Asian dust storm events of spring 2001 and associated pollutants observed in New England by the Atmospheric Investigation, Regional Modeling, Analysis and Prediction (AIRMAP) monitoring network

Between 18 April and 13 May 2001, three statistically extreme dust aerosol events were observed across the entire northeastern United States. High levels of bulk aerosol water-soluble Ca2+ (range = 42–482 pptv) and PM2.5 elemental Ca (range = 19–156 pptv) were observed simultaneously at Atmospheric Investigation, Regional Modeling, Analysis and Prediction (AIRMAP) and Interagency Monitoring of Protected Visual Environments (IMPROVE) stations. On the basis of Ca2+ concentrations, the average bulk dust concentration for all events across all four AIRMAP stations was estimated to be 7.4 μg/m3. There was no evidence of dust outbreaks in North America large enough to explain these events. However, in April 2001, massive dust storms occurred in the Tarim Pendi basin and in the Gobi deserts of southern Mongolia and China. Comparison of elemental ratios of AIRMAP samples to previously reported Asian dust aerosol samples showed that all AIRMAP samples had a chemical composition similar to Asian dust transported over long distances. Within the dust plumes, strong correlations were observed between absorption, scattering, and CO, indicative of an anthropogenic contribution including elemental carbon and SO42− aerosols. Aerosol NO3− was also highly elevated during event days, most likely due to uptake of HNO3 by the dust during transport. A comparison of dust plumes sampled by AIRMAP to those sampled off the Asian coast during the TRACE-P airborne mission and on the U.S. west coast, strongly suggested entrainment of additional pollutants (e.g., CO, aerosol NO3−, and SO42−) as the dust plumes were transported over North America

A major regional air pollution event in the northeastern United States caused by extensive forest fires in Quebec, Canada

During early July 2002, wildfires burned ∼1 × 106 ha of forest in Quebec, Canada. The resultant smoke plume was seen in satellite images blanketing the U.S. east coast. Concurrently, extremely high CO mixing ratios were observed at the Atmospheric Investigation, Regional Modeling, Analysis and Prediction (AIRMAP) network sites in New Hampshire and at the Harvard Forest Environmental Measurement Site (HFEMS) in Massachusetts. The CO enhancements were on the order of 525–1025 ppbv above low mixing ratio conditions on surrounding days. A biomass burning source for the event was confirmed by concomitant enhancements in aerosol K+, NH4+, NO3−, and C2O42− mixing ratios at the AIRMAP sites. Additional data for aerosol K, organic carbon, and elemental carbon from the Interagency Monitoring of Protected Visual Environments network and CO data from Environmental Protection Agency sites indicated that the smoke plume impacted much of the U.S. east coast, from Maine to Virginia. CO mixing ratios and K concentrations at stations with 10-year or longer records suggested that this was the largest biomass burning plume to impact the U.S. east coast in over a decade. Furthermore, CO mixing ratios and aerosol particles with diameters 2.5) mass and scattering coefficients from the AIRMAP network and HFEMS indicated that this event was comparable to the large anthropogenic combustion and haze events which intermittently impact rural New England. The degree of enhancement of O3, NOy, NO3−, NH4+, and SO42− in the biomass plume showed significant variation with elevation and latitude that is attributed to variations in transport and surface depositional processes

Highly active iridium(I) complexes for the selective hydrogenation of carbon-carbon multiple bonds

New iridium(I) complexes, bearing a bulky NHC/phosphine ligand combination, have been established as extremely efficient hydrogenation catalysts that can be used at low catalyst loadings, and are compatible with functional groups which are often sensitive to more routinely employed hydrogenation methods

Seasonal distributions of fine aerosol sulfate in the North American Arctic basin during TOPSE

