solid state sodium oxygen batteries (SOBs) with CuO nanowires (NWs) as the air cathode in an aberration-corrected environmental transmission electron microscope under an oxygen environment. The ORR occurred in a distinct two-step reaction, namely, a first conversion reaction followed by a second multiple ORR. In the former, CuO was first converted to Cu₂O and then to Cu; in the latter, NaO₂ formed first, followed by its disproportionation to Na₂O₂ and O₂. Concurrent with the two distinct electrochemical reactions, the CuO NWs experienced multiple consecutive large volume expansions. It is evident that the freshly formed ultrafine-grained Cu in the conversion reaction catalyzed the latter one-electron-transfer ORR, leading to the formation of NaO₂. Remarkably, no carbonate formation was detected in the oxygen cathode after cycling due to the absence of carbon source in the whole battery setup. These results provide fundamental understanding into the oxygen chemistry in the carbonless air cathode in all solid state Na–O₂ batteries

In Situ Imaging the Oxygen Reduction Reactions of Solid State Na–O₂ Batteries with CuO Nanowires as the Air Cathode

We report real time imaging of the oxygen reduction reactions (ORRs) in all solid state sodium oxygen batteries (SOBs) with CuO nanowires (NWs) as the air cathode in an aberration-corrected environmental transmission electron microscope under an oxygen environment. The ORR occurred in a distinct two-step reaction, namely, a first conversion reaction followed by a second multiple ORR. In the former, CuO was first converted to Cu₂O and then to Cu; in the latter, NaO₂ formed first, followed by its disproportionation to Na₂O₂ and O₂. Concurrent with the two distinct electrochemical reactions, the CuO NWs experienced multiple consecutive large volume expansions. It is evident that the freshly formed ultrafine-grained Cu in the conversion reaction catalyzed the latter one-electron-transfer ORR, leading to the formation of NaO₂. Remarkably, no carbonate formation was detected in the oxygen cathode after cycling due to the absence of carbon source in the whole battery setup. These results provide fundamental understanding into the oxygen chemistry in the carbonless air cathode in all solid state Na–O₂ batteries

Multifunctional PHPMA-Derived Polymer for Ratiometric pH Sensing, Fluorescence Imaging, and Magnetic Resonance Imaging

In this paper, we report synthesis and characterization of a novel multimodality (MRI/fluorescence) probe for pH sensing and imaging. A multifunctional polymer was derived from poly­(<i>N</i>-(2-hydroxypropyl)­methacrylamide) (PHPMA) and integrated with a naphthalimide-based-ratiometric fluorescence probe and a gadolinium–1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid complex (Gd–DOTA complex). The polymer was characterized using UV–vis absorption spectrophotometry, fluorescence spectrofluorophotometry, magnetic resonance imaging (MRI), and confocal microscopy for optical and MRI-based pH sensing and cellular imaging. In vitro labeling of macrophage J774 and esophageal CP-A cell lines shows the polymer’s ability to be internalized in the cells. The transverse relaxation time (<i>T</i>₂) of the polymer was observed to be pH-dependent, whereas the spin-lattice relaxation time (<i>T</i>₁) was not. The pH probe in the polymer shows a strong fluorescence-based ratiometric pH response with emission window changes, exhibiting blue emission under acidic conditions and green emission under basic conditions, respectively. This study provides new materials with multimodalities for pH sensing and imaging

In Situ Imaging the Oxygen Reduction Reactions of Solid State Na–O₂ Batteries with CuO Nanowires as the Air Cathode

We report real time imaging of the oxygen reduction reactions (ORRs) in all solid state sodium oxygen batteries (SOBs) with CuO nanowires (NWs) as the air cathode in an aberration-corrected environmental transmission electron microscope under an oxygen environment. The ORR occurred in a distinct two-step reaction, namely, a first conversion reaction followed by a second multiple ORR. In the former, CuO was first converted to Cu₂O and then to Cu; in the latter, NaO₂ formed first, followed by its disproportionation to Na₂O₂ and O₂. Concurrent with the two distinct electrochemical reactions, the CuO NWs experienced multiple consecutive large volume expansions. It is evident that the freshly formed ultrafine-grained Cu in the conversion reaction catalyzed the latter one-electron-transfer ORR, leading to the formation of NaO₂. Remarkably, no carbonate formation was detected in the oxygen cathode after cycling due to the absence of carbon source in the whole battery setup. These results provide fundamental understanding into the oxygen chemistry in the carbonless air cathode in all solid state Na–O₂ batteries

In Situ Imaging the Oxygen Reduction Reactions of Solid State Na–O₂ Batteries with CuO Nanowires as the Air Cathode

We report real time imaging of the oxygen reduction reactions (ORRs) in all solid state sodium oxygen batteries (SOBs) with CuO nanowires (NWs) as the air cathode in an aberration-corrected environmental transmission electron microscope under an oxygen environment. The ORR occurred in a distinct two-step reaction, namely, a first conversion reaction followed by a second multiple ORR. In the former, CuO was first converted to Cu₂O and then to Cu; in the latter, NaO₂ formed first, followed by its disproportionation to Na₂O₂ and O₂. Concurrent with the two distinct electrochemical reactions, the CuO NWs experienced multiple consecutive large volume expansions. It is evident that the freshly formed ultrafine-grained Cu in the conversion reaction catalyzed the latter one-electron-transfer ORR, leading to the formation of NaO₂. Remarkably, no carbonate formation was detected in the oxygen cathode after cycling due to the absence of carbon source in the whole battery setup. These results provide fundamental understanding into the oxygen chemistry in the carbonless air cathode in all solid state Na–O₂ batteries