We used the mist chamber/ion chromatography technique to quantify fine aerosol SO4=(\u3c2.7 μm) in the Arctic during the Tropospheric Ozone Production about the Spring Equinox Experiment (TOPSE) with about 2.5 min time resolution. Our effective sample area ranged from 50° to 86°N and 53° to 100°W. The seasonal evolution of fine aerosol sulfate in the Arctic troposphere during TOPSE was consistent with the phenomenon of Arctic haze. Arctic haze has been attributed to pollution from sources in the Arctic and pollution transported meridionally along stable isentropes into the Arctic in geographically broad but vertically narrow bands. These layers became more prevalent at higher altitudes as the season progressed toward summer, and the relevant isentropes are not held so close to the surface. Mean fine particle SO4= mixing ratios during TOPSE in February below 1000 m were elevated (112 pptv) and highly variable (between 28 and 290 pptv) but were significantly lower at higher altitudes (about 40 pptv). As the season progressed, elevated mixing ratios and higher variability were observed at higher altitudes, up to 7 km. In May, mixing ratios at the lowest altitudes declined but still remained higher than in February at all altitudes. The high variability in our measurements likely reflects the vertical heterogeneity of the wintertime Arctic atmosphere as the airborne sampling platform passed in and out of these layers. It is presumed that mixing ratios and variability will continue to decline at all altitudes into the summer as wet deposition processes become important in removing aerosol SO4= from the troposphere

Stratospheric influence on the northern North American free troposphere during TOPSE: 7Be as a stratospheric tracer

We use 7Be, with HNO3 and O3, to identify air masses sampled from the NCAR C-130 during TOPSE that retained clear evidence of stratospheric influence. A total of 43 such air masses, spread fairly evenly across the February to May sampling period, and 40°N–86°N latitude range, were encountered. South of 55°N, nearly all clear stratospheric influence was restricted to altitudes above 6 km. At higher latitudes stratospherically influenced air masses were encountered as low as 2 km. Approximately 12% of all TOPSE sampling time at altitudes above 2 km was spent in stratospherically impacted air, above 6 km this increased to more than half of the time. Because it is not certain how much of this stratospherically influenced air irreversibly injected mass (and chemical compounds) into the troposphere, we estimate the stratospheric fraction of O3 in high latitude TOPSE samples based on a linear relationship to7Be and compare it to in situ O3. This analysis indicates that the stratospheric source can account for a dominant fraction (\u3e85%) of in situ O3 throughout TOPSE, but that the stratospheric contribution was nearly constant through the 4 month campaign. In February and March the 7Be based estimates of stratospheric O3 account for 10–15% more O3 than was measured, but by April and May there is up to about 10% more O3 than expected from the stratospheric source. This trend suggests that a seasonal transition from O3 depletion to photochemical production in the high latitude North American troposphere is the major cause of the springtime increase in O3

Ariel - Volume 1 Number 3

Copyright 1969 Arie

Charismatic violence and the sanctification of the super-rich

Drawing historical comparisons between the 19th century and the present, this article describes and analyses how an elite section of the global rich, through mega-giving and a reemerging notion of ‘noblesse oblige’ that is enshrined in the philanthrocapitalism movement, have fostered a sacred rationale for their extreme wealth. Not only do the new nobles hold the power of wealth but, through mega-giving, they generate a moral imagery akin to religious figures who ostensibly self-sacrifice for the good of everyone else. This generates a form of charismatic authority that affords the super-rich an influential space from which to spread a ‘theodicy of privilege’ – legitimating their elevated economic position, shielding growing wealth concentration from criticism, and sanctifying the claim that individual mega-wealth is collectively beneficial. Through its contribution to and facilitation of the inegalitarian status quo, this theodicy engenders various forms of structural violence. Here we explore the mechanisms that enable wealthy donors to position themselves as apparent benefactors of humanity, including a reliance on metrics that appear to justify the claim that targeted philanthropic expenditures can and are reducing global wealth and health inequalities, but which raise unanswered questions surrounding the actual effects of the outcomes claimed